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Metal-organic framework nanopesticide carrier for accurate pesticide delivery and decrement of groundwater pollution.

The motivation of the present study was a synthesis of the nanocomposites of UiO-66@ZnO/Biochar to embed carbendazim (CBZ) pesticide inside its porous structures for smart spraying and cleaner production. CBZ@UiO-66@ZnO/Biochar had the purpose of not only smart spraying to avoid releasing a large am...

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Main Authors:	Nguyen, Hoang Ly, Nguyen, Binh Nguyen, Huynh, Nhu Tran, Thi Thuy, Hang Hoang, Joo, Sang-Woo, Vasseghian, Yasser, Kamyab, Hesam, Chelliapan, Shreeshivadasan, Jirí, Jaromír Klemeš
Format:	Article
Published:	Elsevier Ltd. 2023
Subjects:	QD Chemistry
Online Access:	http://eprints.utm.my/106353/ https://doi.org/10.1016/j.jclepro.2023.136809
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id	my.utm.106353
record_format	eprints
spelling	my.utm.1063532024-06-29T06:57:31Z http://eprints.utm.my/106353/ Metal-organic framework nanopesticide carrier for accurate pesticide delivery and decrement of groundwater pollution. Nguyen, Hoang Ly Nguyen, Binh Nguyen Huynh, Nhu Tran Thi Thuy, Hang Hoang Joo, Sang-Woo Vasseghian, Yasser Kamyab, Hesam Chelliapan, Shreeshivadasan Jirí, Jaromír Klemeš QD Chemistry The motivation of the present study was a synthesis of the nanocomposites of UiO-66@ZnO/Biochar to embed carbendazim (CBZ) pesticide inside its porous structures for smart spraying and cleaner production. CBZ@UiO-66@ZnO/Biochar had the purpose of not only smart spraying to avoid releasing a large amount of CBZ into the groundwater but also of accurately delivering the CBZ pesticide to the desired grass/plant. High-resolution electron microscopy was introduced to characterise the morphologies of prepared composites with spatial elemental distribution mapping. X-ray diffraction (XRD) patterns and micro-Raman spectroscopy were employed for the crystal structures of UiO-66@ZnO. Spectral UV–Vis and Fourier transform-infrared (FT-IR) tools were utilized to estimate the UiO-66@ZnO/Biochar-based adsorption and release of CBZ into the dimethyl sulfoxide (DMSO)-water mixture. Our results indicated that the adsorption capacities of CBZ into the DMSO-water mixture onto UiO-66@ZnO and UiO-66@ZnO/Biochar nanocomposites were obtained at 68.8% and 72.6%. The half-life of photodegradation rate constants for CBZ@UiO-66@ZnO/Biochar was found to be 12.3 times longer than that of free CBZ. Notably, CBZ@UiO-66@ZnO/Biochar inhibitory concentration 50% (IC50) determination was estimated at 73.8 μg/L and 209 μg/L for Fusarium oxysporum and Aspergillus niger. This work provides a comprehensive experimental scheme for the chemisorption process of CBZ onto the UiO-66@ZnO/Biochar composite materials and the nanopesticide applications in sustainable agriculture towards cleaner productions. Elsevier Ltd. 2023-05-20 Article PeerReviewed Nguyen, Hoang Ly and Nguyen, Binh Nguyen and Huynh, Nhu Tran and Thi Thuy, Hang Hoang and Joo, Sang-Woo and Vasseghian, Yasser and Kamyab, Hesam and Chelliapan, Shreeshivadasan and Jirí, Jaromír Klemeš (2023) Metal-organic framework nanopesticide carrier for accurate pesticide delivery and decrement of groundwater pollution. Journal of Cleaner Production, 402 (136809). NA-NA. ISSN 0959-6526 https://doi.org/10.1016/j.jclepro.2023.136809 DOI: 10.1016/j.jclepro.2023.136809
institution	Universiti Teknologi Malaysia
building	UTM Library
collection	Institutional Repository
continent	Asia
country	Malaysia
