Staff View: Investigating the influence of CaO/CaF2 ratios on the synthesis of calcium-alumino-silicate-fluoride-based glass ceramics utilizing recyclable materials

Investigating the influence of CaO/CaF2 ratios on the synthesis of calcium-alumino-silicate-fluoride-based glass ceramics utilizing recyclable materials

This research addresses the significant challenges of waste disposal and the need for sustainable production in the ceramics industry by introducing an approach to fabricating calcium-alumino-silicate-fluoride (CASF) based glass ceramics. Using recyclable materials such as waste soda-lime-silicate (...

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Main Authors:	Roslan, Zuraidah, Amin, Khamirul Matori, Mohd Zaid, Mohd Hafiz, Yaakob, Yazid, Kul, Esra, Loh, Zhi Wei, Zarzali Shah, Aishah, Ahmad Zahudi, Afrina Zulaikha
Format:	Article
Published:	Springer 2024
Online Access:	http://psasir.upm.edu.my/id/eprint/114986/ https://link.springer.com/article/10.1007/s00339-024-08053-x?error=cookies_not_supported&code=9ac9985f-73d0-4d5b-9eef-0a4710d96eff
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spelling	my.upm.eprints.1149862025-02-13T08:00:43Z http://psasir.upm.edu.my/id/eprint/114986/ Investigating the influence of CaO/CaF2 ratios on the synthesis of calcium-alumino-silicate-fluoride-based glass ceramics utilizing recyclable materials Roslan, Zuraidah Amin, Khamirul Matori Mohd Zaid, Mohd Hafiz Yaakob, Yazid Kul, Esra Loh, Zhi Wei Zarzali Shah, Aishah Ahmad Zahudi, Afrina Zulaikha This research addresses the significant challenges of waste disposal and the need for sustainable production in the ceramics industry by introducing an approach to fabricating calcium-alumino-silicate-fluoride (CASF) based glass ceramics. Using recyclable materials such as waste soda-lime-silicate (SLS) glass and clam shells (CS) as primary precursors, a controlled melt-quenching process was employed to investigate how varying the CaO/CaF2 ratios influences the physical and structural properties of CASF glass ceramics. The waste materials and CASF glass ceramics were analyzed using X-ray fluorescence (XRF), X-ray diffraction (XRD), Fourier transforms infrared (FTIR), Scanning electron microscopy (SEM), and Energy dispersive X-ray (EDX) spectroscopy. XRD indicated the crystalline structure in all CASF glass ceramics samples while FTIR spectroscopy detected several linkages, including PO43−, Si-OH, Si-O-Si, CO2, and O-H indicating the development of CASF glass ceramics. SEM analysis showed a non-uniform distribution of particles and EDX analysis, shows the calcium-to-phosphate molar ratio (Ca/P) of CASF glass ceramics. The glass ceramics labeled as G6 possessed better properties, with a minor crystalline phase identified as fluorapatite (Ca5(PO4)3F), which is compatible with the commercial bioglass. These results demonstrate a cost-effective waste-derived bioglass system used in biomedical fields. Springer 2024-11-27 Article PeerReviewed Roslan, Zuraidah and Amin, Khamirul Matori and Mohd Zaid, Mohd Hafiz and Yaakob, Yazid and Kul, Esra and Loh, Zhi Wei and Zarzali Shah, Aishah and Ahmad Zahudi, Afrina Zulaikha (2024) Investigating the influence of CaO/CaF2 ratios on the synthesis of calcium-alumino-silicate-fluoride-based glass ceramics utilizing recyclable materials. Applied Physics A: Materials Science and Processing, 130 (12). art. no. 931. ISSN 0947-8396; eISSN: 1432-0630 https://link.springer.com/article/10.1007/s00339-024-08053-x?error=cookies_not_supported&code=9ac9985f-73d0-4d5b-9eef-0a4710d96eff 10.1007/s00339-024-08053-x
institution	Universiti Putra Malaysia
building	UPM Library
collection	Institutional Repository
continent	Asia
