Activated carbon derived from peat soil as a framework for the preparation of shape-stabilized phase change material

This work focuses on the preparation of AC (activated carbon) through a physical activation method using peat soil as a precursor, followed by the use of the AC as an inorganic framework for the preparation of SPCM (shape-stabilized phase change material). The SPCM, composed of n-octadecane as the c...

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Bibliographic Details
Main Authors: Khadiran, Tumirah, Hussein, Mohd. Zobir, Zainal, Zulkarnain, Rosli, Rafeadah
Format: Article
Language:English
Published: Elsevier 2015
Online Access:http://psasir.upm.edu.my/id/eprint/43646/1/Activated%20carbon%20derived%20from%20peat%20soil%20as%20a%20framework%20for%20the%20preparation%20of%20shape-stabilized%20phase%20change%20material.pdf
http://psasir.upm.edu.my/id/eprint/43646/
http://www.sciencedirect.com/science/article/pii/S036054421500081X
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Summary:This work focuses on the preparation of AC (activated carbon) through a physical activation method using peat soil as a precursor, followed by the use of the AC as an inorganic framework for the preparation of SPCM (shape-stabilized phase change material). The SPCM, composed of n-octadecane as the core and AC pores as a framework, was fabricated by a simple impregnation method, with the mass fraction of n-octadecane varying from 10 to 90 wt.%. The AC has a specific surface area of 893 m2 g−1 and an average pore size of 22 Å. The field emission scanning electron microscope images and nitrogen gas adsorption-desorption isotherms shows that the n-octadecane was actually encapsulated into the AC pores. The melting and freezing temperatures of the composite PCM (phase change material) were 30.9 °C and 24.1 °C, respectively, and its corresponding latent heat values were 95.4 Jg−1 and 99.6 Jg−1, respectively. The composite shows a good thermal reliability, even after 1000 melting/freezing cycles. The present research provided a new SPCM material for thermal energy storage as well as some new insights into the design of composite PCM by tailoring the pore structure of AC derived from peat soil, a natural resource