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Efficient fixation of carbon dioxide by electrolysis - Facile synthesis of useful carboxylic acids

Electrochemical fixation of an atmospheric pressure of carbon dioxide to organic compounds is a useful and attractive method for a synthesis of various carboxylic acids. Electrochemical fixation of carbon dioxide, electrochemical carboxylation, to organic halides, organic triflates, alkenes, aromati...

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Main Author: Tokuda, Masao
Format: Conference or Workshop Item
Language:English
Published: 2006
Subjects:
TP Chemical technology
Online Access:http://eprints.utm.my/id/eprint/358/1/MasaoTokuda2006_Efficientfixationofcarbondioxide.pdf
http://eprints.utm.my/id/eprint/358/
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spelling my.utm.3582015-08-12T03:35:57Z http://eprints.utm.my/id/eprint/358/ Efficient fixation of carbon dioxide by electrolysis - Facile synthesis of useful carboxylic acids Tokuda, Masao TP Chemical technology Electrochemical fixation of an atmospheric pressure of carbon dioxide to organic compounds is a useful and attractive method for a synthesis of various carboxylic acids. Electrochemical fixation of carbon dioxide, electrochemical carboxylation, to organic halides, organic triflates, alkenes, aromatic compounds and carbonyl compounds can readily take place in the presence of an atmospheric pressure of carbon dioxide to give the corresponding carboxylic acids in high yields when a sacrificial anode such as magnesium or aluminum is used in the electrolysis. The electrochemical carboxylation of vinyl bromides was successfully applied to a synthesis of the precursor of non-steroidal anti-inflammatory agents such as ibuprofen and naproxen. On the other hand, supercritical carbon dioxide (scCO2) has significant potential as an environmentally benign solvent in organic synthesis and it could be used both as a solvent and a reagent in these electrochemical carboxylations by using a small amount of co-solvent. 2006-07 Conference or Workshop Item PeerReviewed application/pdf en http://eprints.utm.my/id/eprint/358/1/MasaoTokuda2006_Efficientfixationofcarbondioxide.pdf Tokuda, Masao (2006) Efficient fixation of carbon dioxide by electrolysis - Facile synthesis of useful carboxylic acids. In: 1st International Conference on Natural Resources Engineering & Technology 2006, 24-25th July 2006, Putrajaya, Malaysia.
institution Universiti Teknologi Malaysia
building UTM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Teknologi Malaysia
content_source UTM Institutional Repository
url_provider http://eprints.utm.my/
language English
topic TP Chemical technology
spellingShingle TP Chemical technology
Tokuda, Masao
Efficient fixation of carbon dioxide by electrolysis - Facile synthesis of useful carboxylic acids
description Electrochemical fixation of an atmospheric pressure of carbon dioxide to organic compounds is a useful and attractive method for a synthesis of various carboxylic acids. Electrochemical fixation of carbon dioxide, electrochemical carboxylation, to organic halides, organic triflates, alkenes, aromatic compounds and carbonyl compounds can readily take place in the presence of an atmospheric pressure of carbon dioxide to give the corresponding carboxylic acids in high yields when a sacrificial anode such as magnesium or aluminum is used in the electrolysis. The electrochemical carboxylation of vinyl bromides was successfully applied to a synthesis of the precursor of non-steroidal anti-inflammatory agents such as ibuprofen and naproxen. On the other hand, supercritical carbon dioxide (scCO2) has significant potential as an environmentally benign solvent in organic synthesis and it could be used both as a solvent and a reagent in these electrochemical carboxylations by using a small amount of co-solvent.
format Conference or Workshop Item
author Tokuda, Masao
author_facet Tokuda, Masao
author_sort Tokuda, Masao
title Efficient fixation of carbon dioxide by electrolysis - Facile synthesis of useful carboxylic acids
title_short Efficient fixation of carbon dioxide by electrolysis - Facile synthesis of useful carboxylic acids
title_full Efficient fixation of carbon dioxide by electrolysis - Facile synthesis of useful carboxylic acids
title_fullStr Efficient fixation of carbon dioxide by electrolysis - Facile synthesis of useful carboxylic acids
title_full_unstemmed Efficient fixation of carbon dioxide by electrolysis - Facile synthesis of useful carboxylic acids
title_sort efficient fixation of carbon dioxide by electrolysis - facile synthesis of useful carboxylic acids
publishDate 2006
url http://eprints.utm.my/id/eprint/358/1/MasaoTokuda2006_Efficientfixationofcarbondioxide.pdf
http://eprints.utm.my/id/eprint/358/
_version_ 1643643083891408896
score 13.211869

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