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Jet-fuel range hydrocarbon production from Reutealis trisperma oil over Al-MCM-41 derived from Indonesian Kaolin with different Si/A1 ratio

The catalytic conversion of Reutealis trisperma oil was carried out over a Al-MCM-41 based catalyst with different Si/Al ratio with no added hydrogen to examine the possibility of the direct production of hydrocarbons in the ranges of jet fuel. In a semi-batch reactor, RTO was combined with 3 % cata...

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Main Authors: Nugraha, Reva Edra, Prasetyoko, Didik, Nareswari, Nabila Argya, Aziz, Abdul, Holilah, Holilah, Bahruji, Hasliza, Yusop, Muhammad Rahimi, Asikin-Mijan, Nurul, Suprapto, Suprapto, Taufiq-Yap, Yun Hin, Abdul Jalil, Aishah, Purnami, Santi Wulan, Hartati, Hartati
Format: Article
Language:English
Published: Elsevier 2024
Online Access:http://psasir.upm.edu.my/id/eprint/113741/1/113741.pdf
http://psasir.upm.edu.my/id/eprint/113741/
https://linkinghub.elsevier.com/retrieve/pii/S2666016424002718
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spelling my.upm.eprints.1137412025-01-15T03:36:51Z http://psasir.upm.edu.my/id/eprint/113741/ Jet-fuel range hydrocarbon production from Reutealis trisperma oil over Al-MCM-41 derived from Indonesian Kaolin with different Si/A1 ratio Nugraha, Reva Edra Prasetyoko, Didik Nareswari, Nabila Argya Aziz, Abdul Holilah, Holilah Bahruji, Hasliza Yusop, Muhammad Rahimi Asikin-Mijan, Nurul Suprapto, Suprapto Taufiq-Yap, Yun Hin Abdul Jalil, Aishah Purnami, Santi Wulan Hartati, Hartati The catalytic conversion of Reutealis trisperma oil was carried out over a Al-MCM-41 based catalyst with different Si/Al ratio with no added hydrogen to examine the possibility of the direct production of hydrocarbons in the ranges of jet fuel. In a semi-batch reactor, RTO was combined with 3 % catalyst and heated to 350 °C for 4h. The blank reaction shows the lowest conversion and liquid yield, with values of 39.65 % and 8.74 %, respectively. In contrast, the highest conversion was achieved using the Al-MCM-41 (30) catalyst, and the conversion decreases as the Si/Al ratio of the Al-MCM-41 catalyst increases. Indeed, the mesoporous structure enabled extensive bio-oil diffusion and adsorption, further increasing catalytic conversion. The Al-MCM-41 (30) shows the great performance in catalytic conversion of RTO to hydrocarbon and aromatic chain hydrocarbon. The Al-MCM-41 (30) catalyst resulted in a composition of 41.26 % paraffin, 6.78 % olefin, 21.77 % arenes, and 11.44 % cycloparaffin. This composition is comparable to JP-8 and Jet-A fuels, satisfying the ASTM D7566 standard for aircraft turbine fuel containing synthetic hydrocarbons. The acid site and pore size on the support material influenced the interaction of bio-oil molecules and catalyst which increasing the rate of reactant/product diffusion and improve the jet-fuel production. The obtained results are promising for the use of non-edible RTO and kaolin-derived catalysts in the production of sustainable alternative jet fuels. This approach offers competitive costs and significant environmental and social benefits. © 2024 The Authors Elsevier 2024 Article PeerReviewed text en cc_by_nc_4 http://psasir.upm.edu.my/id/eprint/113741/1/113741.pdf Nugraha, Reva Edra and Prasetyoko, Didik and Nareswari, Nabila Argya and Aziz, Abdul and Holilah, Holilah and Bahruji, Hasliza and Yusop, Muhammad Rahimi and Asikin-Mijan, Nurul and Suprapto, Suprapto and Taufiq-Yap, Yun Hin and Abdul Jalil, Aishah and Purnami, Santi Wulan and Hartati, Hartati (2024) Jet-fuel range hydrocarbon production from Reutealis trisperma oil over Al-MCM-41 derived from Indonesian Kaolin with different Si/A1 ratio. Case Studies in Chemical and Environmental Engineering, 10. art. no. 100877. pp. 1-11. ISSN 2666-0164; eISSN: 2666-0164 https://linkinghub.elsevier.com/retrieve/pii/S2666016424002718 10.1016/j.cscee.2024.100877
institution Universiti Putra Malaysia
