Staff View: Fabrication of novel agrowaste (banana and potato peels)-based biochar/TiO2 nanocomposite for adsorption of Cr(VI), statistical optimization via RSM approach

Fabrication of novel agrowaste (banana and potato peels)-based biochar/TiO2 nanocomposite for adsorption of Cr(VI), statistical optimization via RSM approach

In this research work, a simple, efficient, and eco-friendly procedure for the biosorption of Cr(VI) ions was studied. A detailed comparative study was performed to check the adsorption efficiency of agrowaste (banana and potato peels)-based adsorbents. Firstly, mixed biosorbent was washed, dried an...

Full description

Saved in:

Bibliographic Details
Main Authors:	Ashfaq, Aamna, Nadeem, Raziya, Gong, Hongyu, Rashid, Umer, Saima Noreen, Rehman, Shafique ur, Ahmed, Zubair, Adil, Muhammad, Akhtar, Nayab, Ashfaq, Muhammad Zeeshan, Alharthi, Fahad A., Kazerooni, Elham Ahmed
Format:	Article
Published:	Multidisciplinary Digital Publishing Institute 2022
Online Access:	http://psasir.upm.edu.my/id/eprint/101452/ https://www.mdpi.com/2073-4360/14/13/2644
Tags:	Add Tag No Tags, Be the first to tag this record!

