Bio-polymer modified nanoclay embedded forward osmosis membranes with enhanced desalination performance
The substrate of forward osmosis (FO) thin-film composite (TFC) membranes supports the formation of the selective layer. It can remarkably influence the structure as well as the physiochemical characteristics of the selective layer formed atop. Therefore, the improvement of TFC substrates in terms o...
Saved in:
Main Authors: | , , , , , , , |
---|---|
Format: | Article |
Published: |
John Wiley and Sons Inc
2022
|
Subjects: | |
Online Access: | http://eprints.utm.my/id/eprint/102897/ http://dx.doi.org/10.1002/app.52473 |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
id |
my.utm.102897 |
---|---|
record_format |
eprints |
spelling |
my.utm.1028972023-09-26T06:17:19Z http://eprints.utm.my/id/eprint/102897/ Bio-polymer modified nanoclay embedded forward osmosis membranes with enhanced desalination performance Mamah, Stanley Chinedu Goh, Pei Sean Ismail, Ahmad Fauzi Yogarathinam, Lukka Thuyavan Suzaimi, Nur Diyana Opia, Anthony Chukwunonso Ojo, Samuel Ngwana, Ngouangna Eugene TP Chemical technology The substrate of forward osmosis (FO) thin-film composite (TFC) membranes supports the formation of the selective layer. It can remarkably influence the structure as well as the physiochemical characteristics of the selective layer formed atop. Therefore, the improvement of TFC substrates in terms of its thickness, tortuosity and porosity can further fine tune the properties of the resultant TFC membranes. In this present study, TFC membrane comprising of polyamide selective layer and palygorskite-chitin (PAL-CH) containing polysulfone substrate was developed for FO desalination. The effects of PAL-CH on the surface and structural properties of the substrate were examined. The FO desalination performance of the resultant membranes was evaluated in both active-layer facing feed solution and active-layer facing draw solution modes using NaCl as draw solution. In comparison with the un-modified membrane, the TFC membrane with PAL-CH embedded polysulfone substrate exhibited enhanced water flux and lower structural parameter. The incorporation of PAL-CH hybrid nanomaterial resulted in improved flux of 34.39 L/m(2) h(1), which corresponds to improvement by 110% compared to that of pristine membranes. During the antifouling test, PAL-CH-S/PA membrane attained 97% water recovery while the pristine membrane attained 90% water recovery. John Wiley and Sons Inc 2022 Article PeerReviewed Mamah, Stanley Chinedu and Goh, Pei Sean and Ismail, Ahmad Fauzi and Yogarathinam, Lukka Thuyavan and Suzaimi, Nur Diyana and Opia, Anthony Chukwunonso and Ojo, Samuel and Ngwana, Ngouangna Eugene (2022) Bio-polymer modified nanoclay embedded forward osmosis membranes with enhanced desalination performance. Journal of Applied Polymer Science, 139 (27). n/a. ISSN 0021-8995 http://dx.doi.org/10.1002/app.52473 DOI: 10.1002/app.52473 |
institution |
Universiti Teknologi Malaysia |
building |
UTM Library |
collection |
Institutional Repository |
continent |
Asia |
country |
Malaysia |
content_provider |
Universiti Teknologi Malaysia |
content_source |
UTM Institutional Repository |
url_provider |
http://eprints.utm.my/ |
topic |
TP Chemical technology |
spellingShingle |
TP Chemical technology Mamah, Stanley Chinedu Goh, Pei Sean Ismail, Ahmad Fauzi Yogarathinam, Lukka Thuyavan Suzaimi, Nur Diyana Opia, Anthony Chukwunonso Ojo, Samuel Ngwana, Ngouangna Eugene Bio-polymer modified nanoclay embedded forward osmosis membranes with enhanced desalination performance |
description |
The substrate of forward osmosis (FO) thin-film composite (TFC) membranes supports the formation of the selective layer. It can remarkably influence the structure as well as the physiochemical characteristics of the selective layer formed atop. Therefore, the improvement of TFC substrates in terms of its thickness, tortuosity and porosity can further fine tune the properties of the resultant TFC membranes. In this present study, TFC membrane comprising of polyamide selective layer and palygorskite-chitin (PAL-CH) containing polysulfone substrate was developed for FO desalination. The effects of PAL-CH on the surface and structural properties of the substrate were examined. The FO desalination performance of the resultant membranes was evaluated in both active-layer facing feed solution and active-layer facing draw solution modes using NaCl as draw solution. In comparison with the un-modified membrane, the TFC membrane with PAL-CH embedded polysulfone substrate exhibited enhanced water flux and lower structural parameter. The incorporation of PAL-CH hybrid nanomaterial resulted in improved flux of 34.39 L/m(2) h(1), which corresponds to improvement by 110% compared to that of pristine membranes. During the antifouling test, PAL-CH-S/PA membrane attained 97% water recovery while the pristine membrane attained 90% water recovery. |
format |
Article |
author |
Mamah, Stanley Chinedu Goh, Pei Sean Ismail, Ahmad Fauzi Yogarathinam, Lukka Thuyavan Suzaimi, Nur Diyana Opia, Anthony Chukwunonso Ojo, Samuel Ngwana, Ngouangna Eugene |
author_facet |
Mamah, Stanley Chinedu Goh, Pei Sean Ismail, Ahmad Fauzi Yogarathinam, Lukka Thuyavan Suzaimi, Nur Diyana Opia, Anthony Chukwunonso Ojo, Samuel Ngwana, Ngouangna Eugene |
author_sort |
Mamah, Stanley Chinedu |
title |
Bio-polymer modified nanoclay embedded forward osmosis membranes with enhanced desalination performance |
title_short |
Bio-polymer modified nanoclay embedded forward osmosis membranes with enhanced desalination performance |
title_full |
Bio-polymer modified nanoclay embedded forward osmosis membranes with enhanced desalination performance |
title_fullStr |
Bio-polymer modified nanoclay embedded forward osmosis membranes with enhanced desalination performance |
title_full_unstemmed |
Bio-polymer modified nanoclay embedded forward osmosis membranes with enhanced desalination performance |
title_sort |
bio-polymer modified nanoclay embedded forward osmosis membranes with enhanced desalination performance |
publisher |
John Wiley and Sons Inc |
publishDate |
2022 |
url |
http://eprints.utm.my/id/eprint/102897/ http://dx.doi.org/10.1002/app.52473 |
_version_ |
1778160798603935744 |
score |
13.211869 |