Phase equilibria in the Bi2O3-CuO-Nb2O5 ternary system
A complete subsolidus ternary phase diagram of the Bi2O3-CuO-Nb2O5 (BCN) system was constructed. Careful firing control and phase analysis were applied to determine the phase assemblages and compatibilities over a wide range of temperatures, i.e. 700–925 °C. Phase-pure BCN pyrochlores were found to...
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言語: | English |
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Elsevier
2017
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オンライン・アクセス: | http://psasir.upm.edu.my/id/eprint/13456/1/Phase%20equilibria%20in%20the%20Bi2O3-CuO-Nb2O5%20ternary%20system.pdf http://psasir.upm.edu.my/id/eprint/13456/ https://www.sciencedirect.com/science/article/pii/S0272884216324142#! |
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my.upm.eprints.134562018-06-11T08:33:26Z http://psasir.upm.edu.my/id/eprint/13456/ Phase equilibria in the Bi2O3-CuO-Nb2O5 ternary system Tan, Kar Ban Chon, Mun Ping Khaw, Chwin Chieh Zainal, Zulkarnain Yap, Taufiq Yun Hin Chen, Soo Kien Tan, Phei Yi A complete subsolidus ternary phase diagram of the Bi2O3-CuO-Nb2O5 (BCN) system was constructed. Careful firing control and phase analysis were applied to determine the phase assemblages and compatibilities over a wide range of temperatures, i.e. 700–925 °C. Phase-pure BCN pyrochlores were found to crystallise in cubic symmetry, space group Fd3m, No. 227 with lattice constants in the range of 10.4855 (5)<x<10.5321 (3). The mechanism of this limited subsolidus series could be represented by a general formula, Bi3.08−xCu1.84+2x/9Nb3.08+7x/9O14.16+6x/9 (0≤x≤0.36) wherein the reduction in Bi content was compensated by a proportion amount of copper and niobium together with non-stoichiometry in oxygen. Elsevier 2017 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/13456/1/Phase%20equilibria%20in%20the%20Bi2O3-CuO-Nb2O5%20ternary%20system.pdf Tan, Kar Ban and Chon, Mun Ping and Khaw, Chwin Chieh and Zainal, Zulkarnain and Yap, Taufiq Yun Hin and Chen, Soo Kien and Tan, Phei Yi (2017) Phase equilibria in the Bi2O3-CuO-Nb2O5 ternary system. Ceramics International, 43 (6). pp. 4930-4936. ISSN 0272-8842; ESSN: 1873-3956 https://www.sciencedirect.com/science/article/pii/S0272884216324142#! 10.1016/j.ceramint.2016.12.147 |
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A complete subsolidus ternary phase diagram of the Bi2O3-CuO-Nb2O5 (BCN) system was constructed. Careful firing control and phase analysis were applied to determine the phase assemblages and compatibilities over a wide range of temperatures, i.e. 700–925 °C. Phase-pure BCN pyrochlores were found to crystallise in cubic symmetry, space group Fd3m, No. 227 with lattice constants in the range of 10.4855 (5)<x<10.5321 (3). The mechanism of this limited subsolidus series could be represented by a general formula, Bi3.08−xCu1.84+2x/9Nb3.08+7x/9O14.16+6x/9 (0≤x≤0.36) wherein the reduction in Bi content was compensated by a proportion amount of copper and niobium together with non-stoichiometry in oxygen. |
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Article |
author |
Tan, Kar Ban Chon, Mun Ping Khaw, Chwin Chieh Zainal, Zulkarnain Yap, Taufiq Yun Hin Chen, Soo Kien Tan, Phei Yi |
spellingShingle |
Tan, Kar Ban Chon, Mun Ping Khaw, Chwin Chieh Zainal, Zulkarnain Yap, Taufiq Yun Hin Chen, Soo Kien Tan, Phei Yi Phase equilibria in the Bi2O3-CuO-Nb2O5 ternary system |
author_facet |
Tan, Kar Ban Chon, Mun Ping Khaw, Chwin Chieh Zainal, Zulkarnain Yap, Taufiq Yun Hin Chen, Soo Kien Tan, Phei Yi |
author_sort |
Tan, Kar Ban |
title |
Phase equilibria in the Bi2O3-CuO-Nb2O5 ternary system |
title_short |
Phase equilibria in the Bi2O3-CuO-Nb2O5 ternary system |
title_full |
Phase equilibria in the Bi2O3-CuO-Nb2O5 ternary system |
title_fullStr |
Phase equilibria in the Bi2O3-CuO-Nb2O5 ternary system |
title_full_unstemmed |
Phase equilibria in the Bi2O3-CuO-Nb2O5 ternary system |
title_sort |
phase equilibria in the bi2o3-cuo-nb2o5 ternary system |
publisher |
Elsevier |
publishDate |
2017 |
url |
http://psasir.upm.edu.my/id/eprint/13456/1/Phase%20equilibria%20in%20the%20Bi2O3-CuO-Nb2O5%20ternary%20system.pdf http://psasir.upm.edu.my/id/eprint/13456/ https://www.sciencedirect.com/science/article/pii/S0272884216324142#! |
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1643825336869191680 |
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13.250246 |