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A comparison study on performance of thin film composite membrane embedded with graphene oxide for acetaminophen, diclofenac and ibuprofen separation from waste water

Pharmaceuticals and personal care products (PPCPs) are one of the threats to water safety and security. These contaminants are hard to be removed due to toxicity and resistant to breakdown. In this study, thin film composite polypiperazine-amide membrane modified with graphene oxide (GO) was synthes...

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Main Authors: Ntone, Ellora Priscille Ndia, Abd. Rahman, Sunarti, Abu Samah, Rozaimi, Abdul Wahab, Mohamad Syafiq, Abbas Jawad, Zeinab, Hasbullah, Hasrinah
Format: Article
Published: Institution of Chemical Engineers 2023
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TP Chemical technology
Online Access:http://eprints.utm.my/105896/
http://dx.doi.org/10.1016/j.cherd.2023.05.023
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spelling my.utm.1058962024-05-26T08:57:33Z http://eprints.utm.my/105896/ A comparison study on performance of thin film composite membrane embedded with graphene oxide for acetaminophen, diclofenac and ibuprofen separation from waste water Ntone, Ellora Priscille Ndia Abd. Rahman, Sunarti Abu Samah, Rozaimi Abdul Wahab, Mohamad Syafiq Abbas Jawad, Zeinab Hasbullah, Hasrinah TP Chemical technology Pharmaceuticals and personal care products (PPCPs) are one of the threats to water safety and security. These contaminants are hard to be removed due to toxicity and resistant to breakdown. In this study, thin film composite polypiperazine-amide membrane modified with graphene oxide (GO) was synthesized as a rejection medium for this groups of contaminants. Acetaminophen (ACT), Diclofenac (DCF), and Ibuprofen (IBF) was selected as pharmaceutical pollutants and was rejected at different pH ranging from 4 to 9. ATR-FTIR, surface hydrophilicity, pure water permeability and rejection % was evaluated. The effect of GO on rejection showed that PES/GO-0.2 had the greatest hydrophilic effect, pure water permeability and rejection efficiency on all three drugs. The effect of pH on the membrane showed that DCF had the highest rejection (99.13%) at pH8–9, followed by IBF (95.78%) at pH 8–9, and lastly ACT (97.7%) at pH 7. Thus, thin film composite polypiperazine-amide membrane modified with graphene oxide can be effectively and sustainably applied in water treatment processes. Institution of Chemical Engineers 2023 Article PeerReviewed Ntone, Ellora Priscille Ndia and Abd. Rahman, Sunarti and Abu Samah, Rozaimi and Abdul Wahab, Mohamad Syafiq and Abbas Jawad, Zeinab and Hasbullah, Hasrinah (2023) A comparison study on performance of thin film composite membrane embedded with graphene oxide for acetaminophen, diclofenac and ibuprofen separation from waste water. Chemical Engineering Research and Design, 195 (NA). pp. 28-37. ISSN 0263-8762 http://dx.doi.org/10.1016/j.cherd.2023.05.023 DOI : 10.1016/j.cherd.2023.05.023
institution Universiti Teknologi Malaysia
building UTM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Teknologi Malaysia
content_source UTM Institutional Repository
url_provider http://eprints.utm.my/
topic TP Chemical technology
spellingShingle TP Chemical technology
Ntone, Ellora Priscille Ndia
Abd. Rahman, Sunarti
Abu Samah, Rozaimi
Abdul Wahab, Mohamad Syafiq
Abbas Jawad, Zeinab
Hasbullah, Hasrinah
A comparison study on performance of thin film composite membrane embedded with graphene oxide for acetaminophen, diclofenac and ibuprofen separation from waste water
description Pharmaceuticals and personal care products (PPCPs) are one of the threats to water safety and security. These contaminants are hard to be removed due to toxicity and resistant to breakdown. In this study, thin film composite polypiperazine-amide membrane modified with graphene oxide (GO) was synthesized as a rejection medium for this groups of contaminants. Acetaminophen (ACT), Diclofenac (DCF), and Ibuprofen (IBF) was selected as pharmaceutical pollutants and was rejected at different pH ranging from 4 to 9. ATR-FTIR, surface hydrophilicity, pure water permeability and rejection % was evaluated. The effect of GO on rejection showed that PES/GO-0.2 had the greatest hydrophilic effect, pure water permeability and rejection efficiency on all three drugs. The effect of pH on the membrane showed that DCF had the highest rejection (99.13%) at pH8–9, followed by IBF (95.78%) at pH 8–9, and lastly ACT (97.7%) at pH 7. Thus, thin film composite polypiperazine-amide membrane modified with graphene oxide can be effectively and sustainably applied in water treatment processes.
format Article
author Ntone, Ellora Priscille Ndia
Abd. Rahman, Sunarti
Abu Samah, Rozaimi
Abdul Wahab, Mohamad Syafiq
Abbas Jawad, Zeinab
Hasbullah, Hasrinah
author_facet Ntone, Ellora Priscille Ndia
Abd. Rahman, Sunarti
Abu Samah, Rozaimi
Abdul Wahab, Mohamad Syafiq
Abbas Jawad, Zeinab
Hasbullah, Hasrinah
author_sort Ntone, Ellora Priscille Ndia
title A comparison study on performance of thin film composite membrane embedded with graphene oxide for acetaminophen, diclofenac and ibuprofen separation from waste water
title_short A comparison study on performance of thin film composite membrane embedded with graphene oxide for acetaminophen, diclofenac and ibuprofen separation from waste water
title_full A comparison study on performance of thin film composite membrane embedded with graphene oxide for acetaminophen, diclofenac and ibuprofen separation from waste water
title_fullStr A comparison study on performance of thin film composite membrane embedded with graphene oxide for acetaminophen, diclofenac and ibuprofen separation from waste water
title_full_unstemmed A comparison study on performance of thin film composite membrane embedded with graphene oxide for acetaminophen, diclofenac and ibuprofen separation from waste water
title_sort comparison study on performance of thin film composite membrane embedded with graphene oxide for acetaminophen, diclofenac and ibuprofen separation from waste water
publisher Institution of Chemical Engineers
publishDate 2023
url http://eprints.utm.my/105896/
http://dx.doi.org/10.1016/j.cherd.2023.05.023
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score 13.211869

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