Development of porous MIL-101 derived catalyst application for green diesel production
A novel three-dimensional MIL-101 derived porous carbon-based Ni-doped catalyst was synthesised via slow pyrolysis of Ni/MIL-101(Cr) precursor at 600 °C for 4 h. The catalytic activities were evaluated via one-pot hydrodeoxygenation (HDO) reactions by using palmitic acid (PA) as a model compound to...
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2024
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my.upm.eprints.1058502024-03-29T03:36:55Z http://psasir.upm.edu.my/id/eprint/105850/ Development of porous MIL-101 derived catalyst application for green diesel production Chang, He Abdulkareem-Alsultan, G. Taufiq-Yap, Y.H. Mohd Izham, S. Sivasangar, S. A novel three-dimensional MIL-101 derived porous carbon-based Ni-doped catalyst was synthesised via slow pyrolysis of Ni/MIL-101(Cr) precursor at 600 °C for 4 h. The catalytic activities were evaluated via one-pot hydrodeoxygenation (HDO) reactions by using palmitic acid (PA) as a model compound to produce green diesel within the range of a paraffinic hydrocarbon. The results show that Ni/P-MIL-101 exhibited excellent catalytic activity and recyclability in the HDO reaction of PA at a reaction temperature of 400 °C for 3 h under 3 MPa purified H2 pressure with 5 wt catalyst loading. The conversion of PA and hydrocarbon selectivity were found to be 100 with Ni loading > 8 wt on P-MIL-101. In addition, both 25 and 14 wt Ni/P-MIL-101 catalysts were able to recycle up to 7 and 15 times, respectively, and nearly 100 alkane yield was achieved. The unique properties of Ni/P-MIL-101 catalyst such as finely dispersed added Ni, abundant acid and basic sites, and the presence of Cr2O3 active sites from pyrolysed MIL-101 with its mesoporous structures play a synergetic role in obtaining a very efficient catalyst for hydrodeoxygenation reaction. It is worth mentioning that the catalyst has an excellent catalytic effect on different kinds of fatty acid (ester) raw materials. Therefore, this Ni/P-MIL-101 catalyst has good prospects and potential for industrial application in green diesel production. Elsevier Ltd 2024 Article PeerReviewed Chang, He and Abdulkareem-Alsultan, G. and Taufiq-Yap, Y.H. and Mohd Izham, S. and Sivasangar, S. (2024) Development of porous MIL-101 derived catalyst application for green diesel production. Fuel, 355. art. no. 129459. pp. 1-21. ISSN 0016-2361; ESSN: 1873-7153 https://www.sciencedirect.com/science/article/pii/S0016236123020732 10.1016/j.fuel.2023.129459 |
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A novel three-dimensional MIL-101 derived porous carbon-based Ni-doped catalyst was synthesised via slow pyrolysis of Ni/MIL-101(Cr) precursor at 600 °C for 4 h. The catalytic activities were evaluated via one-pot hydrodeoxygenation (HDO) reactions by using palmitic acid (PA) as a model compound to produce green diesel within the range of a paraffinic hydrocarbon. The results show that Ni/P-MIL-101 exhibited excellent catalytic activity and recyclability in the HDO reaction of PA at a reaction temperature of 400 °C for 3 h under 3 MPa purified H2 pressure with 5 wt catalyst loading. The conversion of PA and hydrocarbon selectivity were found to be 100 with Ni loading > 8 wt on P-MIL-101. In addition, both 25 and 14 wt Ni/P-MIL-101 catalysts were able to recycle up to 7 and 15 times, respectively, and nearly 100 alkane yield was achieved. The unique properties of Ni/P-MIL-101 catalyst such as finely dispersed added Ni, abundant acid and basic sites, and the presence of Cr2O3 active sites from pyrolysed MIL-101 with its mesoporous structures play a synergetic role in obtaining a very efficient catalyst for hydrodeoxygenation reaction. It is worth mentioning that the catalyst has an excellent catalytic effect on different kinds of fatty acid (ester) raw materials. Therefore, this Ni/P-MIL-101 catalyst has good prospects and potential for industrial application in green diesel production. |
| format |
Article |
| author |
Chang, He Abdulkareem-Alsultan, G. Taufiq-Yap, Y.H. Mohd Izham, S. Sivasangar, S. |
| spellingShingle |
Chang, He Abdulkareem-Alsultan, G. Taufiq-Yap, Y.H. Mohd Izham, S. Sivasangar, S. Development of porous MIL-101 derived catalyst application for green diesel production |
| author_facet |
Chang, He Abdulkareem-Alsultan, G. Taufiq-Yap, Y.H. Mohd Izham, S. Sivasangar, S. |
| author_sort |
Chang, He |
| title |
Development of porous MIL-101 derived catalyst application for green diesel production |
| title_short |
Development of porous MIL-101 derived catalyst application for green diesel production |
| title_full |
Development of porous MIL-101 derived catalyst application for green diesel production |
| title_fullStr |
Development of porous MIL-101 derived catalyst application for green diesel production |
| title_full_unstemmed |
Development of porous MIL-101 derived catalyst application for green diesel production |
| title_sort |
development of porous mil-101 derived catalyst application for green diesel production |
| publisher |
Elsevier Ltd |
| publishDate |
2024 |
| url |
http://psasir.upm.edu.my/id/eprint/105850/ https://www.sciencedirect.com/science/article/pii/S0016236123020732 |
| _version_ |
1795013302350249984 |
| score |
13.211869 |