Bamboo fiber based cellulose nanocrystals/poly(Lactic Acid)/Poly(Butylene Succinate) nanocomposites: morphological, mechanical and thermal properties

The purpose of this work was to investigate the effect of cellulose nanocrystals (CNC) from bamboo fiber on the properties of poly (lactic acid) (PLA)/poly (butylene succinate) (PBS) composites fabricated by melt mixing at 175 °C and then hot pressing at 180 °C. PBS and CNC (0.5, 0.75, 1, 1.5 wt.%)...

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Main Authors: Rasheed, Masrat, Jawaid, Mohammad, Parveez, Bisma
Format: Article
Published: Multidisciplinary Digital Publishing Institute 2021
Online Access:http://psasir.upm.edu.my/id/eprint/96177/
https://www.mdpi.com/2073-4360/13/7/1076
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spelling my.upm.eprints.961772023-01-31T03:29:21Z http://psasir.upm.edu.my/id/eprint/96177/ Bamboo fiber based cellulose nanocrystals/poly(Lactic Acid)/Poly(Butylene Succinate) nanocomposites: morphological, mechanical and thermal properties Rasheed, Masrat Jawaid, Mohammad Parveez, Bisma The purpose of this work was to investigate the effect of cellulose nanocrystals (CNC) from bamboo fiber on the properties of poly (lactic acid) (PLA)/poly (butylene succinate) (PBS) composites fabricated by melt mixing at 175 °C and then hot pressing at 180 °C. PBS and CNC (0.5, 0.75, 1, 1.5 wt.%) were added to improvise the properties of PLA. The morphological, physiochemical and crystallinity properties of nanocomposites were analysed by field emission scanning electron microscope (FESEM), Fourier-transform infrared spectroscopy (FTIR) and X-ray diffractometry (XRD), respectively. The thermal and tensile properties were analysed by thermogravimetic analysis (TGA), Differential scanning calorimetry (DSC) and Universal testing machine (UTM). PLA-PBS blend shows homogeneous morphology while the composite shows rod-like CNC particles, which are embedded in the polymer matrix. The uniform distribution of CNC particles in the nanocomposites improves their thermal stability, tensile strength and tensile modulus up to 1 wt.%; however, their elongation at break decreases. Thus, CNC addition in PLA-PBS matrix improves structural and thermal properties of the composite. The composite, thus developed, using CNC (a natural fiber) and PLA-PBS (biodegradable polymers) could be of immense importance as they could allow complete degradation in soil, making it a potential alternative material to existing packaging materials in the market that could be environment friendly Multidisciplinary Digital Publishing Institute 2021 Article PeerReviewed Rasheed, Masrat and Jawaid, Mohammad and Parveez, Bisma (2021) Bamboo fiber based cellulose nanocrystals/poly(Lactic Acid)/Poly(Butylene Succinate) nanocomposites: morphological, mechanical and thermal properties. Polymers, 13 (7). art. no. 1076. pp. 1-15. ISSN 2073-4360 https://www.mdpi.com/2073-4360/13/7/1076 10.3390/polym13071076
institution Universiti Putra Malaysia
building UPM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Putra Malaysia
content_source UPM Institutional Repository
url_provider http://psasir.upm.edu.my/
description The purpose of this work was to investigate the effect of cellulose nanocrystals (CNC) from bamboo fiber on the properties of poly (lactic acid) (PLA)/poly (butylene succinate) (PBS) composites fabricated by melt mixing at 175 °C and then hot pressing at 180 °C. PBS and CNC (0.5, 0.75, 1, 1.5 wt.%) were added to improvise the properties of PLA. The morphological, physiochemical and crystallinity properties of nanocomposites were analysed by field emission scanning electron microscope (FESEM), Fourier-transform infrared spectroscopy (FTIR) and X-ray diffractometry (XRD), respectively. The thermal and tensile properties were analysed by thermogravimetic analysis (TGA), Differential scanning calorimetry (DSC) and Universal testing machine (UTM). PLA-PBS blend shows homogeneous morphology while the composite shows rod-like CNC particles, which are embedded in the polymer matrix. The uniform distribution of CNC particles in the nanocomposites improves their thermal stability, tensile strength and tensile modulus up to 1 wt.%; however, their elongation at break decreases. Thus, CNC addition in PLA-PBS matrix improves structural and thermal properties of the composite. The composite, thus developed, using CNC (a natural fiber) and PLA-PBS (biodegradable polymers) could be of immense importance as they could allow complete degradation in soil, making it a potential alternative material to existing packaging materials in the market that could be environment friendly
format Article
author Rasheed, Masrat
Jawaid, Mohammad
Parveez, Bisma
spellingShingle Rasheed, Masrat
Jawaid, Mohammad
Parveez, Bisma
Bamboo fiber based cellulose nanocrystals/poly(Lactic Acid)/Poly(Butylene Succinate) nanocomposites: morphological, mechanical and thermal properties
author_facet Rasheed, Masrat
Jawaid, Mohammad
Parveez, Bisma
author_sort Rasheed, Masrat
title Bamboo fiber based cellulose nanocrystals/poly(Lactic Acid)/Poly(Butylene Succinate) nanocomposites: morphological, mechanical and thermal properties
title_short Bamboo fiber based cellulose nanocrystals/poly(Lactic Acid)/Poly(Butylene Succinate) nanocomposites: morphological, mechanical and thermal properties
title_full Bamboo fiber based cellulose nanocrystals/poly(Lactic Acid)/Poly(Butylene Succinate) nanocomposites: morphological, mechanical and thermal properties
title_fullStr Bamboo fiber based cellulose nanocrystals/poly(Lactic Acid)/Poly(Butylene Succinate) nanocomposites: morphological, mechanical and thermal properties
title_full_unstemmed Bamboo fiber based cellulose nanocrystals/poly(Lactic Acid)/Poly(Butylene Succinate) nanocomposites: morphological, mechanical and thermal properties
title_sort bamboo fiber based cellulose nanocrystals/poly(lactic acid)/poly(butylene succinate) nanocomposites: morphological, mechanical and thermal properties
publisher Multidisciplinary Digital Publishing Institute
publishDate 2021
url http://psasir.upm.edu.my/id/eprint/96177/
https://www.mdpi.com/2073-4360/13/7/1076
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