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The effect of manganese IV oxide doping on the optical and elastic properties of calcium borate glass derived from waste chicken eggshell

The extraction of CaO from waste eggshell can be used to produce new product known as calcium borate glass doped manganese (IV) oxide. A tertiary (B2O3)0.6 [(CaO)0.4]1-x (MnO2)x glass system with 0.010 ≥ x ≥ 0 M fraction were prepared using conventional melt-quenching technique. XRF spectroscopy con...

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Main Authors: A.S., Asyikin, A.A., Shamimi, S.N., Nazrin, M.K., Halimah, Boukhris, Imed
Format: Article
Published: Elsevier BV 2021
Online Access:http://psasir.upm.edu.my/id/eprint/95394/
https://www.sciencedirect.com/science/article/pii/S0925346721007400
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spelling my.upm.eprints.953942023-01-09T02:10:13Z http://psasir.upm.edu.my/id/eprint/95394/ The effect of manganese IV oxide doping on the optical and elastic properties of calcium borate glass derived from waste chicken eggshell A.S., Asyikin A.A., Shamimi S.N., Nazrin M.K., Halimah Boukhris, Imed The extraction of CaO from waste eggshell can be used to produce new product known as calcium borate glass doped manganese (IV) oxide. A tertiary (B2O3)0.6 [(CaO)0.4]1-x (MnO2)x glass system with 0.010 ≥ x ≥ 0 M fraction were prepared using conventional melt-quenching technique. XRF spectroscopy confirms CaO as the main constituent in the calcined eggshell. XRD spectra unveils the two amorphous humps of the glass samples. FTIR analysis reveals the typical features of CaCO3 and B2O3 network. The density has opposite behaviour with molar volume as MnO2 content increases. Next, the optical band gap and refractive index are evidencing the formation of non-bridging oxygen in the glass matrix. The present glass system also has low polarizability, acidic in nature and have tendency to metallizing. The elastic properties of glass samples were determined using the ultrasonic technique. Elastic moduli such as longitudinal modulus, shear modulus, Young's modulus, bulk modulus, Poisson's ratio and hardness of the glass system were discussed. Elsevier BV 2021 Article PeerReviewed A.S., Asyikin and A.A., Shamimi and S.N., Nazrin and M.K., Halimah and Boukhris, Imed (2021) The effect of manganese IV oxide doping on the optical and elastic properties of calcium borate glass derived from waste chicken eggshell. Optical Materials, 121. pp. 1-9. ISSN 0925-3467; ESSN: 1873-1252 https://www.sciencedirect.com/science/article/pii/S0925346721007400 10.1016/j.optmat.2021.111540
institution Universiti Putra Malaysia
building UPM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Putra Malaysia
content_source UPM Institutional Repository
url_provider http://psasir.upm.edu.my/
description The extraction of CaO from waste eggshell can be used to produce new product known as calcium borate glass doped manganese (IV) oxide. A tertiary (B2O3)0.6 [(CaO)0.4]1-x (MnO2)x glass system with 0.010 ≥ x ≥ 0 M fraction were prepared using conventional melt-quenching technique. XRF spectroscopy confirms CaO as the main constituent in the calcined eggshell. XRD spectra unveils the two amorphous humps of the glass samples. FTIR analysis reveals the typical features of CaCO3 and B2O3 network. The density has opposite behaviour with molar volume as MnO2 content increases. Next, the optical band gap and refractive index are evidencing the formation of non-bridging oxygen in the glass matrix. The present glass system also has low polarizability, acidic in nature and have tendency to metallizing. The elastic properties of glass samples were determined using the ultrasonic technique. Elastic moduli such as longitudinal modulus, shear modulus, Young's modulus, bulk modulus, Poisson's ratio and hardness of the glass system were discussed.
format Article
author A.S., Asyikin
A.A., Shamimi
S.N., Nazrin
M.K., Halimah
Boukhris, Imed
spellingShingle A.S., Asyikin
A.A., Shamimi
S.N., Nazrin
M.K., Halimah
Boukhris, Imed
The effect of manganese IV oxide doping on the optical and elastic properties of calcium borate glass derived from waste chicken eggshell
author_facet A.S., Asyikin
A.A., Shamimi
S.N., Nazrin
M.K., Halimah
Boukhris, Imed
author_sort A.S., Asyikin
title The effect of manganese IV oxide doping on the optical and elastic properties of calcium borate glass derived from waste chicken eggshell
title_short The effect of manganese IV oxide doping on the optical and elastic properties of calcium borate glass derived from waste chicken eggshell
title_full The effect of manganese IV oxide doping on the optical and elastic properties of calcium borate glass derived from waste chicken eggshell
title_fullStr The effect of manganese IV oxide doping on the optical and elastic properties of calcium borate glass derived from waste chicken eggshell
title_full_unstemmed The effect of manganese IV oxide doping on the optical and elastic properties of calcium borate glass derived from waste chicken eggshell
title_sort effect of manganese iv oxide doping on the optical and elastic properties of calcium borate glass derived from waste chicken eggshell
publisher Elsevier BV
publishDate 2021
url http://psasir.upm.edu.my/id/eprint/95394/
https://www.sciencedirect.com/science/article/pii/S0925346721007400
_version_ 1754531215192358912
score 13.211869

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