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A crystallographic study of S-methyl 2-(5-chloro-2-oxoindolin-3-ylidene)hydrazinecarbodithioate

S-methyl 2-(5-chloro-2-oxoindolin-3-ylidene) hydrazinecarbodithioate (SM5ClISA) has been prepared from S-methyldithiocarbazate and 5-chloroisatin. The compound crystallized in monoclinic crystal system with space group P 21/n, Z = 4, V = 1201.85(7) Å3 and unit cell parameters a = 6.5466(2) Å, b = 7....

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Main Authors: Abdul Manan, Mohd Abdul Fatah, Mohamed Tahir, Mohamed Ibrahim, Crouse, Karen Anne, Watkin, David John
Format: Article
Language:English
Published: Springer New York LLC 2011
Online Access:http://psasir.upm.edu.my/id/eprint/12680/1/A%20crystallographic%20study%20of%20S.pdf
http://psasir.upm.edu.my/id/eprint/12680/
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spelling my.upm.eprints.126802015-10-02T03:39:50Z http://psasir.upm.edu.my/id/eprint/12680/ A crystallographic study of S-methyl 2-(5-chloro-2-oxoindolin-3-ylidene)hydrazinecarbodithioate Abdul Manan, Mohd Abdul Fatah Mohamed Tahir, Mohamed Ibrahim Crouse, Karen Anne Watkin, David John S-methyl 2-(5-chloro-2-oxoindolin-3-ylidene) hydrazinecarbodithioate (SM5ClISA) has been prepared from S-methyldithiocarbazate and 5-chloroisatin. The compound crystallized in monoclinic crystal system with space group P 21/n, Z = 4, V = 1201.85(7) Å3 and unit cell parameters a = 6.5466(2) Å, b = 7.5056(3) Å, c = 24.6509(8) Å, α = γ = 90° and β = 97.1434(18)°. The crystal structure reveals that the compound exists in the thione form with the chlorine occupies the fifth position in the isatin ring with the bond length of 1.739(2) Å. The 5-chloroisatin moiety is trans with respect to the C3–N2 and C3–S4 bonds whereas the methyl group of the dithiocarbazate moiety is cis with respect to the C3–N2 and C3–S5 bonds. Springer New York LLC 2011-02 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/12680/1/A%20crystallographic%20study%20of%20S.pdf Abdul Manan, Mohd Abdul Fatah and Mohamed Tahir, Mohamed Ibrahim and Crouse, Karen Anne and Watkin, David John (2011) A crystallographic study of S-methyl 2-(5-chloro-2-oxoindolin-3-ylidene)hydrazinecarbodithioate. Journal of Chemical Crystallography, 41 (2). pp. 230-235. ISSN 1074-1542; ESSN: 1572-8854 10.1007/s10870-010-9869-5
institution Universiti Putra Malaysia
building UPM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Putra Malaysia
content_source UPM Institutional Repository
url_provider http://psasir.upm.edu.my/
language English
description S-methyl 2-(5-chloro-2-oxoindolin-3-ylidene) hydrazinecarbodithioate (SM5ClISA) has been prepared from S-methyldithiocarbazate and 5-chloroisatin. The compound crystallized in monoclinic crystal system with space group P 21/n, Z = 4, V = 1201.85(7) Å3 and unit cell parameters a = 6.5466(2) Å, b = 7.5056(3) Å, c = 24.6509(8) Å, α = γ = 90° and β = 97.1434(18)°. The crystal structure reveals that the compound exists in the thione form with the chlorine occupies the fifth position in the isatin ring with the bond length of 1.739(2) Å. The 5-chloroisatin moiety is trans with respect to the C3–N2 and C3–S4 bonds whereas the methyl group of the dithiocarbazate moiety is cis with respect to the C3–N2 and C3–S5 bonds.
format Article
author Abdul Manan, Mohd Abdul Fatah
Mohamed Tahir, Mohamed Ibrahim
Crouse, Karen Anne
Watkin, David John
spellingShingle Abdul Manan, Mohd Abdul Fatah
Mohamed Tahir, Mohamed Ibrahim
Crouse, Karen Anne
Watkin, David John
A crystallographic study of S-methyl 2-(5-chloro-2-oxoindolin-3-ylidene)hydrazinecarbodithioate
author_facet Abdul Manan, Mohd Abdul Fatah
Mohamed Tahir, Mohamed Ibrahim
Crouse, Karen Anne
Watkin, David John
author_sort Abdul Manan, Mohd Abdul Fatah
title A crystallographic study of S-methyl 2-(5-chloro-2-oxoindolin-3-ylidene)hydrazinecarbodithioate
title_short A crystallographic study of S-methyl 2-(5-chloro-2-oxoindolin-3-ylidene)hydrazinecarbodithioate
title_full A crystallographic study of S-methyl 2-(5-chloro-2-oxoindolin-3-ylidene)hydrazinecarbodithioate
title_fullStr A crystallographic study of S-methyl 2-(5-chloro-2-oxoindolin-3-ylidene)hydrazinecarbodithioate
title_full_unstemmed A crystallographic study of S-methyl 2-(5-chloro-2-oxoindolin-3-ylidene)hydrazinecarbodithioate
title_sort crystallographic study of s-methyl 2-(5-chloro-2-oxoindolin-3-ylidene)hydrazinecarbodithioate
publisher Springer New York LLC
publishDate 2011
url http://psasir.upm.edu.my/id/eprint/12680/1/A%20crystallographic%20study%20of%20S.pdf
http://psasir.upm.edu.my/id/eprint/12680/
_version_ 1643825101238435840
score 13.211869

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