Immobilization of NanoFe3O4 onto fabric material through in situ co-precipitation as a flexible catalyst for humic acid degradation

Humic acid (HA) is a major component in dissolved natural organic matter (NOM) that is commonly found in natural water sources such as surface water and soil. Although HA is non-toxic, it is a precursor of carcinogenic and mutagenic disinfection by-products that will be generated when chlorine and c...

Full description

Saved in:
Bibliographic Details
Main Authors: Lee, Yit Kwan, Yeap, Swee Pin, Sum, Jing Yao, Abu Bakar, yu Haslija, Tan, Lian See, Abbas Jawad, Zeinab
Format: Article
Language:English
Published: Italian Association of Chemical Engineering - AIDIC 2023
Subjects:
Online Access:http://eprints.utm.my/105980/1/TanLianSee2023_ImmobilizationofNanoFe3O4ontoFabricMaterialthroughInSitu.pdf
http://eprints.utm.my/105980/
http://dx.doi.org/10.3303/CET23106169
Tags: Add Tag
No Tags, Be the first to tag this record!
id my.utm.105980
record_format eprints
spelling my.utm.1059802024-05-26T09:43:22Z http://eprints.utm.my/105980/ Immobilization of NanoFe3O4 onto fabric material through in situ co-precipitation as a flexible catalyst for humic acid degradation Lee, Yit Kwan Yeap, Swee Pin Sum, Jing Yao Abu Bakar, yu Haslija Tan, Lian See Abbas Jawad, Zeinab T Technology (General) Humic acid (HA) is a major component in dissolved natural organic matter (NOM) that is commonly found in natural water sources such as surface water and soil. Although HA is non-toxic, it is a precursor of carcinogenic and mutagenic disinfection by-products that will be generated when chlorine and chloramine are applied to disinfect water during the chlorination process. Hence, researchers have been investigating various strategies to remove HA from water sources and nanoparticles stood out as one of the preferred materials for the removal. However, owing to the tiny size of nanoparticles, the recycling, and removal of nanoparticles through sedimentation and centrifugation method is often time and energy-consuming. Therefore, this work set out to immobilize iron oxide nanoparticles (nanoFe3O4) onto fabric material to create a flexible catalyst that is feasible in degrading HA. The immobilization of nanoFe3O4 onto woven and non-woven fabrics was successfully done through in situ co-precipitation method. The flexible catalyst was found to be responsive to magnetic pull, which is one of the properties of nanoFe3O4 itself. On the other hand, scanning electron microscopy (SEM) images have verified the attachment of nanoFe3O4 was in an irregular pattern across the heterogeneous surface and it was grown on the fabric’s filament instead of being trapped between the pores of the fabric. Subsequently, the as-made flexible catalysts were tested and found to be feasible as it can degrade HA completely in 24 to 36 h. More importantly, the flexible catalyst can be removed easily in an instant with a negligible detachment of nanoparticles from the fabric material. While this preliminary result is promising, it is suggested that further study should be carried out to optimize the efficiency of this novel flexible catalyst on the degradation of HA. Italian Association of Chemical Engineering - AIDIC 2023 Article PeerReviewed application/pdf en http://eprints.utm.my/105980/1/TanLianSee2023_ImmobilizationofNanoFe3O4ontoFabricMaterialthroughInSitu.pdf Lee, Yit Kwan and Yeap, Swee Pin and Sum, Jing Yao and Abu Bakar, yu Haslija and Tan, Lian See and Abbas Jawad, Zeinab (2023) Immobilization of NanoFe3O4 onto fabric material through in situ co-precipitation as a flexible catalyst for humic acid degradation. Chemical Engineering Transactions, 106 (NA). pp. 1009-1014. ISSN 2283-9216 http://dx.doi.org/10.3303/CET23106169 DOI : 10.3303/CET23106169
institution Universiti Teknologi Malaysia
building UTM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Teknologi Malaysia
content_source UTM Institutional Repository
url_provider http://eprints.utm.my/
language English
topic T Technology (General)
spellingShingle T Technology (General)
Lee, Yit Kwan
Yeap, Swee Pin
Sum, Jing Yao
Abu Bakar, yu Haslija
Tan, Lian See
Abbas Jawad, Zeinab
Immobilization of NanoFe3O4 onto fabric material through in situ co-precipitation as a flexible catalyst for humic acid degradation
description Humic acid (HA) is a major component in dissolved natural organic matter (NOM) that is commonly found in natural water sources such as surface water and soil. Although HA is non-toxic, it is a precursor of carcinogenic and mutagenic disinfection by-products that will be generated when chlorine and chloramine are applied to disinfect water during the chlorination process. Hence, researchers have been investigating various strategies to remove HA from water sources and nanoparticles stood out as one of the preferred materials for the removal. However, owing to the tiny size of nanoparticles, the recycling, and removal of nanoparticles through sedimentation and centrifugation method is often time and energy-consuming. Therefore, this work set out to immobilize iron oxide nanoparticles (nanoFe3O4) onto fabric material to create a flexible catalyst that is feasible in degrading HA. The immobilization of nanoFe3O4 onto woven and non-woven fabrics was successfully done through in situ co-precipitation method. The flexible catalyst was found to be responsive to magnetic pull, which is one of the properties of nanoFe3O4 itself. On the other hand, scanning electron microscopy (SEM) images have verified the attachment of nanoFe3O4 was in an irregular pattern across the heterogeneous surface and it was grown on the fabric’s filament instead of being trapped between the pores of the fabric. Subsequently, the as-made flexible catalysts were tested and found to be feasible as it can degrade HA completely in 24 to 36 h. More importantly, the flexible catalyst can be removed easily in an instant with a negligible detachment of nanoparticles from the fabric material. While this preliminary result is promising, it is suggested that further study should be carried out to optimize the efficiency of this novel flexible catalyst on the degradation of HA.
format Article
author Lee, Yit Kwan
Yeap, Swee Pin
Sum, Jing Yao
Abu Bakar, yu Haslija
Tan, Lian See
Abbas Jawad, Zeinab
author_facet Lee, Yit Kwan
Yeap, Swee Pin
Sum, Jing Yao
Abu Bakar, yu Haslija
Tan, Lian See
Abbas Jawad, Zeinab
author_sort Lee, Yit Kwan
title Immobilization of NanoFe3O4 onto fabric material through in situ co-precipitation as a flexible catalyst for humic acid degradation
title_short Immobilization of NanoFe3O4 onto fabric material through in situ co-precipitation as a flexible catalyst for humic acid degradation
title_full Immobilization of NanoFe3O4 onto fabric material through in situ co-precipitation as a flexible catalyst for humic acid degradation
title_fullStr Immobilization of NanoFe3O4 onto fabric material through in situ co-precipitation as a flexible catalyst for humic acid degradation
title_full_unstemmed Immobilization of NanoFe3O4 onto fabric material through in situ co-precipitation as a flexible catalyst for humic acid degradation
title_sort immobilization of nanofe3o4 onto fabric material through in situ co-precipitation as a flexible catalyst for humic acid degradation
publisher Italian Association of Chemical Engineering - AIDIC
publishDate 2023
url http://eprints.utm.my/105980/1/TanLianSee2023_ImmobilizationofNanoFe3O4ontoFabricMaterialthroughInSitu.pdf
http://eprints.utm.my/105980/
http://dx.doi.org/10.3303/CET23106169
_version_ 1800714785835188224
score 13.211869