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Controlling the critical parameters of ultrasonication to affect the dispersion state, isolation, and chiral nematic assembly of cellulose nanocrystals

Cellulose nanocrystals (CNCs) are typically extracted from plants and present a range of opto-mechanical properties that warrant their use for the fabrication of sustainable materials. While their commercialization is ongoing, their sustainable extraction at large scale is still being optimized. Ult...

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Main Authors: Robertus Wahyu N. Nugroho, Robertus Wahyu N. Nugroho, Tardy, Blaise L., Eldin, Sayed M., Rushdan, Ahmad Ilyas, Melbi Mahardika, Melbi Mahardika, Nanang Masruchin, Nanang Masruchin
Format: Article
Language:English
Published: Elsevier B.V. 2023
Subjects:
Q Science (General)
Online Access:http://eprints.utm.my/107487/1/AhmadIlyasRushdan2023_ControllingtheCriticalParametersofUltrasonication.pdf
http://eprints.utm.my/107487/
http://dx.doi.org/10.1016/j.ultsonch.2023.106581
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spelling my.utm.1074872024-09-23T03:05:51Z http://eprints.utm.my/107487/ Controlling the critical parameters of ultrasonication to affect the dispersion state, isolation, and chiral nematic assembly of cellulose nanocrystals Robertus Wahyu N. Nugroho, Robertus Wahyu N. Nugroho Tardy, Blaise L. Eldin, Sayed M. Rushdan, Ahmad Ilyas Melbi Mahardika, Melbi Mahardika Nanang Masruchin, Nanang Masruchin Q Science (General) Cellulose nanocrystals (CNCs) are typically extracted from plants and present a range of opto-mechanical properties that warrant their use for the fabrication of sustainable materials. While their commercialization is ongoing, their sustainable extraction at large scale is still being optimized. Ultrasonication is a well-established and routinely used technology for (re-) dispersing and/or isolating plant-based CNCs without the need for additional reagents or chemical processes. Several critical ultrasonication parameters, such as time, amplitude, and energy input, play dominant roles in reducing the particle size and altering the morphology of CNCs. Interestingly, this technology can be coupled with other methods to generate moderate and high yields of CNCs. Besides, the ultrasonics treatment also has a significant impact on the dispersion state and the surface chemistry of CNCs. Accordingly, their ability to self-assemble into liquid crystals and subsequent superstructures can, for example, imbue materials with finely tuned structural colors. This article gives an overview of the primary functions arising from the ultrasonication parameters for stabilizing CNCs, producing CNCs in combination with other promising methods, and highlighting examples where the design of photonic materials using nanocrystal-based celluloses is substantially impacted. Elsevier B.V. 2023-10 Article PeerReviewed application/pdf en http://eprints.utm.my/107487/1/AhmadIlyasRushdan2023_ControllingtheCriticalParametersofUltrasonication.pdf Robertus Wahyu N. Nugroho, Robertus Wahyu N. Nugroho and Tardy, Blaise L. and Eldin, Sayed M. and Rushdan, Ahmad Ilyas and Melbi Mahardika, Melbi Mahardika and Nanang Masruchin, Nanang Masruchin (2023) Controlling the critical parameters of ultrasonication to affect the dispersion state, isolation, and chiral nematic assembly of cellulose nanocrystals. Ultrasonics Sonochemistry, 99 (NA). pp. 1-21. ISSN 1350-4177 http://dx.doi.org/10.1016/j.ultsonch.2023.106581 DOI:10.1016/j.ultsonch.2023.106581
institution Universiti Teknologi Malaysia
building UTM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Teknologi Malaysia
content_source UTM Institutional Repository
url_provider http://eprints.utm.my/
language English
topic Q Science (General)
spellingShingle Q Science (General)
Robertus Wahyu N. Nugroho, Robertus Wahyu N. Nugroho
Tardy, Blaise L.
Eldin, Sayed M.
Rushdan, Ahmad Ilyas
Melbi Mahardika, Melbi Mahardika
Nanang Masruchin, Nanang Masruchin
Controlling the critical parameters of ultrasonication to affect the dispersion state, isolation, and chiral nematic assembly of cellulose nanocrystals
description Cellulose nanocrystals (CNCs) are typically extracted from plants and present a range of opto-mechanical properties that warrant their use for the fabrication of sustainable materials. While their commercialization is ongoing, their sustainable extraction at large scale is still being optimized. Ultrasonication is a well-established and routinely used technology for (re-) dispersing and/or isolating plant-based CNCs without the need for additional reagents or chemical processes. Several critical ultrasonication parameters, such as time, amplitude, and energy input, play dominant roles in reducing the particle size and altering the morphology of CNCs. Interestingly, this technology can be coupled with other methods to generate moderate and high yields of CNCs. Besides, the ultrasonics treatment also has a significant impact on the dispersion state and the surface chemistry of CNCs. Accordingly, their ability to self-assemble into liquid crystals and subsequent superstructures can, for example, imbue materials with finely tuned structural colors. This article gives an overview of the primary functions arising from the ultrasonication parameters for stabilizing CNCs, producing CNCs in combination with other promising methods, and highlighting examples where the design of photonic materials using nanocrystal-based celluloses is substantially impacted.
format Article
author Robertus Wahyu N. Nugroho, Robertus Wahyu N. Nugroho
Tardy, Blaise L.
Eldin, Sayed M.
Rushdan, Ahmad Ilyas
Melbi Mahardika, Melbi Mahardika
Nanang Masruchin, Nanang Masruchin
author_facet Robertus Wahyu N. Nugroho, Robertus Wahyu N. Nugroho
Tardy, Blaise L.
Eldin, Sayed M.
Rushdan, Ahmad Ilyas
Melbi Mahardika, Melbi Mahardika
Nanang Masruchin, Nanang Masruchin
author_sort Robertus Wahyu N. Nugroho, Robertus Wahyu N. Nugroho
title Controlling the critical parameters of ultrasonication to affect the dispersion state, isolation, and chiral nematic assembly of cellulose nanocrystals
title_short Controlling the critical parameters of ultrasonication to affect the dispersion state, isolation, and chiral nematic assembly of cellulose nanocrystals
title_full Controlling the critical parameters of ultrasonication to affect the dispersion state, isolation, and chiral nematic assembly of cellulose nanocrystals
title_fullStr Controlling the critical parameters of ultrasonication to affect the dispersion state, isolation, and chiral nematic assembly of cellulose nanocrystals
title_full_unstemmed Controlling the critical parameters of ultrasonication to affect the dispersion state, isolation, and chiral nematic assembly of cellulose nanocrystals
title_sort controlling the critical parameters of ultrasonication to affect the dispersion state, isolation, and chiral nematic assembly of cellulose nanocrystals
publisher Elsevier B.V.
publishDate 2023
url http://eprints.utm.my/107487/1/AhmadIlyasRushdan2023_ControllingtheCriticalParametersofUltrasonication.pdf
http://eprints.utm.my/107487/
http://dx.doi.org/10.1016/j.ultsonch.2023.106581
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score 13.211869

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