Radiation-induced admicellar graft polymerization of 2-hydroxyethyl methacrylate onto polyvinylidene fluoride membranes using an electron beam accelerator

The efficiency of admicellar graft polymerization in functionalizing polyvinylidene fluoride (PVDF) membranes was explored. The effect of 2-hydroxyethyl methacrylate (HEMA) concentration and the absorbed dose was investigated using a simultaneous method of radiation-induced graft polymerization. The...

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Main Authors: Azzian, Muhammad Irfan Mustaqim, Mohamad, Siti Fatahiyah, Abd. Rahim, Nik Muhamad Faris Hakimi, Abdul Manaf, Mohamad Amirul Aizat, Ramesh, Devi Durgaashini, Asogan, Thirunaukkarasu, Ismail, Nor Hafiza, Wan Salleh, Wan Norharyati
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Published: John Wiley and Sons Inc 2023
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Online Access:http://eprints.utm.my/105887/
http://dx.doi.org/10.1002/ceat.202300014
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spelling my.utm.1058872024-05-26T08:53:44Z http://eprints.utm.my/105887/ Radiation-induced admicellar graft polymerization of 2-hydroxyethyl methacrylate onto polyvinylidene fluoride membranes using an electron beam accelerator Azzian, Muhammad Irfan Mustaqim Mohamad, Siti Fatahiyah Abd. Rahim, Nik Muhamad Faris Hakimi Abdul Manaf, Mohamad Amirul Aizat Ramesh, Devi Durgaashini Asogan, Thirunaukkarasu Ismail, Nor Hafiza Wan Salleh, Wan Norharyati TP Chemical technology The efficiency of admicellar graft polymerization in functionalizing polyvinylidene fluoride (PVDF) membranes was explored. The effect of 2-hydroxyethyl methacrylate (HEMA) concentration and the absorbed dose was investigated using a simultaneous method of radiation-induced graft polymerization. The degree of grafting increased with raising the absorbed dose and HEMA concentration. The Fourier transform infrared (FTIR) peak for C–O stretch and the asymmetric and symmetric stretching of the C–O–C bridge, respectively, proved the presence of poly(2-hydroxyethyl methacrylate) (PHEMA) on the modified PVDF. As the grafting yield increased, rougher surfaces were observed. According to contact angle analysis, the grafted membrane with a higher grafting yield outperformed the low grafting yield membrane in terms of water flux and hydrophilicity. John Wiley and Sons Inc 2023 Article PeerReviewed Azzian, Muhammad Irfan Mustaqim and Mohamad, Siti Fatahiyah and Abd. Rahim, Nik Muhamad Faris Hakimi and Abdul Manaf, Mohamad Amirul Aizat and Ramesh, Devi Durgaashini and Asogan, Thirunaukkarasu and Ismail, Nor Hafiza and Wan Salleh, Wan Norharyati (2023) Radiation-induced admicellar graft polymerization of 2-hydroxyethyl methacrylate onto polyvinylidene fluoride membranes using an electron beam accelerator. Chemical Engineering and Technology, 46 (12). pp. 2617-2625. ISSN 0930-7516 http://dx.doi.org/10.1002/ceat.202300014 DOI : 10.1002/ceat.202300014
institution Universiti Teknologi Malaysia
building UTM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Teknologi Malaysia
content_source UTM Institutional Repository
url_provider http://eprints.utm.my/
topic TP Chemical technology
spellingShingle TP Chemical technology
Azzian, Muhammad Irfan Mustaqim
Mohamad, Siti Fatahiyah
Abd. Rahim, Nik Muhamad Faris Hakimi
Abdul Manaf, Mohamad Amirul Aizat
Ramesh, Devi Durgaashini
Asogan, Thirunaukkarasu
Ismail, Nor Hafiza
Wan Salleh, Wan Norharyati
Radiation-induced admicellar graft polymerization of 2-hydroxyethyl methacrylate onto polyvinylidene fluoride membranes using an electron beam accelerator
description The efficiency of admicellar graft polymerization in functionalizing polyvinylidene fluoride (PVDF) membranes was explored. The effect of 2-hydroxyethyl methacrylate (HEMA) concentration and the absorbed dose was investigated using a simultaneous method of radiation-induced graft polymerization. The degree of grafting increased with raising the absorbed dose and HEMA concentration. The Fourier transform infrared (FTIR) peak for C–O stretch and the asymmetric and symmetric stretching of the C–O–C bridge, respectively, proved the presence of poly(2-hydroxyethyl methacrylate) (PHEMA) on the modified PVDF. As the grafting yield increased, rougher surfaces were observed. According to contact angle analysis, the grafted membrane with a higher grafting yield outperformed the low grafting yield membrane in terms of water flux and hydrophilicity.
format Article
author Azzian, Muhammad Irfan Mustaqim
Mohamad, Siti Fatahiyah
Abd. Rahim, Nik Muhamad Faris Hakimi
Abdul Manaf, Mohamad Amirul Aizat
Ramesh, Devi Durgaashini
Asogan, Thirunaukkarasu
Ismail, Nor Hafiza
Wan Salleh, Wan Norharyati
author_facet Azzian, Muhammad Irfan Mustaqim
Mohamad, Siti Fatahiyah
Abd. Rahim, Nik Muhamad Faris Hakimi
Abdul Manaf, Mohamad Amirul Aizat
Ramesh, Devi Durgaashini
Asogan, Thirunaukkarasu
Ismail, Nor Hafiza
Wan Salleh, Wan Norharyati
author_sort Azzian, Muhammad Irfan Mustaqim
title Radiation-induced admicellar graft polymerization of 2-hydroxyethyl methacrylate onto polyvinylidene fluoride membranes using an electron beam accelerator
title_short Radiation-induced admicellar graft polymerization of 2-hydroxyethyl methacrylate onto polyvinylidene fluoride membranes using an electron beam accelerator
title_full Radiation-induced admicellar graft polymerization of 2-hydroxyethyl methacrylate onto polyvinylidene fluoride membranes using an electron beam accelerator
title_fullStr Radiation-induced admicellar graft polymerization of 2-hydroxyethyl methacrylate onto polyvinylidene fluoride membranes using an electron beam accelerator
title_full_unstemmed Radiation-induced admicellar graft polymerization of 2-hydroxyethyl methacrylate onto polyvinylidene fluoride membranes using an electron beam accelerator
title_sort radiation-induced admicellar graft polymerization of 2-hydroxyethyl methacrylate onto polyvinylidene fluoride membranes using an electron beam accelerator
publisher John Wiley and Sons Inc
publishDate 2023
url http://eprints.utm.my/105887/
http://dx.doi.org/10.1002/ceat.202300014
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