Effect of pH on phosphorylation of sago starch

Sago starch, in a semidry state was phosphorylated with 2% sodium trimetaphosphate (STMP), 5% sodium tripolyphosphate (STPP) singly, and in combination at pH levels between 6 and 11. As the reaction pH was increased from 6 to 11, the degree of phosphorylation was observed to decrease from 0.186 to 0...

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Main Authors: Muhammad, K., Hussin, F., Man, Y.C., Ghazali, H.M.
Format: Article
Language:English
Published: Elsevier Science 2000
Online Access:http://psasir.upm.edu.my/id/eprint/114397/1/114397.pdf
http://psasir.upm.edu.my/id/eprint/114397/
https://linkinghub.elsevier.com/retrieve/pii/S0144861799001204
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spelling my.upm.eprints.1143972025-02-05T03:43:46Z http://psasir.upm.edu.my/id/eprint/114397/ Effect of pH on phosphorylation of sago starch Muhammad, K. Hussin, F. Man, Y.C. Ghazali, H.M. Sago starch, in a semidry state was phosphorylated with 2% sodium trimetaphosphate (STMP), 5% sodium tripolyphosphate (STPP) singly, and in combination at pH levels between 6 and 11. As the reaction pH was increased from 6 to 11, the degree of phosphorylation was observed to decrease from 0.186 to 0.083% P with STPP, except at pH 9 where the degree of phosphorylation was increased to 0.224% P. In the case of STMP, the degree of phosphorylation increased from 0.066 to 0.119% P as reaction pH was increased from 6 to 10. In the reactions using a mixture of STPP and STMP, the P content decreased from 0.320 to 0.115% when a similar range of pH was employed. At the reaction pH of 9, a starch phosphate obtained using STPP exhibited low hot paste viscosity but high cold paste viscosity and shear stability when cooked at 95 °C. Treatment of sago starch with a mixture of STPP and STMP yielded the best starch phosphate at the reaction pH of 9.5 which showed lower hot paste viscosity and much higher cold paste viscosity than that of sago starch phosphates prepared at pH 9 using STPP. Paste clarity measurements of the phosphorylated starches indicated that cross-linking accelerated rapidly above pH 8 with STMP, above pH 9 with STPP, and above pH 6 with a mixture of the two. Elsevier Science 2000 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/114397/1/114397.pdf Muhammad, K. and Hussin, F. and Man, Y.C. and Ghazali, H.M. (2000) Effect of pH on phosphorylation of sago starch. Carbohydrate Polymers, 42 (1). pp. 85-90. ISSN 0144-8617; eISSN: 0144-8617 https://linkinghub.elsevier.com/retrieve/pii/S0144861799001204 10.1016/S0144-8617(99)00120-4
institution Universiti Putra Malaysia
building UPM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Putra Malaysia
content_source UPM Institutional Repository
url_provider http://psasir.upm.edu.my/
language English
description Sago starch, in a semidry state was phosphorylated with 2% sodium trimetaphosphate (STMP), 5% sodium tripolyphosphate (STPP) singly, and in combination at pH levels between 6 and 11. As the reaction pH was increased from 6 to 11, the degree of phosphorylation was observed to decrease from 0.186 to 0.083% P with STPP, except at pH 9 where the degree of phosphorylation was increased to 0.224% P. In the case of STMP, the degree of phosphorylation increased from 0.066 to 0.119% P as reaction pH was increased from 6 to 10. In the reactions using a mixture of STPP and STMP, the P content decreased from 0.320 to 0.115% when a similar range of pH was employed. At the reaction pH of 9, a starch phosphate obtained using STPP exhibited low hot paste viscosity but high cold paste viscosity and shear stability when cooked at 95 °C. Treatment of sago starch with a mixture of STPP and STMP yielded the best starch phosphate at the reaction pH of 9.5 which showed lower hot paste viscosity and much higher cold paste viscosity than that of sago starch phosphates prepared at pH 9 using STPP. Paste clarity measurements of the phosphorylated starches indicated that cross-linking accelerated rapidly above pH 8 with STMP, above pH 9 with STPP, and above pH 6 with a mixture of the two.
format Article
author Muhammad, K.
Hussin, F.
Man, Y.C.
Ghazali, H.M.
spellingShingle Muhammad, K.
Hussin, F.
Man, Y.C.
Ghazali, H.M.
Effect of pH on phosphorylation of sago starch
author_facet Muhammad, K.
Hussin, F.
Man, Y.C.
Ghazali, H.M.
author_sort Muhammad, K.
title Effect of pH on phosphorylation of sago starch
title_short Effect of pH on phosphorylation of sago starch
title_full Effect of pH on phosphorylation of sago starch
title_fullStr Effect of pH on phosphorylation of sago starch
title_full_unstemmed Effect of pH on phosphorylation of sago starch
title_sort effect of ph on phosphorylation of sago starch
publisher Elsevier Science
publishDate 2000
url http://psasir.upm.edu.my/id/eprint/114397/1/114397.pdf
http://psasir.upm.edu.my/id/eprint/114397/
https://linkinghub.elsevier.com/retrieve/pii/S0144861799001204
_version_ 1823276359147847680
score 13.235796