Solidify eutectic electrolytes via the added MXene as nucleation sites for a solid-state zinc-ion battery with reconstructed ion transport

Stationary energy storage infrastructure based on zinc-ion transport and storage chemistry is attracting more attention due to favorable metrics, including cost, safety, and recycling feasibility. However, splitting water and liquid electrolyte fluidity lead to cathode dissolution and Zn corrosion,...

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Main Authors: Meng, Xiangxuan, Du, Mingdong, Li, Yuning, Du, Shiji, Zhao, Lixin, Zheng, Shunri, Zhang, Jian, Li, Haibo, Qiao, Liang, Tan, Kar Ban, Han, Wenjuan, Xu, Shichong, Li, Jiaming, Lu, Ming
Format: Article
Language:English
Published: American Chemical Society 2024
Online Access:http://psasir.upm.edu.my/id/eprint/113267/1/113267.pdf
http://psasir.upm.edu.my/id/eprint/113267/
https://pubs.acs.org/doi/abs/10.1021/acs.nanolett.4c01085
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spelling my.upm.eprints.1132672024-11-20T05:44:49Z http://psasir.upm.edu.my/id/eprint/113267/ Solidify eutectic electrolytes via the added MXene as nucleation sites for a solid-state zinc-ion battery with reconstructed ion transport Meng, Xiangxuan Du, Mingdong Li, Yuning Du, Shiji Zhao, Lixin Zheng, Shunri Zhang, Jian Li, Haibo Qiao, Liang Tan, Kar Ban Han, Wenjuan Xu, Shichong Li, Jiaming Lu, Ming Stationary energy storage infrastructure based on zinc-ion transport and storage chemistry is attracting more attention due to favorable metrics, including cost, safety, and recycling feasibility. However, splitting water and liquid electrolyte fluidity lead to cathode dissolution and Zn corrosion, resulting in rapid attenuation of the capacity and service life. Herein, a new architecture of solid-state electrolytes with high zinc ionic conductivity at room temperature was prepared via solidification of deep eutectic solvents utilizing MXene as nucleation additives. The ionic conductivity of MXene/ZCEs reached 6.69 × 10−4 S cm−1 at room temperature. Dendrite-free Zn plating/stripping with high reversibility can remain for over 2500 h. Subsequently, the fabricated solid-state zinc-ion battery with eliminated HER and suppressed Zn dendrites exhibited excellent cycling performance and could work normally in a range from −10 to 60 °C. This design inspired by eutectic solidification affords new insights into the multivalent solid electrochemistry suffering from slow ion migration. American Chemical Society 2024 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/113267/1/113267.pdf Meng, Xiangxuan and Du, Mingdong and Li, Yuning and Du, Shiji and Zhao, Lixin and Zheng, Shunri and Zhang, Jian and Li, Haibo and Qiao, Liang and Tan, Kar Ban and Han, Wenjuan and Xu, Shichong and Li, Jiaming and Lu, Ming (2024) Solidify eutectic electrolytes via the added MXene as nucleation sites for a solid-state zinc-ion battery with reconstructed ion transport. Nano Letters, 24 (29). pp. 8818-8825. ISSN 1530-6984; eISSN: 1530-6992 https://pubs.acs.org/doi/abs/10.1021/acs.nanolett.4c01085 10.1021/acs.nanolett.4c01085
institution Universiti Putra Malaysia
building UPM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Putra Malaysia
content_source UPM Institutional Repository
url_provider http://psasir.upm.edu.my/
language English
description Stationary energy storage infrastructure based on zinc-ion transport and storage chemistry is attracting more attention due to favorable metrics, including cost, safety, and recycling feasibility. However, splitting water and liquid electrolyte fluidity lead to cathode dissolution and Zn corrosion, resulting in rapid attenuation of the capacity and service life. Herein, a new architecture of solid-state electrolytes with high zinc ionic conductivity at room temperature was prepared via solidification of deep eutectic solvents utilizing MXene as nucleation additives. The ionic conductivity of MXene/ZCEs reached 6.69 × 10−4 S cm−1 at room temperature. Dendrite-free Zn plating/stripping with high reversibility can remain for over 2500 h. Subsequently, the fabricated solid-state zinc-ion battery with eliminated HER and suppressed Zn dendrites exhibited excellent cycling performance and could work normally in a range from −10 to 60 °C. This design inspired by eutectic solidification affords new insights into the multivalent solid electrochemistry suffering from slow ion migration.
format Article
author Meng, Xiangxuan
Du, Mingdong
Li, Yuning
Du, Shiji
Zhao, Lixin
Zheng, Shunri
Zhang, Jian
Li, Haibo
Qiao, Liang
Tan, Kar Ban
Han, Wenjuan
Xu, Shichong
Li, Jiaming
Lu, Ming
spellingShingle Meng, Xiangxuan
Du, Mingdong
Li, Yuning
Du, Shiji
Zhao, Lixin
Zheng, Shunri
Zhang, Jian
Li, Haibo
Qiao, Liang
Tan, Kar Ban
Han, Wenjuan
Xu, Shichong
Li, Jiaming
Lu, Ming
Solidify eutectic electrolytes via the added MXene as nucleation sites for a solid-state zinc-ion battery with reconstructed ion transport
author_facet Meng, Xiangxuan
Du, Mingdong
Li, Yuning
Du, Shiji
Zhao, Lixin
Zheng, Shunri
Zhang, Jian
Li, Haibo
Qiao, Liang
Tan, Kar Ban
Han, Wenjuan
Xu, Shichong
Li, Jiaming
Lu, Ming
author_sort Meng, Xiangxuan
title Solidify eutectic electrolytes via the added MXene as nucleation sites for a solid-state zinc-ion battery with reconstructed ion transport
title_short Solidify eutectic electrolytes via the added MXene as nucleation sites for a solid-state zinc-ion battery with reconstructed ion transport
title_full Solidify eutectic electrolytes via the added MXene as nucleation sites for a solid-state zinc-ion battery with reconstructed ion transport
title_fullStr Solidify eutectic electrolytes via the added MXene as nucleation sites for a solid-state zinc-ion battery with reconstructed ion transport
title_full_unstemmed Solidify eutectic electrolytes via the added MXene as nucleation sites for a solid-state zinc-ion battery with reconstructed ion transport
title_sort solidify eutectic electrolytes via the added mxene as nucleation sites for a solid-state zinc-ion battery with reconstructed ion transport
publisher American Chemical Society
publishDate 2024
url http://psasir.upm.edu.my/id/eprint/113267/1/113267.pdf
http://psasir.upm.edu.my/id/eprint/113267/
https://pubs.acs.org/doi/abs/10.1021/acs.nanolett.4c01085
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score 13.222552