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Synthesis of bio-based monomer from vegetable oil fatty acids and design of functionalized greener polyester

In order to design sustainable materials from vegetable oil-based fatty acids, we propose herewith a method to obtain unsaturated dicarboxylic acids as a polymerizable monomer through metathesis reaction of oleic and linoleic acids with the 2nd generation Grubbs catalyst. Subsequently, functional gr...

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Main Authors: Abd. Rahim, Noor Farisha, Watanabe, Kohtaro, Ariffin, Hidayah, Andou, Yoshito, Hassan, Mohd Ali, Shirai, Yoshihito
Format: Article
Published: Chemical Society of Japan 2014
Online Access:http://psasir.upm.edu.my/id/eprint/35576/
https://www.jstage.jst.go.jp/article/cl/43/9/43_140471/_article
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spelling my.upm.eprints.355762016-01-18T01:09:04Z http://psasir.upm.edu.my/id/eprint/35576/ Synthesis of bio-based monomer from vegetable oil fatty acids and design of functionalized greener polyester Abd. Rahim, Noor Farisha Watanabe, Kohtaro Ariffin, Hidayah Andou, Yoshito Hassan, Mohd Ali Shirai, Yoshihito In order to design sustainable materials from vegetable oil-based fatty acids, we propose herewith a method to obtain unsaturated dicarboxylic acids as a polymerizable monomer through metathesis reaction of oleic and linoleic acids with the 2nd generation Grubbs catalyst. Subsequently, functional green polyester was produced from dicarboxylic acids and aromatic diol. Dicarboxylic acid having similar structure i.e., octadec-9-enedioic acid was successfully obtained from metathesis of both oleic and linoleic acids. Condensation polymerization of octadec-9-enedioic acid with 1,6-hexanediol and 4,4′-biphenol was carried out and it was shown that polymer with aromatic backbone had higher glass-transition temperature than aliphatic polyester. Chemical Society of Japan 2014 Article PeerReviewed Abd. Rahim, Noor Farisha and Watanabe, Kohtaro and Ariffin, Hidayah and Andou, Yoshito and Hassan, Mohd Ali and Shirai, Yoshihito (2014) Synthesis of bio-based monomer from vegetable oil fatty acids and design of functionalized greener polyester. Chemistry Letters, 43 (9). pp. 1517-1519. ISSN 0366-7022; ESSN: 1348-0715 https://www.jstage.jst.go.jp/article/cl/43/9/43_140471/_article 10.1246/cl.140471
institution Universiti Putra Malaysia
building UPM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Putra Malaysia
content_source UPM Institutional Repository
url_provider http://psasir.upm.edu.my/
description In order to design sustainable materials from vegetable oil-based fatty acids, we propose herewith a method to obtain unsaturated dicarboxylic acids as a polymerizable monomer through metathesis reaction of oleic and linoleic acids with the 2nd generation Grubbs catalyst. Subsequently, functional green polyester was produced from dicarboxylic acids and aromatic diol. Dicarboxylic acid having similar structure i.e., octadec-9-enedioic acid was successfully obtained from metathesis of both oleic and linoleic acids. Condensation polymerization of octadec-9-enedioic acid with 1,6-hexanediol and 4,4′-biphenol was carried out and it was shown that polymer with aromatic backbone had higher glass-transition temperature than aliphatic polyester.
format Article
author Abd. Rahim, Noor Farisha
Watanabe, Kohtaro
Ariffin, Hidayah
Andou, Yoshito
Hassan, Mohd Ali
Shirai, Yoshihito
spellingShingle Abd. Rahim, Noor Farisha
Watanabe, Kohtaro
Ariffin, Hidayah
Andou, Yoshito
Hassan, Mohd Ali
Shirai, Yoshihito
Synthesis of bio-based monomer from vegetable oil fatty acids and design of functionalized greener polyester
author_facet Abd. Rahim, Noor Farisha
Watanabe, Kohtaro
Ariffin, Hidayah
Andou, Yoshito
Hassan, Mohd Ali
Shirai, Yoshihito
author_sort Abd. Rahim, Noor Farisha
title Synthesis of bio-based monomer from vegetable oil fatty acids and design of functionalized greener polyester
title_short Synthesis of bio-based monomer from vegetable oil fatty acids and design of functionalized greener polyester
title_full Synthesis of bio-based monomer from vegetable oil fatty acids and design of functionalized greener polyester
title_fullStr Synthesis of bio-based monomer from vegetable oil fatty acids and design of functionalized greener polyester
title_full_unstemmed Synthesis of bio-based monomer from vegetable oil fatty acids and design of functionalized greener polyester
title_sort synthesis of bio-based monomer from vegetable oil fatty acids and design of functionalized greener polyester
publisher Chemical Society of Japan
publishDate 2014
url http://psasir.upm.edu.my/id/eprint/35576/
https://www.jstage.jst.go.jp/article/cl/43/9/43_140471/_article
_version_ 1643831494775406592
score 13.211869

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