country	Malaysia
content_provider	Universiti Putra Malaysia
content_source	UPM Institutional Repository
url_provider	http://psasir.upm.edu.my/
description	This research addresses the significant challenges of waste disposal and the need for sustainable production in the ceramics industry by introducing an approach to fabricating calcium-alumino-silicate-fluoride (CASF) based glass ceramics. Using recyclable materials such as waste soda-lime-silicate (SLS) glass and clam shells (CS) as primary precursors, a controlled melt-quenching process was employed to investigate how varying the CaO/CaF2 ratios influences the physical and structural properties of CASF glass ceramics. The waste materials and CASF glass ceramics were analyzed using X-ray fluorescence (XRF), X-ray diffraction (XRD), Fourier transforms infrared (FTIR), Scanning electron microscopy (SEM), and Energy dispersive X-ray (EDX) spectroscopy. XRD indicated the crystalline structure in all CASF glass ceramics samples while FTIR spectroscopy detected several linkages, including PO43−, Si-OH, Si-O-Si, CO2, and O-H indicating the development of CASF glass ceramics. SEM analysis showed a non-uniform distribution of particles and EDX analysis, shows the calcium-to-phosphate molar ratio (Ca/P) of CASF glass ceramics. The glass ceramics labeled as G6 possessed better properties, with a minor crystalline phase identified as fluorapatite (Ca5(PO4)3F), which is compatible with the commercial bioglass. These results demonstrate a cost-effective waste-derived bioglass system used in biomedical fields.
format	Article
author	Roslan, Zuraidah Amin, Khamirul Matori Mohd Zaid, Mohd Hafiz Yaakob, Yazid Kul, Esra Loh, Zhi Wei Zarzali Shah, Aishah Ahmad Zahudi, Afrina Zulaikha
spellingShingle	Roslan, Zuraidah Amin, Khamirul Matori Mohd Zaid, Mohd Hafiz Yaakob, Yazid Kul, Esra Loh, Zhi Wei Zarzali Shah, Aishah Ahmad Zahudi, Afrina Zulaikha Investigating the influence of CaO/CaF2 ratios on the synthesis of calcium-alumino-silicate-fluoride-based glass ceramics utilizing recyclable materials
author_facet	Roslan, Zuraidah Amin, Khamirul Matori Mohd Zaid, Mohd Hafiz Yaakob, Yazid Kul, Esra Loh, Zhi Wei Zarzali Shah, Aishah Ahmad Zahudi, Afrina Zulaikha
author_sort	Roslan, Zuraidah
title	Investigating the influence of CaO/CaF2 ratios on the synthesis of calcium-alumino-silicate-fluoride-based glass ceramics utilizing recyclable materials
title_short	Investigating the influence of CaO/CaF2 ratios on the synthesis of calcium-alumino-silicate-fluoride-based glass ceramics utilizing recyclable materials
title_full	Investigating the influence of CaO/CaF2 ratios on the synthesis of calcium-alumino-silicate-fluoride-based glass ceramics utilizing recyclable materials
title_fullStr	Investigating the influence of CaO/CaF2 ratios on the synthesis of calcium-alumino-silicate-fluoride-based glass ceramics utilizing recyclable materials
title_full_unstemmed	Investigating the influence of CaO/CaF2 ratios on the synthesis of calcium-alumino-silicate-fluoride-based glass ceramics utilizing recyclable materials
title_sort	investigating the influence of cao/caf2 ratios on the synthesis of calcium-alumino-silicate-fluoride-based glass ceramics utilizing recyclable materials
publisher	Springer
publishDate	2024
url	http://psasir.upm.edu.my/id/eprint/114986/ https://link.springer.com/article/10.1007/s00339-024-08053-x?error=cookies_not_supported&code=9ac9985f-73d0-4d5b-9eef-0a4710d96eff
_version_	1825162409921216512
score	13.239859

Investigating the influence of CaO/CaF2 ratios on the synthesis of calcium-alumino-silicate-fluoride-based glass ceramics utilizing recyclable materials

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