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Adsorptive removal of copper (II) Ions from aqueous solution using a magnetite nano-adsorbent from mill scale waste: synthesis, characterization, adsorption and kinetic modelling studies

In this study, magnetite nano-adsorbent (MNA) was extracted from mill scale waste products, synthesized and applied to eliminate Cu2+ from an aqueous solution. Mill scale waste product was ground using conventional milling and impacted using high-energy ball milling (HEBM) for varying 3, 5, and 7 mi...

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Main Authors:	Sulaiman, Syazana, Azis, Raba'ah Syahidah, Ismail, Ismayadi, Che Man, Hasfalina, Muhammad Yusof, Khairul Faezah, Abba, Muhammad Umar, Katibi, Kamil Kayode
Format:	Article
Published:	Springer 2021
Online Access:	http://psasir.upm.edu.my/id/eprint/95718/ https://link.springer.com/article/10.1186/s11671-021-03622-y
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spelling	my.upm.eprints.957182023-04-05T04:03:12Z http://psasir.upm.edu.my/id/eprint/95718/ Adsorptive removal of copper (II) Ions from aqueous solution using a magnetite nano-adsorbent from mill scale waste: synthesis, characterization, adsorption and kinetic modelling studies Sulaiman, Syazana Azis, Raba'ah Syahidah Ismail, Ismayadi Che Man, Hasfalina Muhammad Yusof, Khairul Faezah Abba, Muhammad Umar Katibi, Kamil Kayode In this study, magnetite nano-adsorbent (MNA) was extracted from mill scale waste products, synthesized and applied to eliminate Cu2+ from an aqueous solution. Mill scale waste product was ground using conventional milling and impacted using high-energy ball milling (HEBM) for varying 3, 5, and 7 milling hours. In this regard, the prepared MNA was investigated using X-ray diffraction (XRD), high-resolution transmission electron microscope (HRTEM), field emission scanning electron microscopy-energy-dispersive X-ray spectroscopy (FESEM-EDS), UV-Vis spectroscopy, Fourier-transform infrared (FTIR), Brunauer-Emmett-Teller (BET) and zeta potential. The resultant MNA-7 h milling time displayed a crystalline structure with irregular shapes of 11.23 nm, specific surface area of 5.98 m2g-1, saturation magnetization, Ms of 8.35 emug-1, and isoelectric point charge at pH 5.4. The optimum adsorption capacity, qe of 4.42 mg.g-1 for the removal of Cu2+ ions was attained at 120 min of contact time. The experimental data were best fitted to the Temkin isotherm model. A comparison between experimental kinetic studies and the theoretical aspects showed that the pseudo-second-order matched the experimental trends with a correlation coefficient of (R2 > 0.99). Besides, regeneration efficiency of 70.87% was achieved after three cycles of reusability studies. The MNA offers a practical, efficient, low-cost approach to reutilize mill scale waste products and provide ultra-fast separation to remove Cu2+ from water. Springer 2021 Article PeerReviewed Sulaiman, Syazana and Azis, Raba'ah Syahidah and Ismail, Ismayadi and Che Man, Hasfalina and Muhammad Yusof, Khairul Faezah and Abba, Muhammad Umar and Katibi, Kamil Kayode (2021) Adsorptive removal of copper (II) Ions from aqueous solution using a magnetite nano-adsorbent from mill scale waste: synthesis, characterization, adsorption and kinetic modelling studies. Nanoscale Research Letters, 16. art. no. 168. pp. 1-17. ISSN 1931-7573; ESSN: 1556-276X https://link.springer.com/article/10.1186/s11671-021-03622-y 10.1186/s11671-021-03622-y
institution	Universiti Putra Malaysia
building	UPM Library
collection	Institutional Repository
continent	Asia
country	Malaysia
content_provider	Universiti Putra Malaysia
content_source	UPM Institutional Repository
url_provider	http://psasir.upm.edu.my/
