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The effect of bismuth oxide substitution on physio-elastic properties of new formulation zinc borate glass system

A new formulation of the bismuth-zinc-borate glass system has been fabricated using the conventional melt-quenching method. The amorphous phase of the glass sample has been confirmed by the nonexistent of any crystalline peak presented by X-ray diffraction patterns. The Fourier-transform infrared sp...

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Main Authors: Almasri, Karima, Mohd Zaid, Mohd Hafiz, Matori, Khamirul Amin, Yaakob, Yazid, Shah, Aishah Zarzali
Format: Article
Published: Springer 2024
Online Access:http://psasir.upm.edu.my/id/eprint/112753/
https://link.springer.com/article/10.1007/s11082-024-06726-8?error=cookies_not_supported&code=1ccb5ae4-e346-4d58-9159-c55aa20ce5d5
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spelling my.upm.eprints.1127532024-11-14T03:58:38Z http://psasir.upm.edu.my/id/eprint/112753/ The effect of bismuth oxide substitution on physio-elastic properties of new formulation zinc borate glass system Almasri, Karima Mohd Zaid, Mohd Hafiz Matori, Khamirul Amin Yaakob, Yazid Shah, Aishah Zarzali A new formulation of the bismuth-zinc-borate glass system has been fabricated using the conventional melt-quenching method. The amorphous phase of the glass sample has been confirmed by the nonexistent of any crystalline peak presented by X-ray diffraction patterns. The Fourier-transform infrared spectroscopy result displays several bands associated with the Zn–O and B–O–B bonding. The glass samples exhibited a density increase from 3.19 to 4.28 g/cm3 and the molar volume increased from 23.48 to 31.00 cm3/mol. The density of the glasses increases due to the addition of Bi2O3 which has a higher atomic mass compared to the other elements in glass compositions. The addition of Bi2O3 contributes more mass to the glass structure, leading to an increase in overall density. The incorporated Bi2O3 reduced the longitudinal (6134.41–5121.94 ms−1) and shear (3310.50–2848.15 ms−1) velocities. The elastic moduli resulted in a decreasing behavior when Bi2O3 concentration increased, and the values ranged from 120.04 to 112.21 GPa for longitudinal modulus, 34.96–34.69 GPa for shear modulus, 73.43–65.95 GPa for bulk modulus, and 90.52–88.56 GPa for Young’s modulus. The Poisson’s ratio presents the same trend as the modulus, while the microhardness shows an inversely proportional trend. The BiZnB4 sample demonstrates the lowest Poisson’s ratio (0.276) and highest microhardness (5.18 GPa) values. These findings show that the physio-elastic properties are composition-dependent, suggesting potential applications as flexible glass panels for dynamic building glass design. Springer 2024 Article PeerReviewed Almasri, Karima and Mohd Zaid, Mohd Hafiz and Matori, Khamirul Amin and Yaakob, Yazid and Shah, Aishah Zarzali (2024) The effect of bismuth oxide substitution on physio-elastic properties of new formulation zinc borate glass system. Optical and Quantum Electronics, 56 (5). art. no. 862. ISSN 0306-8919; eISSN: 1572-817X https://link.springer.com/article/10.1007/s11082-024-06726-8?error=cookies_not_supported&code=1ccb5ae4-e346-4d58-9159-c55aa20ce5d5 10.1007/s11082-024-06726-8
institution Universiti Putra Malaysia
building UPM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Putra Malaysia
content_source UPM Institutional Repository
url_provider http://psasir.upm.edu.my/
description A new formulation of the bismuth-zinc-borate glass system has been fabricated using the conventional melt-quenching method. The amorphous phase of the glass sample has been confirmed by the nonexistent of any crystalline peak presented by X-ray diffraction patterns. The Fourier-transform infrared spectroscopy result displays several bands associated with the Zn–O and B–O–B bonding. The glass samples exhibited a density increase from 3.19 to 4.28 g/cm3 and the molar volume increased from 23.48 to 31.00 cm3/mol. The density of the glasses increases due to the addition of Bi2O3 which has a higher atomic mass compared to the other elements in glass compositions. The addition of Bi2O3 contributes more mass to the glass structure, leading to an increase in overall density. The incorporated Bi2O3 reduced the longitudinal (6134.41–5121.94 ms−1) and shear (3310.50–2848.15 ms−1) velocities. The elastic moduli resulted in a decreasing behavior when Bi2O3 concentration increased, and the values ranged from 120.04 to 112.21 GPa for longitudinal modulus, 34.96–34.69 GPa for shear modulus, 73.43–65.95 GPa for bulk modulus, and 90.52–88.56 GPa for Young’s modulus. The Poisson’s ratio presents the same trend as the modulus, while the microhardness shows an inversely proportional trend. The BiZnB4 sample demonstrates the lowest Poisson’s ratio (0.276) and highest microhardness (5.18 GPa) values. These findings show that the physio-elastic properties are composition-dependent, suggesting potential applications as flexible glass panels for dynamic building glass design.
format Article
author Almasri, Karima
Mohd Zaid, Mohd Hafiz
Matori, Khamirul Amin
Yaakob, Yazid
Shah, Aishah Zarzali
spellingShingle Almasri, Karima
Mohd Zaid, Mohd Hafiz
Matori, Khamirul Amin
Yaakob, Yazid
Shah, Aishah Zarzali
The effect of bismuth oxide substitution on physio-elastic properties of new formulation zinc borate glass system
author_facet Almasri, Karima
Mohd Zaid, Mohd Hafiz
Matori, Khamirul Amin
Yaakob, Yazid
Shah, Aishah Zarzali
author_sort Almasri, Karima
title The effect of bismuth oxide substitution on physio-elastic properties of new formulation zinc borate glass system
title_short The effect of bismuth oxide substitution on physio-elastic properties of new formulation zinc borate glass system
title_full The effect of bismuth oxide substitution on physio-elastic properties of new formulation zinc borate glass system
title_fullStr The effect of bismuth oxide substitution on physio-elastic properties of new formulation zinc borate glass system
title_full_unstemmed The effect of bismuth oxide substitution on physio-elastic properties of new formulation zinc borate glass system
title_sort effect of bismuth oxide substitution on physio-elastic properties of new formulation zinc borate glass system
publisher Springer
publishDate 2024
url http://psasir.upm.edu.my/id/eprint/112753/
https://link.springer.com/article/10.1007/s11082-024-06726-8?error=cookies_not_supported&code=1ccb5ae4-e346-4d58-9159-c55aa20ce5d5
_version_ 1816132712520482816
score 13.223943

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