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Insight into copper and iron ion sequestration from liquid‑phase environment by microcrystalline cellulose biosorbent: experimental and modelling analyses

The paper assesses batch system microcrystalline cellulose (MCC) adsorptive ability for copper and iron uptake from aquatic environment. Field emission scanning electron microscope (FESEM), point zero charge and Fourier transform infrared (FTIR) spectroscopy were used to examine the physicochemical...

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Main Authors: Abdullah, Mohammad, Abdullah, Luqman Chuah, Adeyi, Abel Adekanmi, Md Jamil, Siti Nurul Ain, Choong, Thomas Shean Yaw, A. Majid, Rohah
Format: Article
Language:English
Published: Springer 2024
Subjects:
Environmental engineering
Chemical engineering - Research
Water - Pollution
Online Access:http://psasir.upm.edu.my/id/eprint/113346/1/113346.pdf
http://psasir.upm.edu.my/id/eprint/113346/
https://link.springer.com/article/10.1007/s13738-024-03049-z
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spelling my.upm.eprints.1133462024-11-20T06:07:03Z http://psasir.upm.edu.my/id/eprint/113346/ Insight into copper and iron ion sequestration from liquid‑phase environment by microcrystalline cellulose biosorbent: experimental and modelling analyses Abdullah, Mohammad Abdullah, Luqman Chuah Adeyi, Abel Adekanmi Md Jamil, Siti Nurul Ain Choong, Thomas Shean Yaw A. Majid, Rohah The paper assesses batch system microcrystalline cellulose (MCC) adsorptive ability for copper and iron uptake from aquatic environment. Field emission scanning electron microscope (FESEM), point zero charge and Fourier transform infrared (FTIR) spectroscopy were used to examine the physicochemical and morphological features of MCC. The batch system of the sequestration progression for the elimination of Cu(II) and Fe(II) was used by varying the solution pH, MCC doses, initial copper and iron concentration, and resident time. The maximum removal percentage for Cu(II) and Fe(II) were 99.5% and 96.4%, respectively, at pH 7. The influence of MCC dosage showed the 1.0 g/L of adsorbents results the highest percentage of Cu(II) (99.8%) and Fe(II) (88.63%) correspondingly. Equilibrium data for both metals were well fitted with both Langmuir and Freundlich isotherms, representing monolayer and multilayer adsorption systems. The maximum sorption capacity of MCC was 534.61 mg/g and 845.75 mg/g, respectively, for Cu(II) and Fe(II) ions at room temperature. Pseudosecond-order model best describes the copper and iron kinetic data, signifying the dominance of chemisorption adsorption relation between the negatively charged MCC and adsorbates. After four successive regeneration cycles, the MCC polymer maintained its maximal adsorption capacity, demonstrating effective copper and iron ion separation from aqueous solution. According to the study’s findings, poisonous heavy metals can be successfully removed from aquatic environments using eco-friendly microcrystalline cellulose. Springer 2024-05 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/113346/1/113346.pdf Abdullah, Mohammad and Abdullah, Luqman Chuah and Adeyi, Abel Adekanmi and Md Jamil, Siti Nurul Ain and Choong, Thomas Shean Yaw and A. Majid, Rohah (2024) Insight into copper and iron ion sequestration from liquid‑phase environment by microcrystalline cellulose biosorbent: experimental and modelling analyses. Journal of the Iranian Chemical Society, 21 (7). pp. 1843-1853. ISSN 1735-207X; eISSN: 1735-2428 https://link.springer.com/article/10.1007/s13738-024-03049-z Environmental engineering Chemical engineering - Research Water - Pollution 10.1007/s13738-024-03049-z
institution Universiti Putra Malaysia
building UPM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Putra Malaysia
content_source UPM Institutional Repository
url_provider http://psasir.upm.edu.my/
language English
topic Environmental engineering
Chemical engineering - Research
Water - Pollution
spellingShingle Environmental engineering
Chemical engineering - Research
Water - Pollution
Abdullah, Mohammad
Abdullah, Luqman Chuah
Adeyi, Abel Adekanmi
Md Jamil, Siti Nurul Ain
Choong, Thomas Shean Yaw
A. Majid, Rohah
Insight into copper and iron ion sequestration from liquid‑phase environment by microcrystalline cellulose biosorbent: experimental and modelling analyses
description The paper assesses batch system microcrystalline cellulose (MCC) adsorptive ability for copper and iron uptake from aquatic environment. Field emission scanning electron microscope (FESEM), point zero charge and Fourier transform infrared (FTIR) spectroscopy were used to examine the physicochemical and morphological features of MCC. The batch system of the sequestration progression for the elimination of Cu(II) and Fe(II) was used by varying the solution pH, MCC doses, initial copper and iron concentration, and resident time. The maximum removal percentage for Cu(II) and Fe(II) were 99.5% and 96.4%, respectively, at pH 7. The influence of MCC dosage showed the 1.0 g/L of adsorbents results the highest percentage of Cu(II) (99.8%) and Fe(II) (88.63%) correspondingly. Equilibrium data for both metals were well fitted with both Langmuir and Freundlich isotherms, representing monolayer and multilayer adsorption systems. The maximum sorption capacity of MCC was 534.61 mg/g and 845.75 mg/g, respectively, for Cu(II) and Fe(II) ions at room temperature. Pseudosecond-order model best describes the copper and iron kinetic data, signifying the dominance of chemisorption adsorption relation between the negatively charged MCC and adsorbates. After four successive regeneration cycles, the MCC polymer maintained its maximal adsorption capacity, demonstrating effective copper and iron ion separation from aqueous solution. According to the study’s findings, poisonous heavy metals can be successfully removed from aquatic environments using eco-friendly microcrystalline cellulose.
format Article
author Abdullah, Mohammad
Abdullah, Luqman Chuah
Adeyi, Abel Adekanmi
Md Jamil, Siti Nurul Ain
Choong, Thomas Shean Yaw
A. Majid, Rohah
author_facet Abdullah, Mohammad
Abdullah, Luqman Chuah
Adeyi, Abel Adekanmi
Md Jamil, Siti Nurul Ain
Choong, Thomas Shean Yaw
A. Majid, Rohah
author_sort Abdullah, Mohammad
title Insight into copper and iron ion sequestration from liquid‑phase environment by microcrystalline cellulose biosorbent: experimental and modelling analyses
title_short Insight into copper and iron ion sequestration from liquid‑phase environment by microcrystalline cellulose biosorbent: experimental and modelling analyses
title_full Insight into copper and iron ion sequestration from liquid‑phase environment by microcrystalline cellulose biosorbent: experimental and modelling analyses
title_fullStr Insight into copper and iron ion sequestration from liquid‑phase environment by microcrystalline cellulose biosorbent: experimental and modelling analyses
title_full_unstemmed Insight into copper and iron ion sequestration from liquid‑phase environment by microcrystalline cellulose biosorbent: experimental and modelling analyses
title_sort insight into copper and iron ion sequestration from liquid‑phase environment by microcrystalline cellulose biosorbent: experimental and modelling analyses
publisher Springer
publishDate 2024
url http://psasir.upm.edu.my/id/eprint/113346/1/113346.pdf
http://psasir.upm.edu.my/id/eprint/113346/
https://link.springer.com/article/10.1007/s13738-024-03049-z
_version_ 1817844625966104576
score 13.223943

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