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Development of novel low-cost quaternized adsorbent from palm oil agriculture waste for reactive dye removal

An attempt was made to chemically modify palm kernel shell (MPKS) to increase adsorption affinity towards Reactive Black 5 (RB5). Granulated palm kernel shell (PKS) was quaternized successfully by treating with N-(3-chloro-2-hydroxypropyl)trimethylammonium chloride under alkaline conditions and was...

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Main Authors: Koay, Yin Shin, Ahamad, Intan Salwani, Mobarekeh, Mohsen Nourouzi, Abdullah, Luqman Chuah, Choong, Thomas Shean Yaw
Format: Article
Language:English
Published: College of Natural Resources, North Carolina State University 2014
Online Access:http://psasir.upm.edu.my/id/eprint/37079/1/Development%20of%20novel%20low.pdf
http://psasir.upm.edu.my/id/eprint/37079/
http://ojs.cnr.ncsu.edu/index.php/BioRes/article/view/BioRes_09_1_66_Koay_Quaternized_Adsorbent_Palm_Oil
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spelling my.upm.eprints.370792015-09-18T00:01:40Z http://psasir.upm.edu.my/id/eprint/37079/ Development of novel low-cost quaternized adsorbent from palm oil agriculture waste for reactive dye removal Koay, Yin Shin Ahamad, Intan Salwani Mobarekeh, Mohsen Nourouzi Abdullah, Luqman Chuah Choong, Thomas Shean Yaw An attempt was made to chemically modify palm kernel shell (MPKS) to increase adsorption affinity towards Reactive Black 5 (RB5). Granulated palm kernel shell (PKS) was quaternized successfully by treating with N-(3-chloro-2-hydroxypropyl)trimethylammonium chloride under alkaline conditions and was characterized. Surface characterization by Scanning Electron Microscopy (SEM) and BET analysis confirmed the surface pore enlargement from mesospores to macropores after modification. Fourier Transform-Infrared (FTIR) Spectrometer and CHN analysis revealed that the quaternary ammonia group (NR4+) was successfully reacted on MPKS fiber. pH 4 is the optimum for removal of RB5 on MPKS. Equilibrium isotherms were analyzed by the Langmuir, Freundlich, and Redlich-Peterson models. The Redlich-Peterson model was found to fit well with the data. The maximum adsorption capacity of MPKS was 207.5 mg/g for adsorption of RB5. College of Natural Resources, North Carolina State University 2014 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/37079/1/Development%20of%20novel%20low.pdf Koay, Yin Shin and Ahamad, Intan Salwani and Mobarekeh, Mohsen Nourouzi and Abdullah, Luqman Chuah and Choong, Thomas Shean Yaw (2014) Development of novel low-cost quaternized adsorbent from palm oil agriculture waste for reactive dye removal. BioResources, 9 (1). pp. 66-85. ISSN 1930-2126 http://ojs.cnr.ncsu.edu/index.php/BioRes/article/view/BioRes_09_1_66_Koay_Quaternized_Adsorbent_Palm_Oil
institution Universiti Putra Malaysia
building UPM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Putra Malaysia
content_source UPM Institutional Repository
url_provider http://psasir.upm.edu.my/
language English
description An attempt was made to chemically modify palm kernel shell (MPKS) to increase adsorption affinity towards Reactive Black 5 (RB5). Granulated palm kernel shell (PKS) was quaternized successfully by treating with N-(3-chloro-2-hydroxypropyl)trimethylammonium chloride under alkaline conditions and was characterized. Surface characterization by Scanning Electron Microscopy (SEM) and BET analysis confirmed the surface pore enlargement from mesospores to macropores after modification. Fourier Transform-Infrared (FTIR) Spectrometer and CHN analysis revealed that the quaternary ammonia group (NR4+) was successfully reacted on MPKS fiber. pH 4 is the optimum for removal of RB5 on MPKS. Equilibrium isotherms were analyzed by the Langmuir, Freundlich, and Redlich-Peterson models. The Redlich-Peterson model was found to fit well with the data. The maximum adsorption capacity of MPKS was 207.5 mg/g for adsorption of RB5.
format Article
author Koay, Yin Shin
Ahamad, Intan Salwani
Mobarekeh, Mohsen Nourouzi
Abdullah, Luqman Chuah
Choong, Thomas Shean Yaw
spellingShingle Koay, Yin Shin
Ahamad, Intan Salwani
Mobarekeh, Mohsen Nourouzi
Abdullah, Luqman Chuah
Choong, Thomas Shean Yaw
Development of novel low-cost quaternized adsorbent from palm oil agriculture waste for reactive dye removal
author_facet Koay, Yin Shin
Ahamad, Intan Salwani
Mobarekeh, Mohsen Nourouzi
Abdullah, Luqman Chuah
Choong, Thomas Shean Yaw
author_sort Koay, Yin Shin
title Development of novel low-cost quaternized adsorbent from palm oil agriculture waste for reactive dye removal
title_short Development of novel low-cost quaternized adsorbent from palm oil agriculture waste for reactive dye removal
title_full Development of novel low-cost quaternized adsorbent from palm oil agriculture waste for reactive dye removal
title_fullStr Development of novel low-cost quaternized adsorbent from palm oil agriculture waste for reactive dye removal
title_full_unstemmed Development of novel low-cost quaternized adsorbent from palm oil agriculture waste for reactive dye removal
title_sort development of novel low-cost quaternized adsorbent from palm oil agriculture waste for reactive dye removal
publisher College of Natural Resources, North Carolina State University
publishDate 2014
url http://psasir.upm.edu.my/id/eprint/37079/1/Development%20of%20novel%20low.pdf
http://psasir.upm.edu.my/id/eprint/37079/
http://ojs.cnr.ncsu.edu/index.php/BioRes/article/view/BioRes_09_1_66_Koay_Quaternized_Adsorbent_Palm_Oil
_version_ 1643831908387258368
score 13.211869

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