Clay reinforced hyperbranched polyurethane nanocomposites based on palm oil polyol as shape memory materials
Reactive nanoclay reinforced hyperbranched polyurethane (HPU) nanocomposites have been synthesized with the introduction of palm oil polyol as part of the precursor. The HPU were prepared in a two-step process using polycaprolactonediol, 4,4'-diphenylmethane diisocyanate and 1,4-butanediol as c...
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my.usim-91422015-08-24T03:39:06Z Clay reinforced hyperbranched polyurethane nanocomposites based on palm oil polyol as shape memory materials E.S., Ali, S.A., Zubir, S., Ahmad, Nanoclay; Nanocomposites; Palm oil polyol; Polyurethane Shape memory Reactive nanoclay reinforced hyperbranched polyurethane (HPU) nanocomposites have been synthesized with the introduction of palm oil polyol as part of the precursor. The HPU were prepared in a two-step process using polycaprolactonediol, 4,4'-diphenylmethane diisocyanate and 1,4-butanediol as chain extender. Nanoclay was added with the purpose of improving the properties of the pristine polyurethane. The introduction of palm oil polyol is believed to enhance the mixing process between polymer matrix and filler. Thermal, mechanical and shape memory properties of produced HPU were investigated. The results showed that the crystallinity of HPU nanocomposites decreased with introduction of clay particles and that the mechanical and shape memory properties were enhanced with the addition of small amount of reactive nanoclay (up to 3 wt%). © (2012) Trans Tech Publications, Switzerland. 2015-08-24T03:39:06Z 2015-08-24T03:39:06Z 2012-01-01 Conference Paper 9783-0378-5453-2 1022-6680 http://ddms.usim.edu.my/handle/123456789/9142 en_US |
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Nanoclay; Nanocomposites; Palm oil polyol; Polyurethane Shape memory E.S., Ali, S.A., Zubir, S., Ahmad, Clay reinforced hyperbranched polyurethane nanocomposites based on palm oil polyol as shape memory materials |
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Reactive nanoclay reinforced hyperbranched polyurethane (HPU) nanocomposites have been synthesized with the introduction of palm oil polyol as part of the precursor. The HPU were prepared in a two-step process using polycaprolactonediol, 4,4'-diphenylmethane diisocyanate and 1,4-butanediol as chain extender. Nanoclay was added with the purpose of improving the properties of the pristine polyurethane. The introduction of palm oil polyol is believed to enhance the mixing process between polymer matrix and filler. Thermal, mechanical and shape memory properties of produced HPU were investigated. The results showed that the crystallinity of HPU nanocomposites decreased with introduction of clay particles and that the mechanical and shape memory properties were enhanced with the addition of small amount of reactive nanoclay (up to 3 wt%). © (2012) Trans Tech Publications, Switzerland. |
format |
Conference Paper |
author |
E.S., Ali, S.A., Zubir, S., Ahmad, |
author_facet |
E.S., Ali, S.A., Zubir, S., Ahmad, |
author_sort |
E.S., Ali, |
title |
Clay reinforced hyperbranched polyurethane nanocomposites based on palm oil polyol as shape memory materials |
title_short |
Clay reinforced hyperbranched polyurethane nanocomposites based on palm oil polyol as shape memory materials |
title_full |
Clay reinforced hyperbranched polyurethane nanocomposites based on palm oil polyol as shape memory materials |
title_fullStr |
Clay reinforced hyperbranched polyurethane nanocomposites based on palm oil polyol as shape memory materials |
title_full_unstemmed |
Clay reinforced hyperbranched polyurethane nanocomposites based on palm oil polyol as shape memory materials |
title_sort |
clay reinforced hyperbranched polyurethane nanocomposites based on palm oil polyol as shape memory materials |
publishDate |
2015 |
url |
http://ddms.usim.edu.my/handle/123456789/9142 |
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1645152548655464448 |
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13.222552 |