Role of virgin coconut oil VCO as co-extractant for obtaining xanthones from mangosteen Garcinia mangostana pericarp with supercritical carbon dioxide extraction

Virgin coconut oil (VCO) was used as co-extractant with supercritical carbon dioxide (scCO2) extraction for obtaining xanthones from mangosteen pericarp (MP) without organic co-solvents. In each experiment, 120 g of dried MP that had median particle sizes of 0.85 mm was used. Extraction of MP with 4...

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Bibliographic Details
Main Authors: Siew, Lee Kok, Wan, Jun Lee, Smith, Richard Lee, Suleiman, Norhidayah, Na Jom, Kriskamol, Vangnai, Kanithaporn, Sharaai, Amir Hamzah, Gun, Hean Chong
Format: Article
Language:English
Published: Elsevier BV 2021
Online Access:http://psasir.upm.edu.my/id/eprint/94995/1/Role%20of%20virgin%20coconut%20oil%20VCO%20as%20co-extractant%20for%20obtaining%20xanthones%20from%20mangosteen%20Garcinia%20mangostana%20pericarp%20with%20supercritical%20carbon%20dioxide%20extraction.pdf
http://psasir.upm.edu.my/id/eprint/94995/
https://www.sciencedirect.com/science/article/pii/S0896844621001455
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Summary:Virgin coconut oil (VCO) was used as co-extractant with supercritical carbon dioxide (scCO2) extraction for obtaining xanthones from mangosteen pericarp (MP) without organic co-solvents. In each experiment, 120 g of dried MP that had median particle sizes of 0.85 mm was used. Extraction of MP with 40% VCO co-extractant using scCO2 (1.08 kg/h) for 420 min at 430 bar and 70 °C gave α-mangostin (32.2 mg/g), γ-mangostin (7.2 mg/g), xanthones (28.2 mg/g) in extract and an extraction yield of 31%. The role of VCO is that it promotes dissolution of xanthones and mass transfer into the scCO2 phase as elucidated with the Pardo-Castaño model. The Lentz equation was generalized in terms of (P, T, %VCO, ρCO2) to correlate all extraction curve data to within 7.4% and to estimate extraction yield crossover regions. Xanthones can be separated from mangosteen pericarp with VCO and scCO2 extraction without organic co-solvents.