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Photocatalytic antifouling nanohybrid polysulfone membrane using the synergetic effect of graphene oxide and SiO2 for effective treatment of natural rubber-laden wastewater

This study investigates the effects of graphene oxide (GO) and SiO2 composite as nano-photocatalysts in the polysulfone (PSf) membrane to treat natural rubber-laden wastewater (NRW) treatment under UV irradiation. The membranes were fabricated using the phase inversion process. Characterization resu...

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Main Authors:	Kusworo, Tutuk Djoko, Kumoro, Andri Cahyo, Aryanti, Nita, Utomo, Dani Puji, Hasbullah, Hasrinah, Lingga, Fadhilah Fatma, Widiastuti, Ade, Yulfarida, Monica, Dalanta, Febio, Kurniawan, Tonni Agustiono
Format:	Article
Language:	English
Published:	Elsevier Ltd. 2022
Subjects:	TP Chemical technology
Online Access:	http://eprints.utm.my/103424/1/HasrinahHasbullah2022_PhotocatalyticAntifoulingNanohybridPolysulfoneMembrane.pdf http://eprints.utm.my/103424/ http://dx.doi.org/10.1016/j.memsci.2022.120663
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id	my.utm.103424
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spelling	my.utm.1034242023-11-14T04:24:08Z http://eprints.utm.my/103424/ Photocatalytic antifouling nanohybrid polysulfone membrane using the synergetic effect of graphene oxide and SiO2 for effective treatment of natural rubber-laden wastewater Kusworo, Tutuk Djoko Kumoro, Andri Cahyo Aryanti, Nita Utomo, Dani Puji Hasbullah, Hasrinah Lingga, Fadhilah Fatma Widiastuti, Ade Yulfarida, Monica Dalanta, Febio Kurniawan, Tonni Agustiono TP Chemical technology This study investigates the effects of graphene oxide (GO) and SiO2 composite as nano-photocatalysts in the polysulfone (PSf) membrane to treat natural rubber-laden wastewater (NRW) treatment under UV irradiation. The membranes were fabricated using the phase inversion process. Characterization results showed that the incorporation of GO and SiO2 nanoparticles as a composite successfully changed the properties of the membranes. Optical analysis tests revealed that the composite enhanced the photocatalytic activity and possessed bandgap energy of 3.25 eV, which made the SiO2 more active under UV light exposure after incorporating the GO. The addition of GO/SiO2 to the membrane resulted in more hydrophilic properties with contact angle of 60.34 degrees and water uptake ability of 52.78%. Conducting filtration under UV irradiation using PSf/GO/SiO2 membrane exhibited a remarkable improvement in permeate flux by 129% from 9.85 L m(-2) h(-1) to 22.55 L m(-2) h(-1) and maintained 85.4% of permeate flux stability. With respect to removal performance, under the photo-filtration process, chemical oxygen demand (COD) removal increased from 73 to 84%, and ammonia-nitrogen (NH3-N) removal improved from 78 to 92%. The photocatalytic kinetic evaluation suggested that the pseudo-first order kinetic model had a better fit than the zero-order kinetic. Regeneration tests showed that the PSf/GO/SiO2 membrane has outstanding durability. The resistance during filtration and antifouling potential evaluations revealed that the GO/SiO2 composite under UV light irradiation during filtration remarkably reduced the fouling formation and generated a high flux recovery ratio. This implies that this PSf/GO/SiO2 membrane is promising for advanced treatment of NRW. Elsevier Ltd. 2022 Article PeerReviewed application/pdf en http://eprints.utm.my/103424/1/HasrinahHasbullah2022_PhotocatalyticAntifoulingNanohybridPolysulfoneMembrane.pdf Kusworo, Tutuk Djoko and Kumoro, Andri Cahyo and Aryanti, Nita and Utomo, Dani Puji and Hasbullah, Hasrinah and Lingga, Fadhilah Fatma and Widiastuti, Ade and Yulfarida, Monica and Dalanta, Febio and Kurniawan, Tonni Agustiono (2022) Photocatalytic antifouling nanohybrid polysulfone membrane using the synergetic effect of graphene oxide and SiO2 for effective treatment of natural rubber-laden wastewater. Journal of Membrane Science, 657 (120663). pp. 1-18. ISSN 0376-7388 http://dx.doi.org/10.1016/j.memsci.2022.120663 DOI: 10.1016/j.memsci.2022.120663
institution	Universiti Teknologi Malaysia
building	UTM Library
collection	Institutional Repository
continent	Asia
country	Malaysia
content_provider	Universiti Teknologi Malaysia
