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Determination of optimum conditions in preparing highly reactive electrogenerated zinc by gas chromatograph

Highly reactive electrogenerated zinc metal (EGZn/Naph) was readily prepared by electrolysis of a DMF solution cotaining naphthalene and a supporting electrolyte in a one-compartment cell fitted with a platinum cathode and a zinc anode. The reactivity of this EGZn/Naph elucidated by an efficient tra...

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Main Authors: Abdul Jalil, Aishah, Kurono, Nobuhito, Tokuda, Masao
Format: Conference or Workshop Item
Language:English
Published: 2004
Subjects:
T Technology (General)
Online Access:http://eprints.utm.my/id/eprint/5242/1/AishahAbdulJalil2004_DeterminationOfOptimumConditions.pdf
http://eprints.utm.my/id/eprint/5242/
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spelling my.utm.52422017-09-10T06:40:07Z http://eprints.utm.my/id/eprint/5242/ Determination of optimum conditions in preparing highly reactive electrogenerated zinc by gas chromatograph Abdul Jalil, Aishah Kurono, Nobuhito Tokuda, Masao T Technology (General) Highly reactive electrogenerated zinc metal (EGZn/Naph) was readily prepared by electrolysis of a DMF solution cotaining naphthalene and a supporting electrolyte in a one-compartment cell fitted with a platinum cathode and a zinc anode. The reactivity of this EGZn/Naph elucidated by an efficient transformation of ethyl 2-bromolbutanoate as a model substrate into the corresponding organozinc compound, which can not be achieved by the use of usual zinc metal. It was found that the electrolysis at -10C at a constant current of 60 mA/cm2 under nitrogen atmosphere was the optimum conditions in preparing of the EGZn/Naph. 2004 Conference or Workshop Item PeerReviewed application/pdf en http://eprints.utm.my/id/eprint/5242/1/AishahAbdulJalil2004_DeterminationOfOptimumConditions.pdf Abdul Jalil, Aishah and Kurono, Nobuhito and Tokuda, Masao (2004) Determination of optimum conditions in preparing highly reactive electrogenerated zinc by gas chromatograph. In: Simposium Kimia Analisis Malaysia Ke-17 (SKAM-17), 24-26 Ogos 2004, Swiss-Garden Resort, Pantai Balok, Kuantan. (Submitted)
institution Universiti Teknologi Malaysia
building UTM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Teknologi Malaysia
content_source UTM Institutional Repository
url_provider http://eprints.utm.my/
language English
topic T Technology (General)
spellingShingle T Technology (General)
Abdul Jalil, Aishah
Kurono, Nobuhito
Tokuda, Masao
Determination of optimum conditions in preparing highly reactive electrogenerated zinc by gas chromatograph
description Highly reactive electrogenerated zinc metal (EGZn/Naph) was readily prepared by electrolysis of a DMF solution cotaining naphthalene and a supporting electrolyte in a one-compartment cell fitted with a platinum cathode and a zinc anode. The reactivity of this EGZn/Naph elucidated by an efficient transformation of ethyl 2-bromolbutanoate as a model substrate into the corresponding organozinc compound, which can not be achieved by the use of usual zinc metal. It was found that the electrolysis at -10C at a constant current of 60 mA/cm2 under nitrogen atmosphere was the optimum conditions in preparing of the EGZn/Naph.
format Conference or Workshop Item
author Abdul Jalil, Aishah
Kurono, Nobuhito
Tokuda, Masao
author_facet Abdul Jalil, Aishah
Kurono, Nobuhito
Tokuda, Masao
author_sort Abdul Jalil, Aishah
title Determination of optimum conditions in preparing highly reactive electrogenerated zinc by gas chromatograph
title_short Determination of optimum conditions in preparing highly reactive electrogenerated zinc by gas chromatograph
title_full Determination of optimum conditions in preparing highly reactive electrogenerated zinc by gas chromatograph
title_fullStr Determination of optimum conditions in preparing highly reactive electrogenerated zinc by gas chromatograph
title_full_unstemmed Determination of optimum conditions in preparing highly reactive electrogenerated zinc by gas chromatograph
title_sort determination of optimum conditions in preparing highly reactive electrogenerated zinc by gas chromatograph
publishDate 2004
url http://eprints.utm.my/id/eprint/5242/1/AishahAbdulJalil2004_DeterminationOfOptimumConditions.pdf
http://eprints.utm.my/id/eprint/5242/
_version_ 1643644268886097920
score 13.211869

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