Structural and electrical properties of lanthanide substituted-bismuth titanate prepared by low-temperature combustion synthesis

This paper elucidates the structural and electrical properties of Bi4Ti3O12 (BIT), Bi3.25Nd0.75Ti3O12 (BNT075) and Bi3.25La0.75Ti3O12 (BLT075) compounds that were primarily prepared by a novel combustion route at temperature as low as 300oC. Single crystalline phase of bismuth-layered perovskite...

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Main Authors: Al-Amani, Umar, Srimala , Sreekantan, Ahmad Fauzi , Mohd Noor, Khairunisak , Abd Razak, Satoshi , Tanaka, Keizo , Uematsu
Format: Article
Language:English
Published: Trans Tech Publications, Switzerland 2012
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spelling my.utem.eprints.97482015-05-28T04:06:19Z http://eprints.utem.edu.my/id/eprint/9748/ Structural and electrical properties of lanthanide substituted-bismuth titanate prepared by low-temperature combustion synthesis Al-Amani, Umar Srimala , Sreekantan Ahmad Fauzi , Mohd Noor Khairunisak , Abd Razak Satoshi , Tanaka Keizo , Uematsu T Technology (General) This paper elucidates the structural and electrical properties of Bi4Ti3O12 (BIT), Bi3.25Nd0.75Ti3O12 (BNT075) and Bi3.25La0.75Ti3O12 (BLT075) compounds that were primarily prepared by a novel combustion route at temperature as low as 300oC. Single crystalline phase of bismuth-layered perovskite structure was obtained directly after combustion without calcination. Xray diffraction and Raman spectra analysis showed the phase transition from orthorhombic to tetragonal symmetry with substituting compounds. Compared to BIT, the Curie temperature at maximum dielectric peak of BNT075 and BLT075 decreased to lower values of 434oC and 365oC, respectively. The loss tangen for corresponding substitution compounds were 5 times lower than that of BIT. Besides, BNT075 resulted in large remanent polarization (2Pr) and coercive field (Ec) values of 19μC/cm2 and 45kV/cm, respectively, while 17.6μC/cm2 and 42kV/cm for BLT075. Trans Tech Publications, Switzerland 2012-07-09 Article PeerReviewed image/jpeg en http://eprints.utem.edu.my/id/eprint/9748/1/AMR_545.2012.jpg Al-Amani, Umar and Srimala , Sreekantan and Ahmad Fauzi , Mohd Noor and Khairunisak , Abd Razak and Satoshi , Tanaka and Keizo , Uematsu (2012) Structural and electrical properties of lanthanide substituted-bismuth titanate prepared by low-temperature combustion synthesis. Structural and Electrical Properties of Lanthanide substituted-Bismuth Titanate Prepared by Low-Temperature Combustion Synthesis, 545. pp. 279-284. ISSN 10.4028/www.scientific.net/AMR.545 http://scholar.google.com/scholar?hl=en&q=Structural+and+Electrical+Properties+of+Lanthanide+substituted-Bismuth+Titanate+Prepared+by+Low-Temperature+Combustion+Synthesis&btnG=&as_sdt=1%2C5&as_sdtp= 10.4028/www.scientific.net/AMR.545.279
institution Universiti Teknikal Malaysia Melaka
building UTEM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Teknikal Malaysia Melaka
content_source UTEM Institutional Repository
url_provider http://eprints.utem.edu.my/
language English
topic T Technology (General)
spellingShingle T Technology (General)
Al-Amani, Umar
Srimala , Sreekantan
Ahmad Fauzi , Mohd Noor
Khairunisak , Abd Razak
Satoshi , Tanaka
Keizo , Uematsu
Structural and electrical properties of lanthanide substituted-bismuth titanate prepared by low-temperature combustion synthesis
description This paper elucidates the structural and electrical properties of Bi4Ti3O12 (BIT), Bi3.25Nd0.75Ti3O12 (BNT075) and Bi3.25La0.75Ti3O12 (BLT075) compounds that were primarily prepared by a novel combustion route at temperature as low as 300oC. Single crystalline phase of bismuth-layered perovskite structure was obtained directly after combustion without calcination. Xray diffraction and Raman spectra analysis showed the phase transition from orthorhombic to tetragonal symmetry with substituting compounds. Compared to BIT, the Curie temperature at maximum dielectric peak of BNT075 and BLT075 decreased to lower values of 434oC and 365oC, respectively. The loss tangen for corresponding substitution compounds were 5 times lower than that of BIT. Besides, BNT075 resulted in large remanent polarization (2Pr) and coercive field (Ec) values of 19μC/cm2 and 45kV/cm, respectively, while 17.6μC/cm2 and 42kV/cm for BLT075.
format Article
author Al-Amani, Umar
Srimala , Sreekantan
Ahmad Fauzi , Mohd Noor
Khairunisak , Abd Razak
Satoshi , Tanaka
Keizo , Uematsu
author_facet Al-Amani, Umar
Srimala , Sreekantan
Ahmad Fauzi , Mohd Noor
Khairunisak , Abd Razak
Satoshi , Tanaka
Keizo , Uematsu
author_sort Al-Amani, Umar
title Structural and electrical properties of lanthanide substituted-bismuth titanate prepared by low-temperature combustion synthesis
title_short Structural and electrical properties of lanthanide substituted-bismuth titanate prepared by low-temperature combustion synthesis
title_full Structural and electrical properties of lanthanide substituted-bismuth titanate prepared by low-temperature combustion synthesis
title_fullStr Structural and electrical properties of lanthanide substituted-bismuth titanate prepared by low-temperature combustion synthesis
title_full_unstemmed Structural and electrical properties of lanthanide substituted-bismuth titanate prepared by low-temperature combustion synthesis
title_sort structural and electrical properties of lanthanide substituted-bismuth titanate prepared by low-temperature combustion synthesis
publisher Trans Tech Publications, Switzerland
publishDate 2012
url http://eprints.utem.edu.my/id/eprint/9748/1/AMR_545.2012.jpg
http://eprints.utem.edu.my/id/eprint/9748/
http://scholar.google.com/scholar?hl=en&q=Structural+and+Electrical+Properties+of+Lanthanide+substituted-Bismuth+Titanate+Prepared+by+Low-Temperature+Combustion+Synthesis&btnG=&as_sdt=1%2C5&as_sdtp=
_version_ 1665905406890737664
score 13.211869