content_source	UTM Institutional Repository
url_provider	http://eprints.utm.my/
language	English
topic	TP Chemical technology
spellingShingle	TP Chemical technology Kusworo, Tutuk Djoko Kumoro, Andri Cahyo Aryanti, Nita Utomo, Dani Puji Hasbullah, Hasrinah Lingga, Fadhilah Fatma Widiastuti, Ade Yulfarida, Monica Dalanta, Febio Kurniawan, Tonni Agustiono Photocatalytic antifouling nanohybrid polysulfone membrane using the synergetic effect of graphene oxide and SiO2 for effective treatment of natural rubber-laden wastewater
description	This study investigates the effects of graphene oxide (GO) and SiO2 composite as nano-photocatalysts in the polysulfone (PSf) membrane to treat natural rubber-laden wastewater (NRW) treatment under UV irradiation. The membranes were fabricated using the phase inversion process. Characterization results showed that the incorporation of GO and SiO2 nanoparticles as a composite successfully changed the properties of the membranes. Optical analysis tests revealed that the composite enhanced the photocatalytic activity and possessed bandgap energy of 3.25 eV, which made the SiO2 more active under UV light exposure after incorporating the GO. The addition of GO/SiO2 to the membrane resulted in more hydrophilic properties with contact angle of 60.34 degrees and water uptake ability of 52.78%. Conducting filtration under UV irradiation using PSf/GO/SiO2 membrane exhibited a remarkable improvement in permeate flux by 129% from 9.85 L m(-2) h(-1) to 22.55 L m(-2) h(-1) and maintained 85.4% of permeate flux stability. With respect to removal performance, under the photo-filtration process, chemical oxygen demand (COD) removal increased from 73 to 84%, and ammonia-nitrogen (NH3-N) removal improved from 78 to 92%. The photocatalytic kinetic evaluation suggested that the pseudo-first order kinetic model had a better fit than the zero-order kinetic. Regeneration tests showed that the PSf/GO/SiO2 membrane has outstanding durability. The resistance during filtration and antifouling potential evaluations revealed that the GO/SiO2 composite under UV light irradiation during filtration remarkably reduced the fouling formation and generated a high flux recovery ratio. This implies that this PSf/GO/SiO2 membrane is promising for advanced treatment of NRW.
format	Article
author	Kusworo, Tutuk Djoko Kumoro, Andri Cahyo Aryanti, Nita Utomo, Dani Puji Hasbullah, Hasrinah Lingga, Fadhilah Fatma Widiastuti, Ade Yulfarida, Monica Dalanta, Febio Kurniawan, Tonni Agustiono
author_facet	Kusworo, Tutuk Djoko Kumoro, Andri Cahyo Aryanti, Nita Utomo, Dani Puji Hasbullah, Hasrinah Lingga, Fadhilah Fatma Widiastuti, Ade Yulfarida, Monica Dalanta, Febio Kurniawan, Tonni Agustiono
author_sort	Kusworo, Tutuk Djoko
title	Photocatalytic antifouling nanohybrid polysulfone membrane using the synergetic effect of graphene oxide and SiO2 for effective treatment of natural rubber-laden wastewater
title_short	Photocatalytic antifouling nanohybrid polysulfone membrane using the synergetic effect of graphene oxide and SiO2 for effective treatment of natural rubber-laden wastewater
title_full	Photocatalytic antifouling nanohybrid polysulfone membrane using the synergetic effect of graphene oxide and SiO2 for effective treatment of natural rubber-laden wastewater
title_fullStr	Photocatalytic antifouling nanohybrid polysulfone membrane using the synergetic effect of graphene oxide and SiO2 for effective treatment of natural rubber-laden wastewater
title_full_unstemmed	Photocatalytic antifouling nanohybrid polysulfone membrane using the synergetic effect of graphene oxide and SiO2 for effective treatment of natural rubber-laden wastewater
title_sort	photocatalytic antifouling nanohybrid polysulfone membrane using the synergetic effect of graphene oxide and sio2 for effective treatment of natural rubber-laden wastewater
publisher	Elsevier Ltd.
publishDate	2022
url	http://eprints.utm.my/103424/1/HasrinahHasbullah2022_PhotocatalyticAntifoulingNanohybridPolysulfoneMembrane.pdf http://eprints.utm.my/103424/ http://dx.doi.org/10.1016/j.memsci.2022.120663
_version_	1783876361039904768
score	13.211869

Photocatalytic antifouling nanohybrid polysulfone membrane using the synergetic effect of graphene oxide and SiO2 for effective treatment of natural rubber-laden wastewater

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