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Recent trend of metal promoter role for CO2 hydrogenation to C1 and C2+ products

CO2 hydrogenation as sustainable route for generation of value-added carbon feedstock is identified as green pathway for mitigation of greenhouse gasses emission. CO2 methanation is one of the promising solutions, which only requires reactions at atmospheric pressure while utilizing metal catalysts...

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Main Authors: Novia Amalia Sholeha, Novia Amalia Sholeha, Holilah, Holilah, Bahruji, Hasliza, Ayub, Athirah, Nurul Widiastuti, Nurul Widiastuti, Ratna Ediati, Ratna Ediati, Abdul Jalil, Aishah, Maria Ulfa, Maria Ulfa, Nanang Masruchin, Nanang Masruchin, Reva Edra Nugraha, Reva Edra Nugraha, Didik Prasetyoko, Didik Prasetyoko
Format: Article
Language:English
Published: Elsevier B.V. 2023
Subjects:
Q Science (General)
Online Access:http://eprints.utm.my/107137/1/AishahAbdulJalil2023_RecentTrendofMetalPromoterRole.pdf
http://eprints.utm.my/107137/
http://dx.doi.org/10.1016/j.sajce.2023.01.002
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spelling my.utm.1071372024-08-28T07:10:29Z http://eprints.utm.my/107137/ Recent trend of metal promoter role for CO2 hydrogenation to C1 and C2+ products Novia Amalia Sholeha, Novia Amalia Sholeha Holilah, Holilah Bahruji, Hasliza Ayub, Athirah Nurul Widiastuti, Nurul Widiastuti Ratna Ediati, Ratna Ediati Abdul Jalil, Aishah Maria Ulfa, Maria Ulfa Nanang Masruchin, Nanang Masruchin Reva Edra Nugraha, Reva Edra Nugraha Didik Prasetyoko, Didik Prasetyoko Q Science (General) CO2 hydrogenation as sustainable route for generation of value-added carbon feedstock is identified as green pathway for mitigation of greenhouse gasses emission. CO2 methanation is one of the promising solutions, which only requires reactions at atmospheric pressure while utilizing metal catalysts to overcome kinetic limitations. Metal catalysts can be promoted to alter reducibities, CO2 adsorption capacities, and H2single bondCO2 dissociation potential. The role of metal promoter such as rare earth elements (Ce, Mn, Co, and La) and alkali and alkali earth metal (Li, Na, Ca, and K) will be discussed within the scope of CO2 methanation. The aspect of catalysts modification towards hydrogen dissociation potential and surface oxygen vacancy will be emphasized to enhance selectivity for methane. Another pathway for CO2 hydrogenation is via further conversion into longer chain molecules such as olefin and ethanol. The benefit of metal promoter will be discussed in this review on the effect towards promoting Csingle bondC coupling reaction for producing longer chain alcohol and light olefin. The strategies to develop active catalysts for the coupling reaction of Csingle bondC will be emphasized with the promoter introduction. For the hydrogenation of CO2 to longer chain molecules, the main metal catalysts Ni, Pd, Rh, and Co, and their modification with promoter such as Ga, Cu, and alkali metal Na, K will be discussed. A critical analysis of the CO2 methanation mechanism and further Csingle bondC reaction to longer chain molecules will be discussed, particularly the effect of metal promoters to stabilize the intermediate and maneuver the catalytic reaction pathway into the desired products. Elsevier B.V. 2023-04 Article PeerReviewed application/pdf en http://eprints.utm.my/107137/1/AishahAbdulJalil2023_RecentTrendofMetalPromoterRole.pdf Novia Amalia Sholeha, Novia Amalia Sholeha and Holilah, Holilah and Bahruji, Hasliza and Ayub, Athirah and Nurul Widiastuti, Nurul Widiastuti and Ratna Ediati, Ratna Ediati and Abdul Jalil, Aishah and Maria Ulfa, Maria Ulfa and Nanang Masruchin, Nanang Masruchin and Reva Edra Nugraha, Reva Edra Nugraha and Didik Prasetyoko, Didik Prasetyoko (2023) Recent trend of metal promoter role for CO2 hydrogenation to C1 and C2+ products. South African Journal of Chemical Engineering, 44 (NA). pp. 14-30. ISSN 1026-9185 http://dx.doi.org/10.1016/j.sajce.2023.01.002 DOI:10.1016/j.sajce.2023.01.002
