The correlation of blue shift of photoluminescence and morphology of silicon nanoporous

Porous silicon with diameters ranging from 6.41 to 7.12 nm were synthesized via electrochemical etching by varied anodization current density in ethanoic solutions containing aqueous hydrofluoric acid up to 65mA/cm2.The luminescence properties of the nanoporous at room temperature were analyzed via...

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Bibliographic Details
Main Authors: Al-Jumaili, Batool Eneaze Bandar, Talib, Zainal Abidin, Liew, Josephine Ying Chyi, Paiman, Suriati, Ahmed, Naser Mahmoud, Al-Jumaily, Abdulmajeed Hammadi Jasim, Ramizy, Asmiet, Abdulateef, Sinan A., Muh'd, Ibrahim Bagudo, Mofdal, Manahil Elnoor Edam
Format: Conference or Workshop Item
Language:English
Published: AIP Publishing 2015
Online Access:http://psasir.upm.edu.my/id/eprint/57548/1/The%20correlation%20of%20blue%20shift%20of%20photoluminescence%20and%20morphology%20of%20silicon%20nanoporous.pdf
http://psasir.upm.edu.my/id/eprint/57548/
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Summary:Porous silicon with diameters ranging from 6.41 to 7.12 nm were synthesized via electrochemical etching by varied anodization current density in ethanoic solutions containing aqueous hydrofluoric acid up to 65mA/cm2.The luminescence properties of the nanoporous at room temperature were analyzed via photoluminescence spectroscopy. Photoluminescence PL spectra exhibit a broad emission band in the range of 360-700 nm photon energy. The PL spectrum has a blue shift in varied anodization current density; the blue shift incremented as the existing of anodization although the intensity decreased. The current blue shift is owning to alteration of silicon nanocrystal structure at the superficies. The superficial morphology of the PS layers consists of unified and orderly distribution of nanocrystalline Si structures, have high porosity around (93.75%) and high thickness 39.52 µm.