صورة الغلاف

Bis{2-methoxy-6-[(E)-(4-methylbenzyl)-iminomethyl]phenolato}palladium(II) chloroform monosolvate

In the title complex, [Pd(C16H16NO2)2]�CHCl3, the PdII cation lies on an inversion center. One Cl atom of the CHCl3 solvent molecule lies on a twofold axis and the C—H group is disordered with equal occupancies about this axis with the other Cl atom in a general position with full occupancy. The...

وصف كامل

محفوظ في:
التفاصيل البيبلوغرافية
المؤلفون الرئيسيون: Bahron, Hadariah, Mohd Tajuddin, Amalina, Wan Ibrahim, Wan Nazihah, Suchada, Chantrapromma, Fun, Hoong Kun
التنسيق: مقال
اللغة:English
منشور في: International Union of Crystallography 2014
الموضوعات:
QC1-999 Physics
الوصول للمادة أونلاين:http://eprints.usm.my/38405/1/Bis%7B2-methoxy-6-%5B%28E%29-%284-methylbenzyl%29-.pdf
http://eprints.usm.my/38405/
https://doi.org/10.1107/S1600536814015025
الوسوم: إضافة وسم
لا توجد وسوم, كن أول من يضع وسما على هذه التسجيلة!
id my.usm.eprints.38405
record_format eprints
spelling my.usm.eprints.38405 http://eprints.usm.my/38405/ Bis{2-methoxy-6-[(E)-(4-methylbenzyl)-iminomethyl]phenolato}palladium(II) chloroform monosolvate Bahron, Hadariah Mohd Tajuddin, Amalina Wan Ibrahim, Wan Nazihah Suchada, Chantrapromma Fun, Hoong Kun QC1-999 Physics In the title complex, [Pd(C16H16NO2)2]�CHCl3, the PdII cation lies on an inversion center. One Cl atom of the CHCl3 solvent molecule lies on a twofold axis and the C—H group is disordered with equal occupancies about this axis with the other Cl atom in a general position with full occupancy. The PdII cation is four-coordinate and adopts a square-planar geometry via coordination of the imine N and phenolic O atoms of the two bidentate Schiff base anions. The N and O atoms of these ligands are mutually trans. The plane of the benzene ring makes a dihedral angle of 73.52 (10)� with that of the methoxyphenolate ring. In the crystal, molecules of the PdII complex are arranged into sheets parallel to the ac plane, and the chloroform solvent molecules are located in the interstitial areas between the complex molecules. Weak intermolecular C—H� � �O and C—H� � �� interactions stabilize the packing. International Union of Crystallography 2014 Article PeerReviewed application/pdf en http://eprints.usm.my/38405/1/Bis%7B2-methoxy-6-%5B%28E%29-%284-methylbenzyl%29-.pdf Bahron, Hadariah and Mohd Tajuddin, Amalina and Wan Ibrahim, Wan Nazihah and Suchada, Chantrapromma and Fun, Hoong Kun (2014) Bis{2-methoxy-6-[(E)-(4-methylbenzyl)-iminomethyl]phenolato}palladium(II) chloroform monosolvate. Acta Crystallographica Section E: Structure Reports Online, 2014 (70). pp. 289-290. ISSN 1600-5368 https://doi.org/10.1107/S1600536814015025
institution Universiti Sains Malaysia
building Hamzah Sendut Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Sains Malaysia
content_source USM Institutional Repository
url_provider http://eprints.usm.my/
language English
topic QC1-999 Physics
spellingShingle QC1-999 Physics
Bahron, Hadariah
Mohd Tajuddin, Amalina
Wan Ibrahim, Wan Nazihah
Suchada, Chantrapromma
Fun, Hoong Kun
Bis{2-methoxy-6-[(E)-(4-methylbenzyl)-iminomethyl]phenolato}palladium(II) chloroform monosolvate
description In the title complex, [Pd(C16H16NO2)2]�CHCl3, the PdII cation lies on an inversion center. One Cl atom of the CHCl3 solvent molecule lies on a twofold axis and the C—H group is disordered with equal occupancies about this axis with the other Cl atom in a general position with full occupancy. The PdII cation is four-coordinate and adopts a square-planar geometry via coordination of the imine N and phenolic O atoms of the two bidentate Schiff base anions. The N and O atoms of these ligands are mutually trans. The plane of the benzene ring makes a dihedral angle of 73.52 (10)� with that of the methoxyphenolate ring. In the crystal, molecules of the PdII complex are arranged into sheets parallel to the ac plane, and the chloroform solvent molecules are located in the interstitial areas between the complex molecules. Weak intermolecular C—H� � �O and C—H� � �� interactions stabilize the packing.
format Article
author Bahron, Hadariah
Mohd Tajuddin, Amalina
Wan Ibrahim, Wan Nazihah
Suchada, Chantrapromma
Fun, Hoong Kun
author_facet Bahron, Hadariah
Mohd Tajuddin, Amalina
Wan Ibrahim, Wan Nazihah
Suchada, Chantrapromma
Fun, Hoong Kun
author_sort Bahron, Hadariah
title Bis{2-methoxy-6-[(E)-(4-methylbenzyl)-iminomethyl]phenolato}palladium(II) chloroform monosolvate
title_short Bis{2-methoxy-6-[(E)-(4-methylbenzyl)-iminomethyl]phenolato}palladium(II) chloroform monosolvate
title_full Bis{2-methoxy-6-[(E)-(4-methylbenzyl)-iminomethyl]phenolato}palladium(II) chloroform monosolvate
title_fullStr Bis{2-methoxy-6-[(E)-(4-methylbenzyl)-iminomethyl]phenolato}palladium(II) chloroform monosolvate
title_full_unstemmed Bis{2-methoxy-6-[(E)-(4-methylbenzyl)-iminomethyl]phenolato}palladium(II) chloroform monosolvate
title_sort bis{2-methoxy-6-[(e)-(4-methylbenzyl)-iminomethyl]phenolato}palladium(ii) chloroform monosolvate
publisher International Union of Crystallography
publishDate 2014
url http://eprints.usm.my/38405/1/Bis%7B2-methoxy-6-%5B%28E%29-%284-methylbenzyl%29-.pdf
http://eprints.usm.my/38405/
https://doi.org/10.1107/S1600536814015025
_version_ 1643709348014194688
score 13.251813

مواد مشابهة