Cover Image

Co-Fe dual-atom isolated in N-doped graphydine as an efficient sulfur conversion catalyst in Li-S batteries

Lithium-sulfur (Li-S) batteries have garnered considerable attention as a prospective energy storage device for the future due to their exceptionally high theoretical energy density. Unfortunately, sluggish sulfur reactions create a bottleneck in Li–S batteries, hindering their ability to deliver al...

Full description

Saved in:
Bibliographic Details
Main Authors: Parsaee, Faeze, Fayzullaev, Normurot, Nassar, Maadh Fawzi, Alreda, Baraa Abd, Mahmoud, HassabAlla M.A., Taki, Anmar Ghanim, Faraji, Monireh
Format: Article
Language:English
Published: Elsevier 2024
Online Access:http://psasir.upm.edu.my/id/eprint/112447/1/112447%282%29.pdf
http://psasir.upm.edu.my/id/eprint/112447/
https://linkinghub.elsevier.com/retrieve/pii/S0925838824007230
Tags: Add Tag
No Tags, Be the first to tag this record!
id my.upm.eprints.112447
record_format eprints
spelling my.upm.eprints.1124472024-11-20T06:44:04Z http://psasir.upm.edu.my/id/eprint/112447/ Co-Fe dual-atom isolated in N-doped graphydine as an efficient sulfur conversion catalyst in Li-S batteries Parsaee, Faeze Fayzullaev, Normurot Nassar, Maadh Fawzi Alreda, Baraa Abd Mahmoud, HassabAlla M.A. Taki, Anmar Ghanim Faraji, Monireh Lithium-sulfur (Li-S) batteries have garnered considerable attention as a prospective energy storage device for the future due to their exceptionally high theoretical energy density. Unfortunately, sluggish sulfur reactions create a bottleneck in Li–S batteries, hindering their ability to deliver all their promised energy. In this work, we reported the N-doped graphydine as a sulfur host in a Li-S battery cathode. The graphydine host is decorated with isolated cobalt/iron dual-atom catalyst. Co/Fe sites in Li–S batteries play a double role as an electrocatalyst, speeding up the two-way conversion between sulfur and lithium sulfide during the battery's cycle. These composite electrocatalysts, built with a remarkable 70 wt% sulfur content, achieve a high specific capacity of 1520 mA h g⁻¹ at a low charging current density (0.1 C). At a low current density of 0.1 C, they present remarkable cycling consistency, losing only 0.07% of capacity for each cycle for 1000 cycles. Elsevier 2024 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/112447/1/112447%282%29.pdf Parsaee, Faeze and Fayzullaev, Normurot and Nassar, Maadh Fawzi and Alreda, Baraa Abd and Mahmoud, HassabAlla M.A. and Taki, Anmar Ghanim and Faraji, Monireh (2024) Co-Fe dual-atom isolated in N-doped graphydine as an efficient sulfur conversion catalyst in Li-S batteries. Journal of Alloys and Compounds, 988. art. no. 174136. pp. 1-10. ISSN 0925-8388 https://linkinghub.elsevier.com/retrieve/pii/S0925838824007230 10.1016/j.jallcom.2024.174136
institution Universiti Putra Malaysia
building UPM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Putra Malaysia
content_source UPM Institutional Repository
url_provider http://psasir.upm.edu.my/
language English
description Lithium-sulfur (Li-S) batteries have garnered considerable attention as a prospective energy storage device for the future due to their exceptionally high theoretical energy density. Unfortunately, sluggish sulfur reactions create a bottleneck in Li–S batteries, hindering their ability to deliver all their promised energy. In this work, we reported the N-doped graphydine as a sulfur host in a Li-S battery cathode. The graphydine host is decorated with isolated cobalt/iron dual-atom catalyst. Co/Fe sites in Li–S batteries play a double role as an electrocatalyst, speeding up the two-way conversion between sulfur and lithium sulfide during the battery's cycle. These composite electrocatalysts, built with a remarkable 70 wt% sulfur content, achieve a high specific capacity of 1520 mA h g⁻¹ at a low charging current density (0.1 C). At a low current density of 0.1 C, they present remarkable cycling consistency, losing only 0.07% of capacity for each cycle for 1000 cycles.
format Article
author Parsaee, Faeze
Fayzullaev, Normurot
Nassar, Maadh Fawzi
Alreda, Baraa Abd
Mahmoud, HassabAlla M.A.
Taki, Anmar Ghanim
Faraji, Monireh
spellingShingle Parsaee, Faeze
Fayzullaev, Normurot
Nassar, Maadh Fawzi
Alreda, Baraa Abd
Mahmoud, HassabAlla M.A.
Taki, Anmar Ghanim
Faraji, Monireh
Co-Fe dual-atom isolated in N-doped graphydine as an efficient sulfur conversion catalyst in Li-S batteries
author_facet Parsaee, Faeze
Fayzullaev, Normurot
Nassar, Maadh Fawzi
Alreda, Baraa Abd
Mahmoud, HassabAlla M.A.
Taki, Anmar Ghanim
Faraji, Monireh
author_sort Parsaee, Faeze
title Co-Fe dual-atom isolated in N-doped graphydine as an efficient sulfur conversion catalyst in Li-S batteries
title_short Co-Fe dual-atom isolated in N-doped graphydine as an efficient sulfur conversion catalyst in Li-S batteries
title_full Co-Fe dual-atom isolated in N-doped graphydine as an efficient sulfur conversion catalyst in Li-S batteries
title_fullStr Co-Fe dual-atom isolated in N-doped graphydine as an efficient sulfur conversion catalyst in Li-S batteries
title_full_unstemmed Co-Fe dual-atom isolated in N-doped graphydine as an efficient sulfur conversion catalyst in Li-S batteries
title_sort co-fe dual-atom isolated in n-doped graphydine as an efficient sulfur conversion catalyst in li-s batteries
publisher Elsevier
publishDate 2024
url http://psasir.upm.edu.my/id/eprint/112447/1/112447%282%29.pdf
http://psasir.upm.edu.my/id/eprint/112447/
https://linkinghub.elsevier.com/retrieve/pii/S0925838824007230
_version_ 1817844607882362880
score 13.223943

Similar Items