ZnO/ZnS/Carbon Nanocomposite-Derived Sulfur-Doped carbon nanosheets using a layered nanoreactor: Towards advanced supercapacitor electrodes and devices

Various approaches have been applied to increase the capacity of electric double layer capacitors (EDLC) by increasing the accessible surface area of the electrode material (mainly carbon) for electrolyte ions. One method is to make the active material particles smaller or use graphite-based carbon...

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Main Authors: Yeganeh Ghotbi M., Sikiru S., Rajabi A., Soleimani H., Kou L., Ansari M.N.M., Ramachandaramurthy V.K.
Other Authors: 24484463700
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Published: Elsevier B.V. 2025
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spelling my.uniten.dspace-367142025-03-03T15:44:07Z ZnO/ZnS/Carbon Nanocomposite-Derived Sulfur-Doped carbon nanosheets using a layered nanoreactor: Towards advanced supercapacitor electrodes and devices Yeganeh Ghotbi M. Sikiru S. Rajabi A. Soleimani H. Kou L. Ansari M.N.M. Ramachandaramurthy V.K. 24484463700 57211063469 56622591700 55556142100 57200000963 55489853600 6602912020 Electrodes Electrolytes II-VI semiconductors Nanocomposites Nanoreactors Sulfur Supercapacitor Zinc oxide Active material Carbon material Carbon nanocomposite Doped carbons Energy Layered nanoreactor S values S-doped S-doped carbon ZnO/ZnS Zinc sulfide Various approaches have been applied to increase the capacity of electric double layer capacitors (EDLC) by increasing the accessible surface area of the electrode material (mainly carbon) for electrolyte ions. One method is to make the active material particles smaller or use graphite-based carbon with less thickness. Another method involves doping carbon materials with some group III and V elements to create pseudo-capacitive properties. And finally, hybridization/combination of carbon with some metal compounds due to the inductive synergistic effect. Using the idea of layered nanoreactors, we prepared a ZnO/ZnS/S-doped carbon nanocomposite, i.e. producing a metal oxide/sulfide with a heteroatom-doped carbon material, simultaneously. ZnO/ZnS/carbon nanocomposite was acid washed to remove ZnO and obtain ZnS/C; ZnS/carbon nanocomposite was again acid washed to remove ZnS and obtain S-doped carbon material. ZnO/ZnS/S-doped carbon, ZnS/S-doped carbon nanocomposites and S-doped carbon materials showed the specific capacitance (Cs) values of 119, 1048 and 454F/g, respectively, when used as the active material in the three-electrode system. In addition, the S-doped carbon material showed a Cs value of 57F/g when used as the active material in the fabrication of a symmetric commercial-like supercapacitor device. ? 2024 Elsevier B.V. Final 2025-03-03T07:44:07Z 2025-03-03T07:44:07Z 2024 Article 10.1016/j.cej.2024.150018 2-s2.0-85186526427 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85186526427&doi=10.1016%2fj.cej.2024.150018&partnerID=40&md5=5717608b7d5f00a4425c8acd630c0282 https://irepository.uniten.edu.my/handle/123456789/36714 485 150018 Elsevier B.V. Scopus
institution Universiti Tenaga Nasional
building UNITEN Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Tenaga Nasional
content_source UNITEN Institutional Repository
url_provider http://dspace.uniten.edu.my/
topic Electrodes
Electrolytes
II-VI semiconductors
Nanocomposites
Nanoreactors
Sulfur
Supercapacitor
Zinc oxide
Active material
Carbon material
Carbon nanocomposite
Doped carbons
Energy
Layered nanoreactor
S values
S-doped
S-doped carbon
ZnO/ZnS
Zinc sulfide
spellingShingle Electrodes
Electrolytes
II-VI semiconductors
Nanocomposites
Nanoreactors
Sulfur
Supercapacitor
Zinc oxide
Active material
Carbon material
Carbon nanocomposite
Doped carbons
Energy
Layered nanoreactor
S values
S-doped
S-doped carbon
ZnO/ZnS
Zinc sulfide
Yeganeh Ghotbi M.
Sikiru S.
Rajabi A.
Soleimani H.
Kou L.
Ansari M.N.M.
Ramachandaramurthy V.K.
ZnO/ZnS/Carbon Nanocomposite-Derived Sulfur-Doped carbon nanosheets using a layered nanoreactor: Towards advanced supercapacitor electrodes and devices
description Various approaches have been applied to increase the capacity of electric double layer capacitors (EDLC) by increasing the accessible surface area of the electrode material (mainly carbon) for electrolyte ions. One method is to make the active material particles smaller or use graphite-based carbon with less thickness. Another method involves doping carbon materials with some group III and V elements to create pseudo-capacitive properties. And finally, hybridization/combination of carbon with some metal compounds due to the inductive synergistic effect. Using the idea of layered nanoreactors, we prepared a ZnO/ZnS/S-doped carbon nanocomposite, i.e. producing a metal oxide/sulfide with a heteroatom-doped carbon material, simultaneously. ZnO/ZnS/carbon nanocomposite was acid washed to remove ZnO and obtain ZnS/C; ZnS/carbon nanocomposite was again acid washed to remove ZnS and obtain S-doped carbon material. ZnO/ZnS/S-doped carbon, ZnS/S-doped carbon nanocomposites and S-doped carbon materials showed the specific capacitance (Cs) values of 119, 1048 and 454F/g, respectively, when used as the active material in the three-electrode system. In addition, the S-doped carbon material showed a Cs value of 57F/g when used as the active material in the fabrication of a symmetric commercial-like supercapacitor device. ? 2024 Elsevier B.V.
author2 24484463700
author_facet 24484463700
Yeganeh Ghotbi M.
Sikiru S.
Rajabi A.
Soleimani H.
Kou L.
Ansari M.N.M.
Ramachandaramurthy V.K.
format Article
author Yeganeh Ghotbi M.
Sikiru S.
Rajabi A.
Soleimani H.
Kou L.
Ansari M.N.M.
Ramachandaramurthy V.K.
author_sort Yeganeh Ghotbi M.
title ZnO/ZnS/Carbon Nanocomposite-Derived Sulfur-Doped carbon nanosheets using a layered nanoreactor: Towards advanced supercapacitor electrodes and devices
title_short ZnO/ZnS/Carbon Nanocomposite-Derived Sulfur-Doped carbon nanosheets using a layered nanoreactor: Towards advanced supercapacitor electrodes and devices
title_full ZnO/ZnS/Carbon Nanocomposite-Derived Sulfur-Doped carbon nanosheets using a layered nanoreactor: Towards advanced supercapacitor electrodes and devices
title_fullStr ZnO/ZnS/Carbon Nanocomposite-Derived Sulfur-Doped carbon nanosheets using a layered nanoreactor: Towards advanced supercapacitor electrodes and devices
title_full_unstemmed ZnO/ZnS/Carbon Nanocomposite-Derived Sulfur-Doped carbon nanosheets using a layered nanoreactor: Towards advanced supercapacitor electrodes and devices
title_sort zno/zns/carbon nanocomposite-derived sulfur-doped carbon nanosheets using a layered nanoreactor: towards advanced supercapacitor electrodes and devices
publisher Elsevier B.V.
publishDate 2025
_version_ 1825816116001243136
score 13.244413