building UPM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Putra Malaysia
content_source UPM Institutional Repository
url_provider http://psasir.upm.edu.my/
language English
description The catalytic conversion of Reutealis trisperma oil was carried out over a Al-MCM-41 based catalyst with different Si/Al ratio with no added hydrogen to examine the possibility of the direct production of hydrocarbons in the ranges of jet fuel. In a semi-batch reactor, RTO was combined with 3 % catalyst and heated to 350 °C for 4h. The blank reaction shows the lowest conversion and liquid yield, with values of 39.65 % and 8.74 %, respectively. In contrast, the highest conversion was achieved using the Al-MCM-41 (30) catalyst, and the conversion decreases as the Si/Al ratio of the Al-MCM-41 catalyst increases. Indeed, the mesoporous structure enabled extensive bio-oil diffusion and adsorption, further increasing catalytic conversion. The Al-MCM-41 (30) shows the great performance in catalytic conversion of RTO to hydrocarbon and aromatic chain hydrocarbon. The Al-MCM-41 (30) catalyst resulted in a composition of 41.26 % paraffin, 6.78 % olefin, 21.77 % arenes, and 11.44 % cycloparaffin. This composition is comparable to JP-8 and Jet-A fuels, satisfying the ASTM D7566 standard for aircraft turbine fuel containing synthetic hydrocarbons. The acid site and pore size on the support material influenced the interaction of bio-oil molecules and catalyst which increasing the rate of reactant/product diffusion and improve the jet-fuel production. The obtained results are promising for the use of non-edible RTO and kaolin-derived catalysts in the production of sustainable alternative jet fuels. This approach offers competitive costs and significant environmental and social benefits. © 2024 The Authors
format Article
author Nugraha, Reva Edra
Prasetyoko, Didik
Nareswari, Nabila Argya
Aziz, Abdul
Holilah, Holilah
Bahruji, Hasliza
Yusop, Muhammad Rahimi
Asikin-Mijan, Nurul
Suprapto, Suprapto
Taufiq-Yap, Yun Hin
Abdul Jalil, Aishah
Purnami, Santi Wulan
Hartati, Hartati
spellingShingle Nugraha, Reva Edra
Prasetyoko, Didik
Nareswari, Nabila Argya
Aziz, Abdul
Holilah, Holilah
Bahruji, Hasliza
Yusop, Muhammad Rahimi
Asikin-Mijan, Nurul
Suprapto, Suprapto
Taufiq-Yap, Yun Hin
Abdul Jalil, Aishah
Purnami, Santi Wulan
Hartati, Hartati
Jet-fuel range hydrocarbon production from Reutealis trisperma oil over Al-MCM-41 derived from Indonesian Kaolin with different Si/A1 ratio
author_facet Nugraha, Reva Edra
Prasetyoko, Didik
Nareswari, Nabila Argya
Aziz, Abdul
Holilah, Holilah
Bahruji, Hasliza
Yusop, Muhammad Rahimi
Asikin-Mijan, Nurul
Suprapto, Suprapto
Taufiq-Yap, Yun Hin
Abdul Jalil, Aishah
Purnami, Santi Wulan
Hartati, Hartati
author_sort Nugraha, Reva Edra
title Jet-fuel range hydrocarbon production from Reutealis trisperma oil over Al-MCM-41 derived from Indonesian Kaolin with different Si/A1 ratio
title_short Jet-fuel range hydrocarbon production from Reutealis trisperma oil over Al-MCM-41 derived from Indonesian Kaolin with different Si/A1 ratio
title_full Jet-fuel range hydrocarbon production from Reutealis trisperma oil over Al-MCM-41 derived from Indonesian Kaolin with different Si/A1 ratio
title_fullStr Jet-fuel range hydrocarbon production from Reutealis trisperma oil over Al-MCM-41 derived from Indonesian Kaolin with different Si/A1 ratio
title_full_unstemmed Jet-fuel range hydrocarbon production from Reutealis trisperma oil over Al-MCM-41 derived from Indonesian Kaolin with different Si/A1 ratio
title_sort jet-fuel range hydrocarbon production from reutealis trisperma oil over al-mcm-41 derived from indonesian kaolin with different si/a1 ratio
publisher Elsevier
publishDate 2024
url http://psasir.upm.edu.my/id/eprint/113741/1/113741.pdf
http://psasir.upm.edu.my/id/eprint/113741/
https://linkinghub.elsevier.com/retrieve/pii/S2666016424002718
_version_ 1823093072200728576
score 13.239859

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