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Methoxy-functionalized mesostructured stable carbon catalysts for effective biodiesel production from non-edible feedstock

The nano-architectured Ca(OCH3)2/AC catalyst was prepared through hydrothermal process. In this work, the controlled structural growth and morphology of nano-architectured Ca(OCH3)2/AC catalyst were reported and their conversion activity from non-edible oil source (crude jatropha oil) to biodiesel p...

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Main Authors: Teo, Siow Hwa, Islam, Aminul, Ng, Chi Huey, Mansir, Nasar, Ma, Ting Li, Choong, Thomas Shean Yaw, Yap, Taufiq Yun Hin
Format: Article
Language:English
Published: Elsevier 2018
Online Access:http://psasir.upm.edu.my/id/eprint/74954/1/Methoxy-functionalized%20mesostructured%20stable%20carbon%20catalysts%20for%20effective%20biodiesel%20production%20from%20non-edible%20feedstock.pdf
http://psasir.upm.edu.my/id/eprint/74954/
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spelling my.upm.eprints.749542020-04-20T17:14:56Z http://psasir.upm.edu.my/id/eprint/74954/ Methoxy-functionalized mesostructured stable carbon catalysts for effective biodiesel production from non-edible feedstock Teo, Siow Hwa Islam, Aminul Ng, Chi Huey Mansir, Nasar Ma, Ting Li Choong, Thomas Shean Yaw Yap, Taufiq Yun Hin The nano-architectured Ca(OCH3)2/AC catalyst was prepared through hydrothermal process. In this work, the controlled structural growth and morphology of nano-architectured Ca(OCH3)2/AC catalyst were reported and their conversion activity from non-edible oil source (crude jatropha oil) to biodiesel production was also evaluated in this study. Remarkable difference in catalytic activity for biodiesel production among these samples was observed. It shows that the catalytic properties of the hydrothermal synthesized catalyst was improved by exposing the catalytic active OCH3 predominantly on the surface of catalyst. The 0.4-OMe/AC catalyst with methanol/oil molar ratio of 12:1, agitation speed of 600 rpm and 3 wt% of catalyst provided maximum biodiesel yield of 98.65% at 60 °C for 1 h reaction time. The catalyst exhibited outstanding stability where negligible Ca2+ leaching was detected and the recovered catalyst was reused in 8 successive cycles without significant loss in activity. Therefore, this kind of bimodal porosity catalyst is said to exhibit very high activity, stability, and recyclability, which entailed potential saving and affordable biodiesel production possibilities. Elsevier 2018-02 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/74954/1/Methoxy-functionalized%20mesostructured%20stable%20carbon%20catalysts%20for%20effective%20biodiesel%20production%20from%20non-edible%20feedstock.pdf Teo, Siow Hwa and Islam, Aminul and Ng, Chi Huey and Mansir, Nasar and Ma, Ting Li and Choong, Thomas Shean Yaw and Yap, Taufiq Yun Hin (2018) Methoxy-functionalized mesostructured stable carbon catalysts for effective biodiesel production from non-edible feedstock. Chemical Engineering Journal, 334. 1851 - 1868. ISSN 1385-8947 10.1016/j.cej.2017.11.110
institution Universiti Putra Malaysia
building UPM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Putra Malaysia
content_source UPM Institutional Repository
url_provider http://psasir.upm.edu.my/
language English
description The nano-architectured Ca(OCH3)2/AC catalyst was prepared through hydrothermal process. In this work, the controlled structural growth and morphology of nano-architectured Ca(OCH3)2/AC catalyst were reported and their conversion activity from non-edible oil source (crude jatropha oil) to biodiesel production was also evaluated in this study. Remarkable difference in catalytic activity for biodiesel production among these samples was observed. It shows that the catalytic properties of the hydrothermal synthesized catalyst was improved by exposing the catalytic active OCH3 predominantly on the surface of catalyst. The 0.4-OMe/AC catalyst with methanol/oil molar ratio of 12:1, agitation speed of 600 rpm and 3 wt% of catalyst provided maximum biodiesel yield of 98.65% at 60 °C for 1 h reaction time. The catalyst exhibited outstanding stability where negligible Ca2+ leaching was detected and the recovered catalyst was reused in 8 successive cycles without significant loss in activity. Therefore, this kind of bimodal porosity catalyst is said to exhibit very high activity, stability, and recyclability, which entailed potential saving and affordable biodiesel production possibilities.
format Article
author Teo, Siow Hwa
Islam, Aminul
Ng, Chi Huey
Mansir, Nasar
Ma, Ting Li
Choong, Thomas Shean Yaw
Yap, Taufiq Yun Hin
spellingShingle Teo, Siow Hwa
Islam, Aminul
Ng, Chi Huey
Mansir, Nasar
Ma, Ting Li
Choong, Thomas Shean Yaw
Yap, Taufiq Yun Hin
Methoxy-functionalized mesostructured stable carbon catalysts for effective biodiesel production from non-edible feedstock
author_facet Teo, Siow Hwa
Islam, Aminul
Ng, Chi Huey
Mansir, Nasar
Ma, Ting Li
Choong, Thomas Shean Yaw
Yap, Taufiq Yun Hin
author_sort Teo, Siow Hwa
title Methoxy-functionalized mesostructured stable carbon catalysts for effective biodiesel production from non-edible feedstock
title_short Methoxy-functionalized mesostructured stable carbon catalysts for effective biodiesel production from non-edible feedstock
title_full Methoxy-functionalized mesostructured stable carbon catalysts for effective biodiesel production from non-edible feedstock
title_fullStr Methoxy-functionalized mesostructured stable carbon catalysts for effective biodiesel production from non-edible feedstock
title_full_unstemmed Methoxy-functionalized mesostructured stable carbon catalysts for effective biodiesel production from non-edible feedstock
title_sort methoxy-functionalized mesostructured stable carbon catalysts for effective biodiesel production from non-edible feedstock
publisher Elsevier
publishDate 2018
url http://psasir.upm.edu.my/id/eprint/74954/1/Methoxy-functionalized%20mesostructured%20stable%20carbon%20catalysts%20for%20effective%20biodiesel%20production%20from%20non-edible%20feedstock.pdf
http://psasir.upm.edu.my/id/eprint/74954/
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score 13.211869

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