id	my.upm.eprints.101452
record_format	eprints
spelling	my.upm.eprints.1014522023-09-22T23:30:03Z http://psasir.upm.edu.my/id/eprint/101452/ Fabrication of novel agrowaste (banana and potato peels)-based biochar/TiO2 nanocomposite for adsorption of Cr(VI), statistical optimization via RSM approach Ashfaq, Aamna Nadeem, Raziya Gong, Hongyu Rashid, Umer Saima Noreen Rehman, Shafique ur Ahmed, Zubair Adil, Muhammad Akhtar, Nayab Ashfaq, Muhammad Zeeshan Alharthi, Fahad A. Kazerooni, Elham Ahmed In this research work, a simple, efficient, and eco-friendly procedure for the biosorption of Cr(VI) ions was studied. A detailed comparative study was performed to check the adsorption efficiency of agrowaste (banana and potato peels)-based adsorbents. Firstly, mixed biosorbent was washed, dried and ground into powder, secondly, biosorbent was pyrolyzed into biochar and thirdly TiO2 nanocomposite (TiO2 NC) biosorbent was made by sonicating using prepared biochar and TiO2 NPs. Titanium dioxide nanoparticles (TiO2 NPs) were synthesized by a green method using Psidium guajava leaf extract. The synthesized adsorbents were characterized by SEM, EDX FT-IR, XRD and UV-visible analysis. The effect of four different factors, i.e., pH of the synthetic metallic solution, time, concentration and adsorbent dosage was studied. The optimum conditions were time (120 min), pH (3), concentration (10 ppm) and adsorbent dosage (1.0 g). The kinetic modeling showed that the adsorption of Cr(VI) ion follows a pseudo second-order mechanism and the Langmuir isotherm model was found to fit better for this study. Response surface methodology (RSM)-based optimized parameters provided optimal parameter sets that better represent the adsorption rate models. The uptake capacity of Cr(VI) from aqueous solution was found to be biomass (76.49 mg/L) ˂ biochar (86.51 mg/L) ˂ TiO2 NC (92.89 mg/L). It can be suggested that the produced TiO2 NC could possibly be an efficient biosorbent for the removal of Cr(IV). Multidisciplinary Digital Publishing Institute 2022-06-29 Article PeerReviewed Ashfaq, Aamna and Nadeem, Raziya and Gong, Hongyu and Rashid, Umer and Saima Noreen and Rehman, Shafique ur and Ahmed, Zubair and Adil, Muhammad and Akhtar, Nayab and Ashfaq, Muhammad Zeeshan and Alharthi, Fahad A. and Kazerooni, Elham Ahmed (2022) Fabrication of novel agrowaste (banana and potato peels)-based biochar/TiO2 nanocomposite for adsorption of Cr(VI), statistical optimization via RSM approach. Polymers, 14 (13). art. no. 2644. pp. 1-20. ISSN 2073-4360 https://www.mdpi.com/2073-4360/14/13/2644 10.3390/polym14132644
institution	Universiti Putra Malaysia
building	UPM Library
collection	Institutional Repository
continent	Asia
country	Malaysia
content_provider	Universiti Putra Malaysia
content_source	UPM Institutional Repository
url_provider	http://psasir.upm.edu.my/
description	In this research work, a simple, efficient, and eco-friendly procedure for the biosorption of Cr(VI) ions was studied. A detailed comparative study was performed to check the adsorption efficiency of agrowaste (banana and potato peels)-based adsorbents. Firstly, mixed biosorbent was washed, dried and ground into powder, secondly, biosorbent was pyrolyzed into biochar and thirdly TiO2 nanocomposite (TiO2 NC) biosorbent was made by sonicating using prepared biochar and TiO2 NPs. Titanium dioxide nanoparticles (TiO2 NPs) were synthesized by a green method using Psidium guajava leaf extract. The synthesized adsorbents were characterized by SEM, EDX FT-IR, XRD and UV-visible analysis. The effect of four different factors, i.e., pH of the synthetic metallic solution, time, concentration and adsorbent dosage was studied. The optimum conditions were time (120 min), pH (3), concentration (10 ppm) and adsorbent dosage (1.0 g). The kinetic modeling showed that the adsorption of Cr(VI) ion follows a pseudo second-order mechanism and the Langmuir isotherm model was found to fit better for this study. Response surface methodology (RSM)-based optimized parameters provided optimal parameter sets that better represent the adsorption rate models. The uptake capacity of Cr(VI) from aqueous solution was found to be biomass (76.49 mg/L) ˂ biochar (86.51 mg/L) ˂ TiO2 NC (92.89 mg/L). It can be suggested that the produced TiO2 NC could possibly be an efficient biosorbent for the removal of Cr(IV).
format	Article
author	Ashfaq, Aamna Nadeem, Raziya Gong, Hongyu Rashid, Umer Saima Noreen Rehman, Shafique ur Ahmed, Zubair Adil, Muhammad Akhtar, Nayab Ashfaq, Muhammad Zeeshan Alharthi, Fahad A. Kazerooni, Elham Ahmed
spellingShingle	Ashfaq, Aamna Nadeem, Raziya Gong, Hongyu Rashid, Umer Saima Noreen Rehman, Shafique ur Ahmed, Zubair Adil, Muhammad Akhtar, Nayab Ashfaq, Muhammad Zeeshan Alharthi, Fahad A. Kazerooni, Elham Ahmed Fabrication of novel agrowaste (banana and potato peels)-based biochar/TiO2 nanocomposite for adsorption of Cr(VI), statistical optimization via RSM approach
author_facet	Ashfaq, Aamna Nadeem, Raziya Gong, Hongyu Rashid, Umer Saima Noreen Rehman, Shafique ur Ahmed, Zubair Adil, Muhammad Akhtar, Nayab Ashfaq, Muhammad Zeeshan Alharthi, Fahad A. Kazerooni, Elham Ahmed
author_sort	Ashfaq, Aamna
title	Fabrication of novel agrowaste (banana and potato peels)-based biochar/TiO2 nanocomposite for adsorption of Cr(VI), statistical optimization via RSM approach
title_short	Fabrication of novel agrowaste (banana and potato peels)-based biochar/TiO2 nanocomposite for adsorption of Cr(VI), statistical optimization via RSM approach
title_full	Fabrication of novel agrowaste (banana and potato peels)-based biochar/TiO2 nanocomposite for adsorption of Cr(VI), statistical optimization via RSM approach
title_fullStr	Fabrication of novel agrowaste (banana and potato peels)-based biochar/TiO2 nanocomposite for adsorption of Cr(VI), statistical optimization via RSM approach
title_full_unstemmed	Fabrication of novel agrowaste (banana and potato peels)-based biochar/TiO2 nanocomposite for adsorption of Cr(VI), statistical optimization via RSM approach
title_sort	fabrication of novel agrowaste (banana and potato peels)-based biochar/tio2 nanocomposite for adsorption of cr(vi), statistical optimization via rsm approach
publisher	Multidisciplinary Digital Publishing Institute
publishDate	2022
url	http://psasir.upm.edu.my/id/eprint/101452/ https://www.mdpi.com/2073-4360/14/13/2644
_version_	1781706696323760128
score	13.211869

Fabrication of novel agrowaste (banana and potato peels)-based biochar/TiO2 nanocomposite for adsorption of Cr(VI), statistical optimization via RSM approach

Similar Items