(Benzyldiphenylphosphane-1jP)-[l-bis(diphenylphosphanyl)methane-2:3j2P:P0]nonacarbonyl- 1j3C,2j3C,3j3C-triangulotriruthenium(0)
The asymmetric unit of the title compound, [Ru3(C19H17P)(C25H22P2)(CO)9], consists of two independent molecules. The bis(diphenylphosphanyl)methane ligand bridges an Ru—Ru bond and the benzyldiphenylphosphane ligand binds to the third Ru atom. The Ru—Ru bond cis to the benzyldiphenylphosphane l...
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| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2014
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| Subjects: | |
| Online Access: | http://eprints.usm.my/38389/1/Benzyldiphenylphosphane-1kP%29-.pdf http://eprints.usm.my/38389/ https://doi.org/10.1107/S1600536814015475 |
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| Summary: | The asymmetric unit of the title compound,
[Ru3(C19H17P)(C25H22P2)(CO)9], consists of two independent
molecules. The bis(diphenylphosphanyl)methane ligand
bridges an Ru—Ru bond and the benzyldiphenylphosphane
ligand binds to the third Ru atom. The Ru—Ru bond cis to the
benzyldiphenylphosphane ligand is the longest of the three
Ru—Ru bonds in both molecules. In the crystal, molecules are
linked by C—H� � �O hydrogen bonds, forming layers parallel
to the ac plane. C—H� � �� contacts further stabilize the crystal
packing. |
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