Photoactive hybrid film photocatalyst of polyethersulfone-ZnO for the degradation of methyl orange dye: kinetic study and operational parameters

A facile and effective technique to immobilize photocatalyst nanoparticles by incorporating zinc oxide (ZnO) into polyethersulfone polymeric films by means of a phase inversion technique is reported. The degradation study of methyl orange (MO) dye was performed using a series of ZnO-embedded polymer...

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Bibliographic Details
Main Authors: Mohd Hir, Zul Adlan, Abdullah, Abdul Halim, Zainal, Zulkarnain, Lim, Hong Ngee
Format: Article
Language:English
Published: MDPI AG 2017
Online Access:http://psasir.upm.edu.my/id/eprint/62736/1/Photoactive%20hybrid.pdf
http://psasir.upm.edu.my/id/eprint/62736/
https://www.mdpi.com/2073-4344/7/11/313/htm
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Summary:A facile and effective technique to immobilize photocatalyst nanoparticles by incorporating zinc oxide (ZnO) into polyethersulfone polymeric films by means of a phase inversion technique is reported. The degradation study of methyl orange (MO) dye was performed using a series of ZnO-embedded polymer hybrid systems. The photoactivity of the films increased in parallel with increased ZnO loading up to 17 wt%. The photodegradation process followed a pseudo first-order kinetics with an achievement of almost 100% MO removal in original conditions. The PZ-17 film demonstrated an excellent and comparable degradation performance up to five cycles, signifying the reliability of the film photocatalyst against ultraviolet irradiation and degradation.