content_provider	Universiti Teknologi Malaysia
content_source	UTM Institutional Repository
url_provider	http://eprints.utm.my/
topic	QD Chemistry
spellingShingle	QD Chemistry Nguyen, Hoang Ly Nguyen, Binh Nguyen Huynh, Nhu Tran Thi Thuy, Hang Hoang Joo, Sang-Woo Vasseghian, Yasser Kamyab, Hesam Chelliapan, Shreeshivadasan Jirí, Jaromír Klemeš Metal-organic framework nanopesticide carrier for accurate pesticide delivery and decrement of groundwater pollution.
description	The motivation of the present study was a synthesis of the nanocomposites of UiO-66@ZnO/Biochar to embed carbendazim (CBZ) pesticide inside its porous structures for smart spraying and cleaner production. CBZ@UiO-66@ZnO/Biochar had the purpose of not only smart spraying to avoid releasing a large amount of CBZ into the groundwater but also of accurately delivering the CBZ pesticide to the desired grass/plant. High-resolution electron microscopy was introduced to characterise the morphologies of prepared composites with spatial elemental distribution mapping. X-ray diffraction (XRD) patterns and micro-Raman spectroscopy were employed for the crystal structures of UiO-66@ZnO. Spectral UV–Vis and Fourier transform-infrared (FT-IR) tools were utilized to estimate the UiO-66@ZnO/Biochar-based adsorption and release of CBZ into the dimethyl sulfoxide (DMSO)-water mixture. Our results indicated that the adsorption capacities of CBZ into the DMSO-water mixture onto UiO-66@ZnO and UiO-66@ZnO/Biochar nanocomposites were obtained at 68.8% and 72.6%. The half-life of photodegradation rate constants for CBZ@UiO-66@ZnO/Biochar was found to be 12.3 times longer than that of free CBZ. Notably, CBZ@UiO-66@ZnO/Biochar inhibitory concentration 50% (IC50) determination was estimated at 73.8 μg/L and 209 μg/L for Fusarium oxysporum and Aspergillus niger. This work provides a comprehensive experimental scheme for the chemisorption process of CBZ onto the UiO-66@ZnO/Biochar composite materials and the nanopesticide applications in sustainable agriculture towards cleaner productions.
format	Article
author	Nguyen, Hoang Ly Nguyen, Binh Nguyen Huynh, Nhu Tran Thi Thuy, Hang Hoang Joo, Sang-Woo Vasseghian, Yasser Kamyab, Hesam Chelliapan, Shreeshivadasan Jirí, Jaromír Klemeš
author_facet	Nguyen, Hoang Ly Nguyen, Binh Nguyen Huynh, Nhu Tran Thi Thuy, Hang Hoang Joo, Sang-Woo Vasseghian, Yasser Kamyab, Hesam Chelliapan, Shreeshivadasan Jirí, Jaromír Klemeš
author_sort	Nguyen, Hoang Ly
title	Metal-organic framework nanopesticide carrier for accurate pesticide delivery and decrement of groundwater pollution.
title_short	Metal-organic framework nanopesticide carrier for accurate pesticide delivery and decrement of groundwater pollution.
title_full	Metal-organic framework nanopesticide carrier for accurate pesticide delivery and decrement of groundwater pollution.
title_fullStr	Metal-organic framework nanopesticide carrier for accurate pesticide delivery and decrement of groundwater pollution.
title_full_unstemmed	Metal-organic framework nanopesticide carrier for accurate pesticide delivery and decrement of groundwater pollution.
title_sort	metal-organic framework nanopesticide carrier for accurate pesticide delivery and decrement of groundwater pollution.
publisher	Elsevier Ltd.
publishDate	2023
url	http://eprints.utm.my/106353/ https://doi.org/10.1016/j.jclepro.2023.136809
_version_	1803334996035895296
score	13.211869

Metal-organic framework nanopesticide carrier for accurate pesticide delivery and decrement of groundwater pollution.

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