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Supercapattery performance of carbon nanofibers decorated with poly(3,4-ethlenedioxythiophene) and cobalt oxide

Supercapattery epitomizes the next level of energy storage technology which demonstrates the pros of a supercapacitor and a battery. In this work, we developed a positive electrode of supercapattery comprised of porous functionalized carbon nanofibers (pfCNFs) as a template for the electrodeposition...

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Main Authors: Azman, Nur Hawa Nabilah, Sulaiman, Yusran
Format: Article
Published: Elsevier 2022
Online Access:http://psasir.upm.edu.my/id/eprint/103359/
https://www.sciencedirect.com/science/article/pii/S0272884222000256
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spelling my.upm.eprints.1033592023-06-19T04:10:00Z http://psasir.upm.edu.my/id/eprint/103359/ Supercapattery performance of carbon nanofibers decorated with poly(3,4-ethlenedioxythiophene) and cobalt oxide Azman, Nur Hawa Nabilah Sulaiman, Yusran Supercapattery epitomizes the next level of energy storage technology which demonstrates the pros of a supercapacitor and a battery. In this work, we developed a positive electrode of supercapattery comprised of porous functionalized carbon nanofibers (pfCNFs) as a template for the electrodeposition of poly(3,4-ethylenedioxythiophene) (PEDOT) and incorporation of cobalt oxide (Co3O4) through hydrothermal and annealing. Interestingly, the composite displays a flower-like structure observed on the fibers. The functionalized carbon nanofibers/poly(3,4-ethylenedioxythiophene)/cobalt oxide (pfCNFs/PEDOT/Co3O4) exhibited obvious redox peaks demonstrating its battery type property with high specific capacity (Csp) and specific capacity (Cs) of 849.65 F g-1 and 679.72 C g-1, respectively. As for the real application, the positive electrode of pfCNFs/PEDOT/Co3O4 and nitrogen-doped graphene as a negative electrode was assembled with a polyvinyl alcohol/potassium hydroxide gel used as a separator. The pfCNFs/PEDOT/Co3O4//NDG displayed specific energy of 14.54 Wh kg-1 and specific power of 1726.96 W kg-1 at 2 A g-1. In addition, the device also exhibited remarkable cycling stability with 106.26% capacitance retention over 2000 cycles revealing its prospect as an electrode for supercapattery. Elsevier 2022 Article PeerReviewed Azman, Nur Hawa Nabilah and Sulaiman, Yusran (2022) Supercapattery performance of carbon nanofibers decorated with poly(3,4-ethlenedioxythiophene) and cobalt oxide. Ceramics International, 48 (8). 11772 - 11778. ISSN 0272-8842; ESSN: 1873-3956 https://www.sciencedirect.com/science/article/pii/S0272884222000256 10.1016/j.ceramint.2022.01.036
institution Universiti Putra Malaysia
building UPM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Putra Malaysia
content_source UPM Institutional Repository
url_provider http://psasir.upm.edu.my/
description Supercapattery epitomizes the next level of energy storage technology which demonstrates the pros of a supercapacitor and a battery. In this work, we developed a positive electrode of supercapattery comprised of porous functionalized carbon nanofibers (pfCNFs) as a template for the electrodeposition of poly(3,4-ethylenedioxythiophene) (PEDOT) and incorporation of cobalt oxide (Co3O4) through hydrothermal and annealing. Interestingly, the composite displays a flower-like structure observed on the fibers. The functionalized carbon nanofibers/poly(3,4-ethylenedioxythiophene)/cobalt oxide (pfCNFs/PEDOT/Co3O4) exhibited obvious redox peaks demonstrating its battery type property with high specific capacity (Csp) and specific capacity (Cs) of 849.65 F g-1 and 679.72 C g-1, respectively. As for the real application, the positive electrode of pfCNFs/PEDOT/Co3O4 and nitrogen-doped graphene as a negative electrode was assembled with a polyvinyl alcohol/potassium hydroxide gel used as a separator. The pfCNFs/PEDOT/Co3O4//NDG displayed specific energy of 14.54 Wh kg-1 and specific power of 1726.96 W kg-1 at 2 A g-1. In addition, the device also exhibited remarkable cycling stability with 106.26% capacitance retention over 2000 cycles revealing its prospect as an electrode for supercapattery.
format Article
author Azman, Nur Hawa Nabilah
Sulaiman, Yusran
spellingShingle Azman, Nur Hawa Nabilah
Sulaiman, Yusran
Supercapattery performance of carbon nanofibers decorated with poly(3,4-ethlenedioxythiophene) and cobalt oxide
author_facet Azman, Nur Hawa Nabilah
Sulaiman, Yusran
author_sort Azman, Nur Hawa Nabilah
title Supercapattery performance of carbon nanofibers decorated with poly(3,4-ethlenedioxythiophene) and cobalt oxide
title_short Supercapattery performance of carbon nanofibers decorated with poly(3,4-ethlenedioxythiophene) and cobalt oxide
title_full Supercapattery performance of carbon nanofibers decorated with poly(3,4-ethlenedioxythiophene) and cobalt oxide
title_fullStr Supercapattery performance of carbon nanofibers decorated with poly(3,4-ethlenedioxythiophene) and cobalt oxide
title_full_unstemmed Supercapattery performance of carbon nanofibers decorated with poly(3,4-ethlenedioxythiophene) and cobalt oxide
title_sort supercapattery performance of carbon nanofibers decorated with poly(3,4-ethlenedioxythiophene) and cobalt oxide
publisher Elsevier
publishDate 2022
url http://psasir.upm.edu.my/id/eprint/103359/
https://www.sciencedirect.com/science/article/pii/S0272884222000256
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score 13.211869

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