A study on the catalytic technology for reduction of naphthenic acid compound from acidic crude oil
The existence of naphthenic acid (NA) in acidic crude oil tends to corrode the oil refinery equipment. In this study, a catalytic deacidification reaction involving the deacidifying agent and the synthesised catalyst was aimed to eliminate NA from acidic crude oil. Diethanolamine-polyethylene glycol...
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my.utm.1038212023-11-27T06:28:49Z http://eprints.utm.my/103821/ A study on the catalytic technology for reduction of naphthenic acid compound from acidic crude oil Mohd. Shukri, Nurasmat Wan Abu Bakar, Wan Azelee Muhammad Reezhuan, Russman Wan Abdullah, Wan Nazwanie QD Chemistry The existence of naphthenic acid (NA) in acidic crude oil tends to corrode the oil refinery equipment. In this study, a catalytic deacidification reaction involving the deacidifying agent and the synthesised catalyst was aimed to eliminate NA from acidic crude oil. Diethanolamine-polyethylene glycol (DEA-PEG) was introduced as a deacidifying agent. The wet impregnation method was applied for synthesizing the calcium oxide catalyst doped by copper supported on alumina (Cu/Ca/Al2O3). The potential catalyst was characterised utilising field emission scanning electron microscopy-energy dispersive X-ray (FESEM-EDX), Brunauer-Emmett-Teller (BET), and X-ray diffraction spectroscopy (XRD). The parameters include deacidifying agent dosing, loading dopant ratio and catalyst calcination temperature were performed to enhance the catalytic deacidification process in this study. Data showed that the total acidic number (TAN) value for crude B met the PETRONAS requirement for the TAN value below one using 1500 mg/L of DEA-PEG assisted by Cu/Ca (10:90)/Al2O3 catalyst. 2022 Conference or Workshop Item PeerReviewed Mohd. Shukri, Nurasmat and Wan Abu Bakar, Wan Azelee and Muhammad Reezhuan, Russman and Wan Abdullah, Wan Nazwanie (2022) A study on the catalytic technology for reduction of naphthenic acid compound from acidic crude oil. In: 10th International Conference on X-Rays and Related Techniques in Research and Industry, ICXRI 2021, 18 August 2021 - 19 August 2021, Virtual, Online. http://dx.doi.org/10.4028/p-mwjz0x |
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QD Chemistry Mohd. Shukri, Nurasmat Wan Abu Bakar, Wan Azelee Muhammad Reezhuan, Russman Wan Abdullah, Wan Nazwanie A study on the catalytic technology for reduction of naphthenic acid compound from acidic crude oil |
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The existence of naphthenic acid (NA) in acidic crude oil tends to corrode the oil refinery equipment. In this study, a catalytic deacidification reaction involving the deacidifying agent and the synthesised catalyst was aimed to eliminate NA from acidic crude oil. Diethanolamine-polyethylene glycol (DEA-PEG) was introduced as a deacidifying agent. The wet impregnation method was applied for synthesizing the calcium oxide catalyst doped by copper supported on alumina (Cu/Ca/Al2O3). The potential catalyst was characterised utilising field emission scanning electron microscopy-energy dispersive X-ray (FESEM-EDX), Brunauer-Emmett-Teller (BET), and X-ray diffraction spectroscopy (XRD). The parameters include deacidifying agent dosing, loading dopant ratio and catalyst calcination temperature were performed to enhance the catalytic deacidification process in this study. Data showed that the total acidic number (TAN) value for crude B met the PETRONAS requirement for the TAN value below one using 1500 mg/L of DEA-PEG assisted by Cu/Ca (10:90)/Al2O3 catalyst. |
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Conference or Workshop Item |
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Mohd. Shukri, Nurasmat Wan Abu Bakar, Wan Azelee Muhammad Reezhuan, Russman Wan Abdullah, Wan Nazwanie |
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Mohd. Shukri, Nurasmat Wan Abu Bakar, Wan Azelee Muhammad Reezhuan, Russman Wan Abdullah, Wan Nazwanie |
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Mohd. Shukri, Nurasmat |
title |
A study on the catalytic technology for reduction of naphthenic acid compound from acidic crude oil |
title_short |
A study on the catalytic technology for reduction of naphthenic acid compound from acidic crude oil |
title_full |
A study on the catalytic technology for reduction of naphthenic acid compound from acidic crude oil |
title_fullStr |
A study on the catalytic technology for reduction of naphthenic acid compound from acidic crude oil |
title_full_unstemmed |
A study on the catalytic technology for reduction of naphthenic acid compound from acidic crude oil |
title_sort |
study on the catalytic technology for reduction of naphthenic acid compound from acidic crude oil |
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2022 |
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http://eprints.utm.my/103821/ http://dx.doi.org/10.4028/p-mwjz0x |
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