Polypyrrole/Graphene Composite Films Synthesized via Potentiostatic Deposition

A one-step electrochemical process has been employed to synthesize composite films of polypyrrole/graphene (PPy/GR) by electrochemical polymerization on indium tin oxide (ITO) from an aqueous solution containing pyrrole monomer, graphene oxide (GO) nanosheets and sodium p-toluenesulfonate (NapTS). T...

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Main Authors: Y. S, Lim,, Y. P, Tan,, H. N, Lim,, W. T, Tan,, M A, Mahnaz,, Z. A., Talib,, N. M., Huang,, A., Kassim,, M. A., Yarmo,
Format: Article
Language:English
Published: Wiley-Blackwell 2015
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Online Access:http://ddms.usim.edu.my/handle/123456789/8362
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spelling my.usim-83622017-03-28T06:23:56Z Polypyrrole/Graphene Composite Films Synthesized via Potentiostatic Deposition Y. S, Lim, Y. P, Tan, H. N, Lim, W. T, Tan, M A, Mahnaz, Z. A., Talib, N. M., Huang, A., Kassim, M. A., Yarmo, Conducting Polymers Graphene Electrochemistry Composite A one-step electrochemical process has been employed to synthesize composite films of polypyrrole/graphene (PPy/GR) by electrochemical polymerization on indium tin oxide (ITO) from an aqueous solution containing pyrrole monomer, graphene oxide (GO) nanosheets and sodium p-toluenesulfonate (NapTS). Thermogravimetric analysis (TGA) confirmed the formation of a composite; the degradation temperature of the new hybrid was between those of PPy and GO. Moreover, the bulbous surface of PPy and the almost transparent tissue-like GO nanosheets were replaced by the new appearance of the composite where the surface was flat but creased. As GO is nonconductive, we deduced that it had been reduced to conducting graphene in the composite film during the electrodeposition process, based on an electrical conductivity study measured with a four-point probe. On average, the electrical conductivity of the PPy/GR composites was twofold higher than that of the pure PPy film, indicating that the incorporation of graphene was able to enhance the conductivity of PPy film. (C) 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 128: 224-229, 2013 2015-06-15T07:21:09Z 2015-06-15T07:21:09Z 2013 Article 0021-8995 http://ddms.usim.edu.my/handle/123456789/8362 en Wiley-Blackwell
institution Universiti Sains Islam Malaysia
building USIM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universit Sains Islam i Malaysia
content_source USIM Institutional Repository
url_provider http://ddms.usim.edu.my/
language English
topic Conducting Polymers
Graphene
Electrochemistry
Composite
spellingShingle Conducting Polymers
Graphene
Electrochemistry
Composite
Y. S, Lim,
Y. P, Tan,
H. N, Lim,
W. T, Tan,
M A, Mahnaz,
Z. A., Talib,
N. M., Huang,
A., Kassim,
M. A., Yarmo,
Polypyrrole/Graphene Composite Films Synthesized via Potentiostatic Deposition
description A one-step electrochemical process has been employed to synthesize composite films of polypyrrole/graphene (PPy/GR) by electrochemical polymerization on indium tin oxide (ITO) from an aqueous solution containing pyrrole monomer, graphene oxide (GO) nanosheets and sodium p-toluenesulfonate (NapTS). Thermogravimetric analysis (TGA) confirmed the formation of a composite; the degradation temperature of the new hybrid was between those of PPy and GO. Moreover, the bulbous surface of PPy and the almost transparent tissue-like GO nanosheets were replaced by the new appearance of the composite where the surface was flat but creased. As GO is nonconductive, we deduced that it had been reduced to conducting graphene in the composite film during the electrodeposition process, based on an electrical conductivity study measured with a four-point probe. On average, the electrical conductivity of the PPy/GR composites was twofold higher than that of the pure PPy film, indicating that the incorporation of graphene was able to enhance the conductivity of PPy film. (C) 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 128: 224-229, 2013
format Article
author Y. S, Lim,
Y. P, Tan,
H. N, Lim,
W. T, Tan,
M A, Mahnaz,
Z. A., Talib,
N. M., Huang,
A., Kassim,
M. A., Yarmo,
author_facet Y. S, Lim,
Y. P, Tan,
H. N, Lim,
W. T, Tan,
M A, Mahnaz,
Z. A., Talib,
N. M., Huang,
A., Kassim,
M. A., Yarmo,
author_sort Y. S, Lim,
title Polypyrrole/Graphene Composite Films Synthesized via Potentiostatic Deposition
title_short Polypyrrole/Graphene Composite Films Synthesized via Potentiostatic Deposition
title_full Polypyrrole/Graphene Composite Films Synthesized via Potentiostatic Deposition
title_fullStr Polypyrrole/Graphene Composite Films Synthesized via Potentiostatic Deposition
title_full_unstemmed Polypyrrole/Graphene Composite Films Synthesized via Potentiostatic Deposition
title_sort polypyrrole/graphene composite films synthesized via potentiostatic deposition
publisher Wiley-Blackwell
publishDate 2015
url http://ddms.usim.edu.my/handle/123456789/8362
_version_ 1645152402018402304
score 13.222552