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Novel conformational isomerism in a six-coordinate silver(i) complex of a sexadentate macrocycle with an 'N3S3' donor set

The synthesis and structural characterization of the condensation product formed by a template reaction of 2, 6-diacetylpyridine and 3, 6, 9-trithiaundecane-1, 11-diamine about silver(1) (as perchlorate) are described. Crystals are monoclinic, C2/c, a 27.114(10), b 7.546(5), c 22.137(10) Å, β 105.35...

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Main Authors: Bin, Sidik Silong, Kildea, John D., White, Allan H.
Format: Article
Published: CSIRO Publishing 1989
Online Access:http://psasir.upm.edu.my/id/eprint/115194/
https://www.publish.csiro.au/ch/CH9891387
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spelling my.upm.eprints.1151942025-02-26T02:19:13Z http://psasir.upm.edu.my/id/eprint/115194/ Novel conformational isomerism in a six-coordinate silver(i) complex of a sexadentate macrocycle with an 'N3S3' donor set Bin, Sidik Silong Kildea, John D. White, Allan H. The synthesis and structural characterization of the condensation product formed by a template reaction of 2, 6-diacetylpyridine and 3, 6, 9-trithiaundecane-1, 11-diamine about silver(1) (as perchlorate) are described. Crystals are monoclinic, C2/c, a 27.114(10), b 7.546(5), c 22.137(10) Å, β 105.35(3)°, Z=8×[AgL]+(ClO4)- (L = C17H25N3S3). R was 0.057 for 2372 'observed' reflections. The six-coordinate silver(l) atom lies in a novel environment comprised of a mer-triaza moiety derived from 2, 6-diacetylpyridine [Ag-N, 2.422(8) (central), 2.538(8), 2.546(9) Å (distal)] and a fac-trithia moiety straddling its plane [Ag-S, 2.603(6) (central), 2-815(4), 2.881(3) Å (distal)]. The complex cation is a different conformational isomer to that found in the previously studied tetraphenylborate salt. In the latter, Ag-N are 2.422(9) (central), 2.613(9), 2.399(7) Å (distal), with Ag-S 2.670(3) (central), 2.655(3), 2.949(4) Å (distal). CSIRO Publishing 1989 Article PeerReviewed Bin, Sidik Silong and Kildea, John D. and White, Allan H. (1989) Novel conformational isomerism in a six-coordinate silver(i) complex of a sexadentate macrocycle with an 'N3S3' donor set. Australian Journal of Chemistry, 42 (8). pp. 1387-1391. ISSN 0004-9425; eISSN: 1445-0038 https://www.publish.csiro.au/ch/CH9891387 10.1071/CH9891387
institution Universiti Putra Malaysia
building UPM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Putra Malaysia
content_source UPM Institutional Repository
url_provider http://psasir.upm.edu.my/
description The synthesis and structural characterization of the condensation product formed by a template reaction of 2, 6-diacetylpyridine and 3, 6, 9-trithiaundecane-1, 11-diamine about silver(1) (as perchlorate) are described. Crystals are monoclinic, C2/c, a 27.114(10), b 7.546(5), c 22.137(10) Å, β 105.35(3)°, Z=8×[AgL]+(ClO4)- (L = C17H25N3S3). R was 0.057 for 2372 'observed' reflections. The six-coordinate silver(l) atom lies in a novel environment comprised of a mer-triaza moiety derived from 2, 6-diacetylpyridine [Ag-N, 2.422(8) (central), 2.538(8), 2.546(9) Å (distal)] and a fac-trithia moiety straddling its plane [Ag-S, 2.603(6) (central), 2-815(4), 2.881(3) Å (distal)]. The complex cation is a different conformational isomer to that found in the previously studied tetraphenylborate salt. In the latter, Ag-N are 2.422(9) (central), 2.613(9), 2.399(7) Å (distal), with Ag-S 2.670(3) (central), 2.655(3), 2.949(4) Å (distal).
format Article
author Bin, Sidik Silong
Kildea, John D.
White, Allan H.
spellingShingle Bin, Sidik Silong
Kildea, John D.
White, Allan H.
Novel conformational isomerism in a six-coordinate silver(i) complex of a sexadentate macrocycle with an 'N3S3' donor set
author_facet Bin, Sidik Silong
Kildea, John D.
White, Allan H.
author_sort Bin, Sidik Silong
title Novel conformational isomerism in a six-coordinate silver(i) complex of a sexadentate macrocycle with an 'N3S3' donor set
title_short Novel conformational isomerism in a six-coordinate silver(i) complex of a sexadentate macrocycle with an 'N3S3' donor set
title_full Novel conformational isomerism in a six-coordinate silver(i) complex of a sexadentate macrocycle with an 'N3S3' donor set
title_fullStr Novel conformational isomerism in a six-coordinate silver(i) complex of a sexadentate macrocycle with an 'N3S3' donor set
title_full_unstemmed Novel conformational isomerism in a six-coordinate silver(i) complex of a sexadentate macrocycle with an 'N3S3' donor set
title_sort novel conformational isomerism in a six-coordinate silver(i) complex of a sexadentate macrocycle with an 'n3s3' donor set
publisher CSIRO Publishing
publishDate 1989
url http://psasir.upm.edu.my/id/eprint/115194/
https://www.publish.csiro.au/ch/CH9891387
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score 13.244413

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