institution Universiti Teknologi Malaysia
building UTM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Teknologi Malaysia
content_source UTM Institutional Repository
url_provider http://eprints.utm.my/
language English
topic Q Science (General)
spellingShingle Q Science (General)
Novia Amalia Sholeha, Novia Amalia Sholeha
Holilah, Holilah
Bahruji, Hasliza
Ayub, Athirah
Nurul Widiastuti, Nurul Widiastuti
Ratna Ediati, Ratna Ediati
Abdul Jalil, Aishah
Maria Ulfa, Maria Ulfa
Nanang Masruchin, Nanang Masruchin
Reva Edra Nugraha, Reva Edra Nugraha
Didik Prasetyoko, Didik Prasetyoko
Recent trend of metal promoter role for CO2 hydrogenation to C1 and C2+ products
description CO2 hydrogenation as sustainable route for generation of value-added carbon feedstock is identified as green pathway for mitigation of greenhouse gasses emission. CO2 methanation is one of the promising solutions, which only requires reactions at atmospheric pressure while utilizing metal catalysts to overcome kinetic limitations. Metal catalysts can be promoted to alter reducibities, CO2 adsorption capacities, and H2single bondCO2 dissociation potential. The role of metal promoter such as rare earth elements (Ce, Mn, Co, and La) and alkali and alkali earth metal (Li, Na, Ca, and K) will be discussed within the scope of CO2 methanation. The aspect of catalysts modification towards hydrogen dissociation potential and surface oxygen vacancy will be emphasized to enhance selectivity for methane. Another pathway for CO2 hydrogenation is via further conversion into longer chain molecules such as olefin and ethanol. The benefit of metal promoter will be discussed in this review on the effect towards promoting Csingle bondC coupling reaction for producing longer chain alcohol and light olefin. The strategies to develop active catalysts for the coupling reaction of Csingle bondC will be emphasized with the promoter introduction. For the hydrogenation of CO2 to longer chain molecules, the main metal catalysts Ni, Pd, Rh, and Co, and their modification with promoter such as Ga, Cu, and alkali metal Na, K will be discussed. A critical analysis of the CO2 methanation mechanism and further Csingle bondC reaction to longer chain molecules will be discussed, particularly the effect of metal promoters to stabilize the intermediate and maneuver the catalytic reaction pathway into the desired products.
format Article
author Novia Amalia Sholeha, Novia Amalia Sholeha
Holilah, Holilah
Bahruji, Hasliza
Ayub, Athirah
Nurul Widiastuti, Nurul Widiastuti
Ratna Ediati, Ratna Ediati
Abdul Jalil, Aishah
Maria Ulfa, Maria Ulfa
Nanang Masruchin, Nanang Masruchin
Reva Edra Nugraha, Reva Edra Nugraha
Didik Prasetyoko, Didik Prasetyoko
author_facet Novia Amalia Sholeha, Novia Amalia Sholeha
Holilah, Holilah
Bahruji, Hasliza
Ayub, Athirah
Nurul Widiastuti, Nurul Widiastuti
Ratna Ediati, Ratna Ediati
Abdul Jalil, Aishah
Maria Ulfa, Maria Ulfa
Nanang Masruchin, Nanang Masruchin
Reva Edra Nugraha, Reva Edra Nugraha
Didik Prasetyoko, Didik Prasetyoko
author_sort Novia Amalia Sholeha, Novia Amalia Sholeha
title Recent trend of metal promoter role for CO2 hydrogenation to C1 and C2+ products
title_short Recent trend of metal promoter role for CO2 hydrogenation to C1 and C2+ products
title_full Recent trend of metal promoter role for CO2 hydrogenation to C1 and C2+ products
title_fullStr Recent trend of metal promoter role for CO2 hydrogenation to C1 and C2+ products
title_full_unstemmed Recent trend of metal promoter role for CO2 hydrogenation to C1 and C2+ products
title_sort recent trend of metal promoter role for co2 hydrogenation to c1 and c2+ products
publisher Elsevier B.V.
publishDate 2023
url http://eprints.utm.my/107137/1/AishahAbdulJalil2023_RecentTrendofMetalPromoterRole.pdf
http://eprints.utm.my/107137/
http://dx.doi.org/10.1016/j.sajce.2023.01.002
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score 13.211869

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