description	In this study, magnetite nano-adsorbent (MNA) was extracted from mill scale waste products, synthesized and applied to eliminate Cu2+ from an aqueous solution. Mill scale waste product was ground using conventional milling and impacted using high-energy ball milling (HEBM) for varying 3, 5, and 7 milling hours. In this regard, the prepared MNA was investigated using X-ray diffraction (XRD), high-resolution transmission electron microscope (HRTEM), field emission scanning electron microscopy-energy-dispersive X-ray spectroscopy (FESEM-EDS), UV-Vis spectroscopy, Fourier-transform infrared (FTIR), Brunauer-Emmett-Teller (BET) and zeta potential. The resultant MNA-7 h milling time displayed a crystalline structure with irregular shapes of 11.23 nm, specific surface area of 5.98 m2g-1, saturation magnetization, Ms of 8.35 emug-1, and isoelectric point charge at pH 5.4. The optimum adsorption capacity, qe of 4.42 mg.g-1 for the removal of Cu2+ ions was attained at 120 min of contact time. The experimental data were best fitted to the Temkin isotherm model. A comparison between experimental kinetic studies and the theoretical aspects showed that the pseudo-second-order matched the experimental trends with a correlation coefficient of (R2 > 0.99). Besides, regeneration efficiency of 70.87% was achieved after three cycles of reusability studies. The MNA offers a practical, efficient, low-cost approach to reutilize mill scale waste products and provide ultra-fast separation to remove Cu2+ from water.
format	Article
author	Sulaiman, Syazana Azis, Raba'ah Syahidah Ismail, Ismayadi Che Man, Hasfalina Muhammad Yusof, Khairul Faezah Abba, Muhammad Umar Katibi, Kamil Kayode
spellingShingle	Sulaiman, Syazana Azis, Raba'ah Syahidah Ismail, Ismayadi Che Man, Hasfalina Muhammad Yusof, Khairul Faezah Abba, Muhammad Umar Katibi, Kamil Kayode Adsorptive removal of copper (II) Ions from aqueous solution using a magnetite nano-adsorbent from mill scale waste: synthesis, characterization, adsorption and kinetic modelling studies
author_facet	Sulaiman, Syazana Azis, Raba'ah Syahidah Ismail, Ismayadi Che Man, Hasfalina Muhammad Yusof, Khairul Faezah Abba, Muhammad Umar Katibi, Kamil Kayode
author_sort	Sulaiman, Syazana
title	Adsorptive removal of copper (II) Ions from aqueous solution using a magnetite nano-adsorbent from mill scale waste: synthesis, characterization, adsorption and kinetic modelling studies
title_short	Adsorptive removal of copper (II) Ions from aqueous solution using a magnetite nano-adsorbent from mill scale waste: synthesis, characterization, adsorption and kinetic modelling studies
title_full	Adsorptive removal of copper (II) Ions from aqueous solution using a magnetite nano-adsorbent from mill scale waste: synthesis, characterization, adsorption and kinetic modelling studies
title_fullStr	Adsorptive removal of copper (II) Ions from aqueous solution using a magnetite nano-adsorbent from mill scale waste: synthesis, characterization, adsorption and kinetic modelling studies
title_full_unstemmed	Adsorptive removal of copper (II) Ions from aqueous solution using a magnetite nano-adsorbent from mill scale waste: synthesis, characterization, adsorption and kinetic modelling studies
title_sort	adsorptive removal of copper (ii) ions from aqueous solution using a magnetite nano-adsorbent from mill scale waste: synthesis, characterization, adsorption and kinetic modelling studies
publisher	Springer
publishDate	2021
url	http://psasir.upm.edu.my/id/eprint/95718/ https://link.springer.com/article/10.1186/s11671-021-03622-y
_version_	1762394222828191744
score	13.211869

Adsorptive removal of copper (II) Ions from aqueous solution using a magnetite nano-adsorbent from mill scale waste: synthesis, characterization, adsorption and kinetic modelling studies

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