Rooting out faulty adsorption models. Comment on ?Magnetic Prussian blue nanoshells are controllable (sic) anchored on the surface of molybdenum disulfide nanosheets for efficient separation of radioactive cesium from water?

This correspondence critically examines and rectifies modeling deficiencies identified in a recent article published in this journal. Our analysis covers a range of models and issues, including the Temkin isotherm, the Flory?Huggins isotherm, the pseudo-first-order kinetic model, the pseudo-second-o...

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Main Authors: Chu K.H., Hashim M.A., Hayder G., Bollinger J.-C.
Other Authors: 7402453718
Format: Letter
Published: Elsevier B.V. 2025
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spelling my.uniten.dspace-366002025-03-03T15:43:19Z Rooting out faulty adsorption models. Comment on ?Magnetic Prussian blue nanoshells are controllable (sic) anchored on the surface of molybdenum disulfide nanosheets for efficient separation of radioactive cesium from water? Chu K.H. Hashim M.A. Hayder G. Bollinger J.-C. 7402453718 7005780117 56239664100 35546414700 Kinetic parameters Kinetic theory Layered semiconductors Molybdenum disulfide Silicon carbide disulfide ferric ferrocyanide molybdenum nanosheet nanoshell cesium water Adsorption kinetics Adsorption modeling Defective models Erroneous model Magnetic Prussian blues Molybdenum disulfide nanosheets Radioactive cesiums Rootings Temkin isotherm Thermodynamics calculations adsorption adsorption kinetics calculation chemical reaction kinetics elovich kinetic model intragranular diffusion model isotherm kinetics Letter mathematical model pseudo first order kinetic model pseudo second order kinetic model thermodynamics adsorption calculation controlled study diffusion isotherm letter nonhuman rooting thermodynamics Adsorption This correspondence critically examines and rectifies modeling deficiencies identified in a recent article published in this journal. Our analysis covers a range of models and issues, including the Temkin isotherm, the Flory?Huggins isotherm, the pseudo-first-order kinetic model, the pseudo-second-order kinetic model, the intraparticle diffusion model, the Elovich kinetic model, and the computation of thermodynamic parameters. The elucidation and correction of these modeling issues contribute to a more accurate and reliable understanding of the studied phenomena, thereby enhancing the scientific rigor of the subject paper. ? 2024 Elsevier B.V. Final 2025-03-03T07:43:19Z 2025-03-03T07:43:19Z 2024 Letter 10.1016/j.scitotenv.2024.171118 2-s2.0-85185536705 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85185536705&doi=10.1016%2fj.scitotenv.2024.171118&partnerID=40&md5=96a247a0ce3997f5f6255ed6eef12c4f https://irepository.uniten.edu.my/handle/123456789/36600 921 171118 Elsevier B.V. Scopus
institution Universiti Tenaga Nasional
building UNITEN Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Tenaga Nasional
content_source UNITEN Institutional Repository
url_provider http://dspace.uniten.edu.my/
topic Kinetic parameters
Kinetic theory
Layered semiconductors
Molybdenum disulfide
Silicon carbide
disulfide
ferric ferrocyanide
molybdenum
nanosheet
nanoshell
cesium
water
Adsorption kinetics
Adsorption modeling
Defective models
Erroneous model
Magnetic Prussian blues
Molybdenum disulfide nanosheets
Radioactive cesiums
Rootings
Temkin isotherm
Thermodynamics calculations
adsorption
adsorption kinetics
calculation
chemical reaction kinetics
elovich kinetic model
intragranular diffusion model
isotherm
kinetics
Letter
mathematical model
pseudo first order kinetic model
pseudo second order kinetic model
thermodynamics
adsorption
calculation
controlled study
diffusion
isotherm
letter
nonhuman
rooting
thermodynamics
Adsorption
spellingShingle Kinetic parameters
Kinetic theory
Layered semiconductors
Molybdenum disulfide
Silicon carbide
disulfide
ferric ferrocyanide
molybdenum
nanosheet
nanoshell
cesium
water
Adsorption kinetics
Adsorption modeling
Defective models
Erroneous model
Magnetic Prussian blues
Molybdenum disulfide nanosheets
Radioactive cesiums
Rootings
Temkin isotherm
Thermodynamics calculations
adsorption
adsorption kinetics
calculation
chemical reaction kinetics
elovich kinetic model
intragranular diffusion model
isotherm
kinetics
Letter
mathematical model
pseudo first order kinetic model
pseudo second order kinetic model
thermodynamics
adsorption
calculation
controlled study
diffusion
isotherm
letter
nonhuman
rooting
thermodynamics
Adsorption
Chu K.H.
Hashim M.A.
Hayder G.
Bollinger J.-C.
Rooting out faulty adsorption models. Comment on ?Magnetic Prussian blue nanoshells are controllable (sic) anchored on the surface of molybdenum disulfide nanosheets for efficient separation of radioactive cesium from water?
description This correspondence critically examines and rectifies modeling deficiencies identified in a recent article published in this journal. Our analysis covers a range of models and issues, including the Temkin isotherm, the Flory?Huggins isotherm, the pseudo-first-order kinetic model, the pseudo-second-order kinetic model, the intraparticle diffusion model, the Elovich kinetic model, and the computation of thermodynamic parameters. The elucidation and correction of these modeling issues contribute to a more accurate and reliable understanding of the studied phenomena, thereby enhancing the scientific rigor of the subject paper. ? 2024 Elsevier B.V.
author2 7402453718
author_facet 7402453718
Chu K.H.
Hashim M.A.
Hayder G.
Bollinger J.-C.
format Letter
author Chu K.H.
Hashim M.A.
Hayder G.
Bollinger J.-C.
author_sort Chu K.H.
title Rooting out faulty adsorption models. Comment on ?Magnetic Prussian blue nanoshells are controllable (sic) anchored on the surface of molybdenum disulfide nanosheets for efficient separation of radioactive cesium from water?
title_short Rooting out faulty adsorption models. Comment on ?Magnetic Prussian blue nanoshells are controllable (sic) anchored on the surface of molybdenum disulfide nanosheets for efficient separation of radioactive cesium from water?
title_full Rooting out faulty adsorption models. Comment on ?Magnetic Prussian blue nanoshells are controllable (sic) anchored on the surface of molybdenum disulfide nanosheets for efficient separation of radioactive cesium from water?
title_fullStr Rooting out faulty adsorption models. Comment on ?Magnetic Prussian blue nanoshells are controllable (sic) anchored on the surface of molybdenum disulfide nanosheets for efficient separation of radioactive cesium from water?
title_full_unstemmed Rooting out faulty adsorption models. Comment on ?Magnetic Prussian blue nanoshells are controllable (sic) anchored on the surface of molybdenum disulfide nanosheets for efficient separation of radioactive cesium from water?
title_sort rooting out faulty adsorption models. comment on ?magnetic prussian blue nanoshells are controllable (sic) anchored on the surface of molybdenum disulfide nanosheets for efficient separation of radioactive cesium from water?
publisher Elsevier B.V.
publishDate 2025
_version_ 1825816239716433920
score 13.244413