Bio-polymer modified nanoclay embedded forward osmosis membranes with enhanced desalination performance

The substrate of forward osmosis (FO) thin-film composite (TFC) membranes supports the formation of the selective layer. It can remarkably influence the structure as well as the physiochemical characteristics of the selective layer formed atop. Therefore, the improvement of TFC substrates in terms o...

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Main Authors: Mamah, Stanley Chinedu, Goh, Pei Sean, Ismail, Ahmad Fauzi, Yogarathinam, Lukka Thuyavan, Suzaimi, Nur Diyana, Opia, Anthony Chukwunonso, Ojo, Samuel, Ngwana, Ngouangna Eugene
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Published: John Wiley and Sons Inc 2022
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Online Access:http://eprints.utm.my/id/eprint/102897/
http://dx.doi.org/10.1002/app.52473
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spelling my.utm.1028972023-09-26T06:17:19Z http://eprints.utm.my/id/eprint/102897/ Bio-polymer modified nanoclay embedded forward osmosis membranes with enhanced desalination performance Mamah, Stanley Chinedu Goh, Pei Sean Ismail, Ahmad Fauzi Yogarathinam, Lukka Thuyavan Suzaimi, Nur Diyana Opia, Anthony Chukwunonso Ojo, Samuel Ngwana, Ngouangna Eugene TP Chemical technology The substrate of forward osmosis (FO) thin-film composite (TFC) membranes supports the formation of the selective layer. It can remarkably influence the structure as well as the physiochemical characteristics of the selective layer formed atop. Therefore, the improvement of TFC substrates in terms of its thickness, tortuosity and porosity can further fine tune the properties of the resultant TFC membranes. In this present study, TFC membrane comprising of polyamide selective layer and palygorskite-chitin (PAL-CH) containing polysulfone substrate was developed for FO desalination. The effects of PAL-CH on the surface and structural properties of the substrate were examined. The FO desalination performance of the resultant membranes was evaluated in both active-layer facing feed solution and active-layer facing draw solution modes using NaCl as draw solution. In comparison with the un-modified membrane, the TFC membrane with PAL-CH embedded polysulfone substrate exhibited enhanced water flux and lower structural parameter. The incorporation of PAL-CH hybrid nanomaterial resulted in improved flux of 34.39 L/m(2) h(1), which corresponds to improvement by 110% compared to that of pristine membranes. During the antifouling test, PAL-CH-S/PA membrane attained 97% water recovery while the pristine membrane attained 90% water recovery. John Wiley and Sons Inc 2022 Article PeerReviewed Mamah, Stanley Chinedu and Goh, Pei Sean and Ismail, Ahmad Fauzi and Yogarathinam, Lukka Thuyavan and Suzaimi, Nur Diyana and Opia, Anthony Chukwunonso and Ojo, Samuel and Ngwana, Ngouangna Eugene (2022) Bio-polymer modified nanoclay embedded forward osmosis membranes with enhanced desalination performance. Journal of Applied Polymer Science, 139 (27). n/a. ISSN 0021-8995 http://dx.doi.org/10.1002/app.52473 DOI: 10.1002/app.52473
institution Universiti Teknologi Malaysia
building UTM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Teknologi Malaysia
content_source UTM Institutional Repository
url_provider http://eprints.utm.my/
topic TP Chemical technology
spellingShingle TP Chemical technology
Mamah, Stanley Chinedu
Goh, Pei Sean
Ismail, Ahmad Fauzi
Yogarathinam, Lukka Thuyavan
Suzaimi, Nur Diyana
Opia, Anthony Chukwunonso
Ojo, Samuel
Ngwana, Ngouangna Eugene
Bio-polymer modified nanoclay embedded forward osmosis membranes with enhanced desalination performance
description The substrate of forward osmosis (FO) thin-film composite (TFC) membranes supports the formation of the selective layer. It can remarkably influence the structure as well as the physiochemical characteristics of the selective layer formed atop. Therefore, the improvement of TFC substrates in terms of its thickness, tortuosity and porosity can further fine tune the properties of the resultant TFC membranes. In this present study, TFC membrane comprising of polyamide selective layer and palygorskite-chitin (PAL-CH) containing polysulfone substrate was developed for FO desalination. The effects of PAL-CH on the surface and structural properties of the substrate were examined. The FO desalination performance of the resultant membranes was evaluated in both active-layer facing feed solution and active-layer facing draw solution modes using NaCl as draw solution. In comparison with the un-modified membrane, the TFC membrane with PAL-CH embedded polysulfone substrate exhibited enhanced water flux and lower structural parameter. The incorporation of PAL-CH hybrid nanomaterial resulted in improved flux of 34.39 L/m(2) h(1), which corresponds to improvement by 110% compared to that of pristine membranes. During the antifouling test, PAL-CH-S/PA membrane attained 97% water recovery while the pristine membrane attained 90% water recovery.
format Article
author Mamah, Stanley Chinedu
Goh, Pei Sean
Ismail, Ahmad Fauzi
Yogarathinam, Lukka Thuyavan
Suzaimi, Nur Diyana
Opia, Anthony Chukwunonso
Ojo, Samuel
Ngwana, Ngouangna Eugene
author_facet Mamah, Stanley Chinedu
Goh, Pei Sean
Ismail, Ahmad Fauzi
Yogarathinam, Lukka Thuyavan
Suzaimi, Nur Diyana
Opia, Anthony Chukwunonso
Ojo, Samuel
Ngwana, Ngouangna Eugene
author_sort Mamah, Stanley Chinedu
title Bio-polymer modified nanoclay embedded forward osmosis membranes with enhanced desalination performance
title_short Bio-polymer modified nanoclay embedded forward osmosis membranes with enhanced desalination performance
title_full Bio-polymer modified nanoclay embedded forward osmosis membranes with enhanced desalination performance
title_fullStr Bio-polymer modified nanoclay embedded forward osmosis membranes with enhanced desalination performance
title_full_unstemmed Bio-polymer modified nanoclay embedded forward osmosis membranes with enhanced desalination performance
title_sort bio-polymer modified nanoclay embedded forward osmosis membranes with enhanced desalination performance
publisher John Wiley and Sons Inc
publishDate 2022
url http://eprints.utm.my/id/eprint/102897/
http://dx.doi.org/10.1002/app.52473
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score 13.211869