Staff View: Synthesis and spectroscopic characterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT): X-ray crystal structure of [PhSnCl2(BPCT)]

Synthesis and spectroscopic characterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT): X-ray crystal structure of [PhSnCl2(BPCT)]

The reaction of 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone [HBPCT, (1)] ligand with organotin(IV) chloride(s) lead to the formation of three new organotin(IV) complexes: [MeSnCl2(BPCT)] (2), [PhSnCl2(BPCT)] (3) and [Ph2SnCl(BPCT)] (4). The ligand (1) and its organotin(IV) complexes (2-4) hav...

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Main Authors:	Shamsuddin, Mustaffa, Affan, M. A., Salam, M. A., Ahmad, Fasihuddin, Ismail, J., Ali, Hapipah M.
Format:	Article
Published:	Elsevier B. V. 2011
Subjects:	QD Chemistry
Online Access:	http://eprints.utm.my/id/eprint/29421/ http://dx.doi.org/10.1016/j.ica.2010.11.002
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spelling	my.utm.294212022-01-31T08:41:23Z http://eprints.utm.my/id/eprint/29421/ Synthesis and spectroscopic characterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT): X-ray crystal structure of [PhSnCl2(BPCT)] Shamsuddin, Mustaffa Affan, M. A. Salam, M. A. Ahmad, Fasihuddin Ismail, J. Ali, Hapipah M. QD Chemistry The reaction of 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone [HBPCT, (1)] ligand with organotin(IV) chloride(s) lead to the formation of three new organotin(IV) complexes: [MeSnCl2(BPCT)] (2), [PhSnCl2(BPCT)] (3) and [Ph2SnCl(BPCT)] (4). The ligand (1) and its organotin(IV) complexes (2-4) have been synthesized and characterized by CHN analyses, molar conductivity, UV-Vis, FT-IR and H-1 NMR spectral studies. The single crystal X-ray diffraction studies indicated that [PhSnCl2(BPCT)] (3) is six coordinated and adopts strongly a distorted octahedral configuration with the coordination through pyridine-N, azomethine-N and thiolato-S atoms of the ligand. The crystal system of [PhSnCl2(BPCT)] (3) is orthorhombic with space group P2ac2n and the unit cell dimensions: a = 28.1363(5) angstrom, b = 9.5970(2) angstrom, c = 9.4353(2) angstrom. Elsevier B. V. 2011-01-30 Article PeerReviewed Shamsuddin, Mustaffa and Affan, M. A. and Salam, M. A. and Ahmad, Fasihuddin and Ismail, J. and Ali, Hapipah M. (2011) Synthesis and spectroscopic characterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT): X-ray crystal structure of [PhSnCl2(BPCT)]. Inorganica Chimica Acta, 366 (1). pp. 227-232. ISSN 0020-1693 http://dx.doi.org/10.1016/j.ica.2010.11.002 DOI:10.1016/j.ica.2010.11.002
institution	Universiti Teknologi Malaysia
building	UTM Library
collection	Institutional Repository
continent	Asia
country	Malaysia
content_provider	Universiti Teknologi Malaysia
content_source	UTM Institutional Repository
url_provider	http://eprints.utm.my/
topic	QD Chemistry
spellingShingle	QD Chemistry Shamsuddin, Mustaffa Affan, M. A. Salam, M. A. Ahmad, Fasihuddin Ismail, J. Ali, Hapipah M. Synthesis and spectroscopic characterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT): X-ray crystal structure of [PhSnCl2(BPCT)]
description	The reaction of 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone [HBPCT, (1)] ligand with organotin(IV) chloride(s) lead to the formation of three new organotin(IV) complexes: [MeSnCl2(BPCT)] (2), [PhSnCl2(BPCT)] (3) and [Ph2SnCl(BPCT)] (4). The ligand (1) and its organotin(IV) complexes (2-4) have been synthesized and characterized by CHN analyses, molar conductivity, UV-Vis, FT-IR and H-1 NMR spectral studies. The single crystal X-ray diffraction studies indicated that [PhSnCl2(BPCT)] (3) is six coordinated and adopts strongly a distorted octahedral configuration with the coordination through pyridine-N, azomethine-N and thiolato-S atoms of the ligand. The crystal system of [PhSnCl2(BPCT)] (3) is orthorhombic with space group P2ac2n and the unit cell dimensions: a = 28.1363(5) angstrom, b = 9.5970(2) angstrom, c = 9.4353(2) angstrom.
format	Article
author	Shamsuddin, Mustaffa Affan, M. A. Salam, M. A. Ahmad, Fasihuddin Ismail, J. Ali, Hapipah M.
author_facet	Shamsuddin, Mustaffa Affan, M. A. Salam, M. A. Ahmad, Fasihuddin Ismail, J. Ali, Hapipah M.
author_sort	Shamsuddin, Mustaffa
title	Synthesis and spectroscopic characterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT): X-ray crystal structure of [PhSnCl2(BPCT)]
title_short	Synthesis and spectroscopic characterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT): X-ray crystal structure of [PhSnCl2(BPCT)]
title_full	Synthesis and spectroscopic characterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT): X-ray crystal structure of [PhSnCl2(BPCT)]
title_fullStr	Synthesis and spectroscopic characterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT): X-ray crystal structure of [PhSnCl2(BPCT)]
title_full_unstemmed	Synthesis and spectroscopic characterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT): X-ray crystal structure of [PhSnCl2(BPCT)]
title_sort	synthesis and spectroscopic characterization of organotin(iv) complexes with 2-benzoylpyridine-n(4)-cyclohexylthiosemicarbazone (hbpct): x-ray crystal structure of [phsncl2(bpct)]
publisher	Elsevier B. V.
publishDate	2011
url	http://eprints.utm.my/id/eprint/29421/ http://dx.doi.org/10.1016/j.ica.2010.11.002
_version_	1724073264174596096
score	13.211869

Synthesis and spectroscopic characterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT): X-ray crystal structure of [PhSnCl2(BPCT)]

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