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Study of ionic liquids (AIL and PIL) viscosity and its functional groups under heat treatment on cutting tool surface using fourier-transform infrared spectroscopy (FTIR)

This study was conducted to investigate the efficiency of Minimum Quantity Lubrication (MQL) technique by using Modified Jatropha Oil (MJO) bio-based lubricant with the presence of 10% Ammonium Ionic Liquid (MJO+AIL10%) and 1% Phosphonium Ionic Liquid (MJO+PIL1%) additives respectively at various te...

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Main Authors:	Md Yasser, Mona Alis, Embong, Zaidi, Abd Rahim, Erween, Abdullah Sani, Amiril Sahab, Kamdani, Kamaruddin
Format:	Article
Language:	English
Published:	Trans Tech Publications 2020
Subjects:	TJ Mechanical engineering and machinery
Online Access:	http://eprints.uthm.edu.my/6108/1/AJ%202020%20%28184%29.pdf http://eprints.uthm.edu.my/6108/ https://dx.doi.org/ 10.4028/www.scientific.net/MSF.981.98
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id	my.uthm.eprints.6108
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spelling	my.uthm.eprints.61082022-01-26T07:42:08Z http://eprints.uthm.edu.my/6108/ Study of ionic liquids (AIL and PIL) viscosity and its functional groups under heat treatment on cutting tool surface using fourier-transform infrared spectroscopy (FTIR) Md Yasser, Mona Alis Embong, Zaidi Abd Rahim, Erween Abdullah Sani, Amiril Sahab Kamdani, Kamaruddin TJ Mechanical engineering and machinery This study was conducted to investigate the efficiency of Minimum Quantity Lubrication (MQL) technique by using Modified Jatropha Oil (MJO) bio-based lubricant with the presence of 10% Ammonium Ionic Liquid (MJO+AIL10%) and 1% Phosphonium Ionic Liquid (MJO+PIL1%) additives respectively at various temperature of 200 ̊C, 300 ̊C and 400 ̊C heat treatment to determine the ability to exhibit corrosion and wear throughout the process. Fourier-Transform Infrared Spectroscopy (FTIR) analysis revealed prominent peaks of functional groups in these bio-lubricants; esters (C-O) and (C=O), alkanes (C-H), hydroxide (O-H), and nitrile groups deposited on the cutting tool surface. Initially, nitrile group is detected on cutting tool surface without lubricants at 2200 to 2300 absorption band reduced to lower intensity and most likely concealed by MJO+AIL10% compared to MJO+PIL1% where the nitrile group remains reflected in FTIR spectrum. In this work, it is proved that MJO+AIL10% has higher viscosity as compared to MJO+PIL1%. in the context of functional groups and supported the previous study on MJO+AIL10% as corrosion inhibitor. Trans Tech Publications 2020 Article PeerReviewed text en http://eprints.uthm.edu.my/6108/1/AJ%202020%20%28184%29.pdf Md Yasser, Mona Alis and Embong, Zaidi and Abd Rahim, Erween and Abdullah Sani, Amiril Sahab and Kamdani, Kamaruddin (2020) Study of ionic liquids (AIL and PIL) viscosity and its functional groups under heat treatment on cutting tool surface using fourier-transform infrared spectroscopy (FTIR). Materials Science Forum, 981. pp. 98-103. ISSN 0255-5476 https://dx.doi.org/ 10.4028/www.scientific.net/MSF.981.98
institution	Universiti Tun Hussein Onn Malaysia
building	UTHM Library
collection	Institutional Repository
continent	Asia
country	Malaysia
content_provider	Universiti Tun Hussein Onn Malaysia
content_source	UTHM Institutional Repository
url_provider	http://eprints.uthm.edu.my/
language	English
topic	TJ Mechanical engineering and machinery
spellingShingle	TJ Mechanical engineering and machinery Md Yasser, Mona Alis Embong, Zaidi Abd Rahim, Erween Abdullah Sani, Amiril Sahab Kamdani, Kamaruddin Study of ionic liquids (AIL and PIL) viscosity and its functional groups under heat treatment on cutting tool surface using fourier-transform infrared spectroscopy (FTIR)
description	This study was conducted to investigate the efficiency of Minimum Quantity Lubrication (MQL) technique by using Modified Jatropha Oil (MJO) bio-based lubricant with the presence of 10% Ammonium Ionic Liquid (MJO+AIL10%) and 1% Phosphonium Ionic Liquid (MJO+PIL1%) additives respectively at various temperature of 200 ̊C, 300 ̊C and 400 ̊C heat treatment to determine the ability to exhibit corrosion and wear throughout the process. Fourier-Transform Infrared Spectroscopy (FTIR) analysis revealed prominent peaks of functional groups in these bio-lubricants; esters (C-O) and (C=O), alkanes (C-H), hydroxide (O-H), and nitrile groups deposited on the cutting tool surface. Initially, nitrile group is detected on cutting tool surface without lubricants at 2200 to 2300 absorption band reduced to lower intensity and most likely concealed by MJO+AIL10% compared to MJO+PIL1% where the nitrile group remains reflected in FTIR spectrum. In this work, it is proved that MJO+AIL10% has higher viscosity as compared to MJO+PIL1%. in the context of functional groups and supported the previous study on MJO+AIL10% as corrosion inhibitor.
format	Article
author	Md Yasser, Mona Alis Embong, Zaidi Abd Rahim, Erween Abdullah Sani, Amiril Sahab Kamdani, Kamaruddin
author_facet	Md Yasser, Mona Alis Embong, Zaidi Abd Rahim, Erween Abdullah Sani, Amiril Sahab Kamdani, Kamaruddin
author_sort	Md Yasser, Mona Alis
title	Study of ionic liquids (AIL and PIL) viscosity and its functional groups under heat treatment on cutting tool surface using fourier-transform infrared spectroscopy (FTIR)
title_short	Study of ionic liquids (AIL and PIL) viscosity and its functional groups under heat treatment on cutting tool surface using fourier-transform infrared spectroscopy (FTIR)
title_full	Study of ionic liquids (AIL and PIL) viscosity and its functional groups under heat treatment on cutting tool surface using fourier-transform infrared spectroscopy (FTIR)
title_fullStr	Study of ionic liquids (AIL and PIL) viscosity and its functional groups under heat treatment on cutting tool surface using fourier-transform infrared spectroscopy (FTIR)
title_full_unstemmed	Study of ionic liquids (AIL and PIL) viscosity and its functional groups under heat treatment on cutting tool surface using fourier-transform infrared spectroscopy (FTIR)
title_sort	study of ionic liquids (ail and pil) viscosity and its functional groups under heat treatment on cutting tool surface using fourier-transform infrared spectroscopy (ftir)
publisher	Trans Tech Publications
publishDate	2020
url	http://eprints.uthm.edu.my/6108/1/AJ%202020%20%28184%29.pdf http://eprints.uthm.edu.my/6108/ https://dx.doi.org/ 10.4028/www.scientific.net/MSF.981.98
_version_	1738581451191877632
score	13.223943

Study of ionic liquids (AIL and PIL) viscosity and its functional groups under heat treatment on cutting tool surface using fourier-transform infrared spectroscopy (FTIR)

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