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2-Naphthylmethyl N-[1-(4-pyridyl)ethylidene]hydrazinecarbodithioate.

The molecules in the crystal structure of the title compound, C19H17N3S2, are linked by an intermolecular N-H...N [2.839 (5) Å] hydrogen bond via the [alpha]-N and the pyridyl N atoms. The thione S atom is in a trans position with respect to the methylpyridine fragment across the C-N bond but adopts...

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Main Authors: How, Fiona Ni Foong, Watkin, David J., Crouse, Karen Anne, Mohamed Tahir, Mohamed Ibrahim
Format: Article
Language:English
English
Published: International Union of Crystallography 2007
Online Access:http://psasir.upm.edu.my/id/eprint/24954/1/2.pdf
http://psasir.upm.edu.my/id/eprint/24954/
http://www.iucr.org/
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spelling my.upm.eprints.249542015-09-17T03:26:47Z http://psasir.upm.edu.my/id/eprint/24954/ 2-Naphthylmethyl N-[1-(4-pyridyl)ethylidene]hydrazinecarbodithioate. How, Fiona Ni Foong Watkin, David J. Crouse, Karen Anne Mohamed Tahir, Mohamed Ibrahim The molecules in the crystal structure of the title compound, C19H17N3S2, are linked by an intermolecular N-H...N [2.839 (5) Å] hydrogen bond via the [alpha]-N and the pyridyl N atoms. The thione S atom is in a trans position with respect to the methylpyridine fragment across the C-N bond but adopts a cis position with respect to the naphthalene ring across the C-S bond. There is a [pi]-[pi] stacking interaction between the naphthalene rings, with a centroid-centroid distance of 3.397 (2) Å. International Union of Crystallography 2007-07 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/24954/1/2.pdf How, Fiona Ni Foong and Watkin, David J. and Crouse, Karen Anne and Mohamed Tahir, Mohamed Ibrahim (2007) 2-Naphthylmethyl N-[1-(4-pyridyl)ethylidene]hydrazinecarbodithioate. Acta Crystallographica Section E: Structure Reports Online, E63 (7). pp. 3135-3136. ISSN 1600-5368; ESSN:1600-5368 http://www.iucr.org/ 10.1107/S1600536807025652 English
institution Universiti Putra Malaysia
building UPM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Putra Malaysia
content_source UPM Institutional Repository
url_provider http://psasir.upm.edu.my/
language English
English
description The molecules in the crystal structure of the title compound, C19H17N3S2, are linked by an intermolecular N-H...N [2.839 (5) Å] hydrogen bond via the [alpha]-N and the pyridyl N atoms. The thione S atom is in a trans position with respect to the methylpyridine fragment across the C-N bond but adopts a cis position with respect to the naphthalene ring across the C-S bond. There is a [pi]-[pi] stacking interaction between the naphthalene rings, with a centroid-centroid distance of 3.397 (2) Å.
format Article
author How, Fiona Ni Foong
Watkin, David J.
Crouse, Karen Anne
Mohamed Tahir, Mohamed Ibrahim
spellingShingle How, Fiona Ni Foong
Watkin, David J.
Crouse, Karen Anne
Mohamed Tahir, Mohamed Ibrahim
2-Naphthylmethyl N-[1-(4-pyridyl)ethylidene]hydrazinecarbodithioate.
author_facet How, Fiona Ni Foong
Watkin, David J.
Crouse, Karen Anne
Mohamed Tahir, Mohamed Ibrahim
author_sort How, Fiona Ni Foong
title 2-Naphthylmethyl N-[1-(4-pyridyl)ethylidene]hydrazinecarbodithioate.
title_short 2-Naphthylmethyl N-[1-(4-pyridyl)ethylidene]hydrazinecarbodithioate.
title_full 2-Naphthylmethyl N-[1-(4-pyridyl)ethylidene]hydrazinecarbodithioate.
title_fullStr 2-Naphthylmethyl N-[1-(4-pyridyl)ethylidene]hydrazinecarbodithioate.
title_full_unstemmed 2-Naphthylmethyl N-[1-(4-pyridyl)ethylidene]hydrazinecarbodithioate.
title_sort 2-naphthylmethyl n-[1-(4-pyridyl)ethylidene]hydrazinecarbodithioate.
publisher International Union of Crystallography
publishDate 2007
url http://psasir.upm.edu.my/id/eprint/24954/1/2.pdf
http://psasir.upm.edu.my/id/eprint/24954/
http://www.iucr.org/
_version_ 1643828514517942272
score 13.211869

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