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Complete electrochemical dechlorination of chlorobenzenes in the presence of various arene mediators

Electrochemical dechlorination of chlorobenzenes in the presence of various arene mediators such as naphthalene, biphenyl, phenanthrene, anthracene, and pyrene, was studied. The amount of mediator required was able to be reduced to 0.01 equiv. for all mediators except for anthracene, with the comple...

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Main Authors:	A. Jalil, Aishah, Triwahyono, Sugeng, M. Razali, N. Aini, H. Hairom, N. Hanis, Idris, Ani, M. Muhid, M. Nazlan, Ismail, Azlyana, M. Yahaya, N. Aisyah, L. Ahmad, N. Akma, Dzinun, Hazlini
Format:	Article
Language:	English
Published:	Elsevier 2010
Subjects:	QD Chemistry TP Chemical technology
Online Access:	http://eprints.utm.my/id/eprint/10083/2/AishahAJalil2010_Complete_electrochemical_dechlorination_of_chlorobenzenes.pdf http://eprints.utm.my/id/eprint/10083/ http://dx.doi.org/10.1016/j.jhazmat.2009.09.091
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id	my.utm.10083
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spelling	my.utm.100832017-02-15T01:20:03Z http://eprints.utm.my/id/eprint/10083/ Complete electrochemical dechlorination of chlorobenzenes in the presence of various arene mediators A. Jalil, Aishah Triwahyono, Sugeng M. Razali, N. Aini H. Hairom, N. Hanis Idris, Ani M. Muhid, M. Nazlan Ismail, Azlyana M. Yahaya, N. Aisyah L. Ahmad, N. Akma Dzinun, Hazlini QD Chemistry TP Chemical technology Electrochemical dechlorination of chlorobenzenes in the presence of various arene mediators such as naphthalene, biphenyl, phenanthrene, anthracene, and pyrene, was studied. The amount of mediator required was able to be reduced to 0.01 equiv. for all mediators except for anthracene, with the complete dechlorination of mono-, 1,3-di- and 1,2,4-trichlorobenzene still achieved. This catalytic amount of mediator plays an important role in accelerating the dechlorination through the rapid formation of radical anions prior to reduction of the chlorobenzenes. Elsevier 2010-02-15 Article PeerReviewed application/pdf en http://eprints.utm.my/id/eprint/10083/2/AishahAJalil2010_Complete_electrochemical_dechlorination_of_chlorobenzenes.pdf A. Jalil, Aishah and Triwahyono, Sugeng and M. Razali, N. Aini and H. Hairom, N. Hanis and Idris, Ani and M. Muhid, M. Nazlan and Ismail, Azlyana and M. Yahaya, N. Aisyah and L. Ahmad, N. Akma and Dzinun, Hazlini (2010) Complete electrochemical dechlorination of chlorobenzenes in the presence of various arene mediators. Journal of Hazardous Materials, 174 (1-3). pp. 581-585. ISSN 0304-3894 http://dx.doi.org/10.1016/j.jhazmat.2009.09.091 doi:10.1016/j.jhazmat.2009.09.091
institution	Universiti Teknologi Malaysia
building	UTM Library
collection	Institutional Repository
continent	Asia
country	Malaysia
content_provider	Universiti Teknologi Malaysia
content_source	UTM Institutional Repository
url_provider	http://eprints.utm.my/
language	English
topic	QD Chemistry TP Chemical technology
spellingShingle	QD Chemistry TP Chemical technology A. Jalil, Aishah Triwahyono, Sugeng M. Razali, N. Aini H. Hairom, N. Hanis Idris, Ani M. Muhid, M. Nazlan Ismail, Azlyana M. Yahaya, N. Aisyah L. Ahmad, N. Akma Dzinun, Hazlini Complete electrochemical dechlorination of chlorobenzenes in the presence of various arene mediators
description	Electrochemical dechlorination of chlorobenzenes in the presence of various arene mediators such as naphthalene, biphenyl, phenanthrene, anthracene, and pyrene, was studied. The amount of mediator required was able to be reduced to 0.01 equiv. for all mediators except for anthracene, with the complete dechlorination of mono-, 1,3-di- and 1,2,4-trichlorobenzene still achieved. This catalytic amount of mediator plays an important role in accelerating the dechlorination through the rapid formation of radical anions prior to reduction of the chlorobenzenes.
format	Article
author	A. Jalil, Aishah Triwahyono, Sugeng M. Razali, N. Aini H. Hairom, N. Hanis Idris, Ani M. Muhid, M. Nazlan Ismail, Azlyana M. Yahaya, N. Aisyah L. Ahmad, N. Akma Dzinun, Hazlini
author_facet	A. Jalil, Aishah Triwahyono, Sugeng M. Razali, N. Aini H. Hairom, N. Hanis Idris, Ani M. Muhid, M. Nazlan Ismail, Azlyana M. Yahaya, N. Aisyah L. Ahmad, N. Akma Dzinun, Hazlini
author_sort	A. Jalil, Aishah
title	Complete electrochemical dechlorination of chlorobenzenes in the presence of various arene mediators
title_short	Complete electrochemical dechlorination of chlorobenzenes in the presence of various arene mediators
title_full	Complete electrochemical dechlorination of chlorobenzenes in the presence of various arene mediators
title_fullStr	Complete electrochemical dechlorination of chlorobenzenes in the presence of various arene mediators
title_full_unstemmed	Complete electrochemical dechlorination of chlorobenzenes in the presence of various arene mediators
title_sort	complete electrochemical dechlorination of chlorobenzenes in the presence of various arene mediators
publisher	Elsevier
publishDate	2010
url	http://eprints.utm.my/id/eprint/10083/2/AishahAJalil2010_Complete_electrochemical_dechlorination_of_chlorobenzenes.pdf http://eprints.utm.my/id/eprint/10083/ http://dx.doi.org/10.1016/j.jhazmat.2009.09.091
_version_	1643645320955953152
score	13.211869

Complete electrochemical dechlorination of chlorobenzenes in the presence of various arene mediators

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