RSM based optimization of chemical and enzymatic transesterification of palm oil: biodiesel production and assessment of exhaust emission levels
Current study presents RSM based optimized production of biodiesel from palm oil using chemical and enzymatic transesterification. The emission behavior of biodiesel and its blends, namely, POB-5, POB-20, POB-40, POB-50, POB-80, and POB-100 was examined using diesel engine (equipped with tube well)....
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my.upm.eprints.353012015-12-31T05:07:34Z http://psasir.upm.edu.my/id/eprint/35301/ RSM based optimization of chemical and enzymatic transesterification of palm oil: biodiesel production and assessment of exhaust emission levels Mumtaz, Muhammad Waseem Mukhtar, Hamid Anwar, Farooq Saari, Nazamid Current study presents RSM based optimized production of biodiesel from palm oil using chemical and enzymatic transesterification. The emission behavior of biodiesel and its blends, namely, POB-5, POB-20, POB-40, POB-50, POB-80, and POB-100 was examined using diesel engine (equipped with tube well). Optimized palm oil fatty acid methyl esters (POFAMEs) yields were depicted to be , , and % for chemical transesterification catalyzed by NaOH, KOH, and NaOCH3, respectively, whereas for enzymatic transesterification reactions catalyzed by NOVOZYME-435 and A. n. lipase optimized biodiesel yields were and %, respectively. Distinct decrease in particulate matter (PM) and carbon monoxide (CO) levels was experienced in exhaust emissions from engine operating on biodiesel blends POB-5, POB-20, POB-40, POB-50, POB-80, and POB-100 comparative to conventional petroleum diesel. Percentage change in CO and PM emissions for different biodiesel blends ranged from −2.1 to −68.7% and −6.2 to −58.4%, respectively, relative to conventional diesel, whereas an irregular trend was observed for NOx emissions. Only POB-5 and POB-20 showed notable reductions, whereas all other blends (POB-40 to POB-100) showed slight increase in NOx emission levels from 2.6 to 5.5% comparative to petroleum diesel. Hindawi Publishing Corporation 2014 Article PeerReviewed Mumtaz, Muhammad Waseem and Mukhtar, Hamid and Anwar, Farooq and Saari, Nazamid (2014) RSM based optimization of chemical and enzymatic transesterification of palm oil: biodiesel production and assessment of exhaust emission levels. The Scientific World Journal, 2014. art. no. 526105. pp. 1-11. ISSN 2356-6140; ESSN: 1537-744X http://www.hindawi.com/journals/tswj/2014/526105/abs/ 10.1155/2014/526105 |
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Current study presents RSM based optimized production of biodiesel from palm oil using chemical and enzymatic transesterification. The emission behavior of biodiesel and its blends, namely, POB-5, POB-20, POB-40, POB-50, POB-80, and POB-100 was examined using diesel engine (equipped with tube well). Optimized palm oil fatty acid methyl esters (POFAMEs) yields were depicted to be , , and % for chemical transesterification catalyzed by NaOH, KOH, and NaOCH3, respectively, whereas for enzymatic transesterification reactions catalyzed by NOVOZYME-435 and A. n. lipase optimized biodiesel yields were and %, respectively. Distinct decrease in particulate matter (PM) and carbon monoxide (CO) levels was experienced in exhaust emissions from engine operating on biodiesel blends POB-5, POB-20, POB-40, POB-50, POB-80, and POB-100 comparative to conventional petroleum diesel. Percentage change in CO and PM emissions for different biodiesel blends ranged from −2.1 to −68.7% and −6.2 to −58.4%, respectively, relative to conventional diesel, whereas an irregular trend was observed for NOx emissions. Only POB-5 and POB-20 showed notable reductions, whereas all other blends (POB-40 to POB-100) showed slight increase in NOx emission levels from 2.6 to 5.5% comparative to petroleum diesel. |
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Article |
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Mumtaz, Muhammad Waseem Mukhtar, Hamid Anwar, Farooq Saari, Nazamid |
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Mumtaz, Muhammad Waseem Mukhtar, Hamid Anwar, Farooq Saari, Nazamid RSM based optimization of chemical and enzymatic transesterification of palm oil: biodiesel production and assessment of exhaust emission levels |
author_facet |
Mumtaz, Muhammad Waseem Mukhtar, Hamid Anwar, Farooq Saari, Nazamid |
author_sort |
Mumtaz, Muhammad Waseem |
title |
RSM based optimization of chemical and enzymatic transesterification of palm oil: biodiesel production and assessment of exhaust emission levels |
title_short |
RSM based optimization of chemical and enzymatic transesterification of palm oil: biodiesel production and assessment of exhaust emission levels |
title_full |
RSM based optimization of chemical and enzymatic transesterification of palm oil: biodiesel production and assessment of exhaust emission levels |
title_fullStr |
RSM based optimization of chemical and enzymatic transesterification of palm oil: biodiesel production and assessment of exhaust emission levels |
title_full_unstemmed |
RSM based optimization of chemical and enzymatic transesterification of palm oil: biodiesel production and assessment of exhaust emission levels |
title_sort |
rsm based optimization of chemical and enzymatic transesterification of palm oil: biodiesel production and assessment of exhaust emission levels |
publisher |
Hindawi Publishing Corporation |
publishDate |
2014 |
url |
http://psasir.upm.edu.my/id/eprint/35301/ http://www.hindawi.com/journals/tswj/2014/526105/abs/ |
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1643831412886863872 |
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13.211869 |