表紙画像

Kinetic study of lipase-catalyzed glycerolysis of palm olein using Lipozyme TLIM in solvent-free system

Diacylglycerol (DAG) and monoacylglycerol (MAG) are two natural occurring minor components found in most edible fats and oils. These compounds have gained increasing market demand owing to their unique physicochemical properties. Enzymatic glycerolysis in solvent-free system might be a promising app...

詳細記述

保存先:
書誌詳細
主要な著者: Choong, Thomas Shean Yaw, Yeoh, Chiou Moi, Phuah, Eng Tong, Siew, Wai Lin, Lee, Yee Ying, Tang, Teck Kim, Abdullah, Luqman Chuah
フォーマット: 論文
言語:English
出版事項: Public Library of Science 2018
オンライン･アクセス:http://psasir.upm.edu.my/id/eprint/70961/1/journal.pone.0192375.pdf
http://psasir.upm.edu.my/id/eprint/70961/
https://journals.plos.org/plosone/article?id=10.1371/journal.pone.0192375
タグ: タグ追加
タグなし, このレコードへの初めてのタグを付けませんか!
id my.upm.eprints.70961
record_format eprints
spelling my.upm.eprints.709612019-09-10T06:14:21Z http://psasir.upm.edu.my/id/eprint/70961/ Kinetic study of lipase-catalyzed glycerolysis of palm olein using Lipozyme TLIM in solvent-free system Choong, Thomas Shean Yaw Yeoh, Chiou Moi Phuah, Eng Tong Siew, Wai Lin Lee, Yee Ying Tang, Teck Kim Abdullah, Luqman Chuah Diacylglycerol (DAG) and monoacylglycerol (MAG) are two natural occurring minor components found in most edible fats and oils. These compounds have gained increasing market demand owing to their unique physicochemical properties. Enzymatic glycerolysis in solvent-free system might be a promising approach in producing DAG and MAG-enriched oil. Understanding on glycerolysis mechanism is therefore of great importance for process simulation and optimization. In this study, a commercial immobilized lipase (Lipozyme TL IM) was used to catalyze the glycerolysis reaction. The kinetics of enzymatic glycerolysis reaction between triacylglycerol (TAG) and glycerol (G) were modeled using rate equation with unsteady-state assumption. Ternary complex, ping-pong bi-bi and complex ping-pong bi-bi models were proposed and compared in this study. The reaction rate constants were determined using non-linear regression and sum of square errors (SSE) were minimized. Present work revealed satisfactory agreement between experimental data and the result generated by complex ping-pong bi-bi model as compared to other models. The proposed kinetic model would facilitate understanding on enzymatic glycerolysis for DAG and MAG production and design optimization of a pilot-scale reactor. Public Library of Science 2018 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/70961/1/journal.pone.0192375.pdf Choong, Thomas Shean Yaw and Yeoh, Chiou Moi and Phuah, Eng Tong and Siew, Wai Lin and Lee, Yee Ying and Tang, Teck Kim and Abdullah, Luqman Chuah (2018) Kinetic study of lipase-catalyzed glycerolysis of palm olein using Lipozyme TLIM in solvent-free system. PLOS ONE, 13 (2). art. no. e0192375. pp. 1-13. ISSN 1932-6203 https://journals.plos.org/plosone/article?id=10.1371/journal.pone.0192375 10.1371/journal.pone.0192375
institution Universiti Putra Malaysia
building UPM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Putra Malaysia
content_source UPM Institutional Repository
url_provider http://psasir.upm.edu.my/
language English
description Diacylglycerol (DAG) and monoacylglycerol (MAG) are two natural occurring minor components found in most edible fats and oils. These compounds have gained increasing market demand owing to their unique physicochemical properties. Enzymatic glycerolysis in solvent-free system might be a promising approach in producing DAG and MAG-enriched oil. Understanding on glycerolysis mechanism is therefore of great importance for process simulation and optimization. In this study, a commercial immobilized lipase (Lipozyme TL IM) was used to catalyze the glycerolysis reaction. The kinetics of enzymatic glycerolysis reaction between triacylglycerol (TAG) and glycerol (G) were modeled using rate equation with unsteady-state assumption. Ternary complex, ping-pong bi-bi and complex ping-pong bi-bi models were proposed and compared in this study. The reaction rate constants were determined using non-linear regression and sum of square errors (SSE) were minimized. Present work revealed satisfactory agreement between experimental data and the result generated by complex ping-pong bi-bi model as compared to other models. The proposed kinetic model would facilitate understanding on enzymatic glycerolysis for DAG and MAG production and design optimization of a pilot-scale reactor.
format Article
author Choong, Thomas Shean Yaw
Yeoh, Chiou Moi
Phuah, Eng Tong
Siew, Wai Lin
Lee, Yee Ying
Tang, Teck Kim
Abdullah, Luqman Chuah
spellingShingle Choong, Thomas Shean Yaw
Yeoh, Chiou Moi
Phuah, Eng Tong
Siew, Wai Lin
Lee, Yee Ying
Tang, Teck Kim
Abdullah, Luqman Chuah
Kinetic study of lipase-catalyzed glycerolysis of palm olein using Lipozyme TLIM in solvent-free system
author_facet Choong, Thomas Shean Yaw
Yeoh, Chiou Moi
Phuah, Eng Tong
Siew, Wai Lin
Lee, Yee Ying
Tang, Teck Kim
Abdullah, Luqman Chuah
author_sort Choong, Thomas Shean Yaw
title Kinetic study of lipase-catalyzed glycerolysis of palm olein using Lipozyme TLIM in solvent-free system
title_short Kinetic study of lipase-catalyzed glycerolysis of palm olein using Lipozyme TLIM in solvent-free system
title_full Kinetic study of lipase-catalyzed glycerolysis of palm olein using Lipozyme TLIM in solvent-free system
title_fullStr Kinetic study of lipase-catalyzed glycerolysis of palm olein using Lipozyme TLIM in solvent-free system
title_full_unstemmed Kinetic study of lipase-catalyzed glycerolysis of palm olein using Lipozyme TLIM in solvent-free system
title_sort kinetic study of lipase-catalyzed glycerolysis of palm olein using lipozyme tlim in solvent-free system
publisher Public Library of Science
publishDate 2018
url http://psasir.upm.edu.my/id/eprint/70961/1/journal.pone.0192375.pdf
http://psasir.upm.edu.my/id/eprint/70961/
https://journals.plos.org/plosone/article?id=10.1371/journal.pone.0192375
_version_ 1646008967398162432
score 13.251813

類似資料