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Comprehensive study on effect of sintering temperature on the physical, structural and optical properties of Er3+ doped ZnO-GSLS glasses

The Er3+ doped zinc soda lime silica (ZnO-GSLS) glass system was prepared by the conventional melt-quenching technique using waste green soda lime silica (GSLS) glass, zinc oxide (ZnO) and erbium oxide (Er2O3) powder as starting materials. Er3+ doped willemite based glass-ceramics (Zn2SiO4:Er3+) wer...

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Main Authors: Abdul Rashid, Siti Syuhaida, Ab Aziz, Sidek, Matori, Khamirul Amin, Mohd Zaid, Mohd Hafiz, Mohamed, Nurzilla
Format: Article
Language:English
Published: Elsevier 2017
Online Access:http://psasir.upm.edu.my/id/eprint/57011/1/57011.pdf
http://psasir.upm.edu.my/id/eprint/57011/
http://www.sciencedirect.com/science/article/pii/S2211379717304333#!
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spelling my.upm.eprints.570112017-09-07T03:09:58Z http://psasir.upm.edu.my/id/eprint/57011/ Comprehensive study on effect of sintering temperature on the physical, structural and optical properties of Er3+ doped ZnO-GSLS glasses Abdul Rashid, Siti Syuhaida Ab Aziz, Sidek Matori, Khamirul Amin Mohd Zaid, Mohd Hafiz Mohamed, Nurzilla The Er3+ doped zinc soda lime silica (ZnO-GSLS) glass system was prepared by the conventional melt-quenching technique using waste green soda lime silica (GSLS) glass, zinc oxide (ZnO) and erbium oxide (Er2O3) powder as starting materials. Er3+ doped willemite based glass-ceramics (Zn2SiO4:Er3+) were derived from this precursor glass by a controlled sintering process. The effect of sintering temperature on the density and linear shrinkage of the sample was investigated. XRD analysis revealed the presence of thermodynamically stable zinc orthosilicate (α-Zn2SiO4) phase at sintering temperatures above 700 °C. FESEM image shows the presence of densely packed grains as the sintering temperature increase. FTIR spectroscopy was used to observe the structural of SiO4 and ZnO4 groups in the formation of willemite phase evolution. The UV–Vis absorption spectra reveals four peaks centered at excitation of electron from ground state 4I15/2 to 4G11/2 (∼363 nm), 4F7/2 (∼488 nm), 2H11/2 (∼523 nm), and 4F9/2 (∼652 nm). PL spectroscopy measurements were performed at room temperature using 385 nm excitation wavelengths. Enhancement of the Er3+ luminescence was observed with the progression of sintering temperature. Elsevier 2017 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/57011/1/57011.pdf Abdul Rashid, Siti Syuhaida and Ab Aziz, Sidek and Matori, Khamirul Amin and Mohd Zaid, Mohd Hafiz and Mohamed, Nurzilla (2017) Comprehensive study on effect of sintering temperature on the physical, structural and optical properties of Er3+ doped ZnO-GSLS glasses. Results in Physics, 7. pp. 2224-2231. ISSN 2211-3797 http://www.sciencedirect.com/science/article/pii/S2211379717304333#! 10.1016/j.rinp.2017.04.004
institution Universiti Putra Malaysia
building UPM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Putra Malaysia
content_source UPM Institutional Repository
url_provider http://psasir.upm.edu.my/
language English
description The Er3+ doped zinc soda lime silica (ZnO-GSLS) glass system was prepared by the conventional melt-quenching technique using waste green soda lime silica (GSLS) glass, zinc oxide (ZnO) and erbium oxide (Er2O3) powder as starting materials. Er3+ doped willemite based glass-ceramics (Zn2SiO4:Er3+) were derived from this precursor glass by a controlled sintering process. The effect of sintering temperature on the density and linear shrinkage of the sample was investigated. XRD analysis revealed the presence of thermodynamically stable zinc orthosilicate (α-Zn2SiO4) phase at sintering temperatures above 700 °C. FESEM image shows the presence of densely packed grains as the sintering temperature increase. FTIR spectroscopy was used to observe the structural of SiO4 and ZnO4 groups in the formation of willemite phase evolution. The UV–Vis absorption spectra reveals four peaks centered at excitation of electron from ground state 4I15/2 to 4G11/2 (∼363 nm), 4F7/2 (∼488 nm), 2H11/2 (∼523 nm), and 4F9/2 (∼652 nm). PL spectroscopy measurements were performed at room temperature using 385 nm excitation wavelengths. Enhancement of the Er3+ luminescence was observed with the progression of sintering temperature.
format Article
author Abdul Rashid, Siti Syuhaida
Ab Aziz, Sidek
Matori, Khamirul Amin
Mohd Zaid, Mohd Hafiz
Mohamed, Nurzilla
spellingShingle Abdul Rashid, Siti Syuhaida
Ab Aziz, Sidek
Matori, Khamirul Amin
Mohd Zaid, Mohd Hafiz
Mohamed, Nurzilla
Comprehensive study on effect of sintering temperature on the physical, structural and optical properties of Er3+ doped ZnO-GSLS glasses
author_facet Abdul Rashid, Siti Syuhaida
Ab Aziz, Sidek
Matori, Khamirul Amin
Mohd Zaid, Mohd Hafiz
Mohamed, Nurzilla
author_sort Abdul Rashid, Siti Syuhaida
title Comprehensive study on effect of sintering temperature on the physical, structural and optical properties of Er3+ doped ZnO-GSLS glasses
title_short Comprehensive study on effect of sintering temperature on the physical, structural and optical properties of Er3+ doped ZnO-GSLS glasses
title_full Comprehensive study on effect of sintering temperature on the physical, structural and optical properties of Er3+ doped ZnO-GSLS glasses
title_fullStr Comprehensive study on effect of sintering temperature on the physical, structural and optical properties of Er3+ doped ZnO-GSLS glasses
title_full_unstemmed Comprehensive study on effect of sintering temperature on the physical, structural and optical properties of Er3+ doped ZnO-GSLS glasses
title_sort comprehensive study on effect of sintering temperature on the physical, structural and optical properties of er3+ doped zno-gsls glasses
publisher Elsevier
publishDate 2017
url http://psasir.upm.edu.my/id/eprint/57011/1/57011.pdf
http://psasir.upm.edu.my/id/eprint/57011/
http://www.sciencedirect.com/science/article/pii/S2211379717304333#!
_version_ 1643836359570358272
score 13.211869

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