Recent advances in silicon nanomaterials for lithium-ion batteries: Synthesis approaches, emerging trends, challenges, and opportunities

Lithium-ion batteries (LIBs) are essential for powering a wide range of current devices, including portable electronics and electric vehicles, because they have a high energy density, can be recharged, and are versatile. Silicon (Si)-based materials are being extensively studied as very promising an...

Full description

Saved in:
Bibliographic Details
Main Authors: Hossain M.A.M., Tiong S.K., Hannan M.A., Ker P.J., Fattah I.M.R., Mahlia T.M.I.
Other Authors: 57226629032
Format: Review
Published: Elsevier B.V. 2025
Subjects:
Tags: Add Tag
No Tags, Be the first to tag this record!
id my.uniten.dspace-36524
record_format dspace
spelling my.uniten.dspace-365242025-03-03T15:42:52Z Recent advances in silicon nanomaterials for lithium-ion batteries: Synthesis approaches, emerging trends, challenges, and opportunities Hossain M.A.M. Tiong S.K. Hannan M.A. Ker P.J. Fattah I.M.R. Mahlia T.M.I. 57226629032 15128307800 7103014445 37461740800 58776756000 56997615100 Anodes Energy policy Ions Mass transfer Nanostructured materials Silicon 'current Academic sectors Emerging trends Energy Higher energy density Industrial sector New trend Portable electronics Silicon-based materials Specific capacities Lithium-ion batteries Lithium-ion batteries (LIBs) are essential for powering a wide range of current devices, including portable electronics and electric vehicles, because they have a high energy density, can be recharged, and are versatile. Silicon (Si)-based materials are being extensively studied as very promising anode compounds for future LIBs due to their moderate operating potential, high theoretical mass-specific capacity, and abundance. Consequently, it received considerable interest from both the academic and industrial sectors. However, electrochemical efficiency is hindered by significant changes in volume, leading to inadequate cyclability and eventual electrode malfunction. Nanostructured Si anodes address these issues by offering a reduced lithium diffusion distance, effective strain relaxation, improved mass transfer, and efficient electrical contact. The research on Si nanomaterials is highly significant due to the increasing need for improved energy density and safety in the rapidly developing field of energy storage. Recently, there have been attempts to mitigate the negative consequences of bulk effects, and nanosizing has emerged as a widely acknowledged and effective method. However, it has also encountered a limitation in its progress. Hence, this review aims to provide an in-depth overview of recent research on advances in Si materials, synthesis techniques, prevailing trends, and challenges, followed by emphasizing opportunities for future scientific study and commercial development of lithium-ion batteries. Overall, this review study holds significant merit as a reference tool for academics, researchers, and industry to explore research gaps and improve Si-based LIBs, which will shed light on solving the global energy crisis. ? 2024 Elsevier B.V. Final 2025-03-03T07:42:52Z 2025-03-03T07:42:52Z 2024 Review 10.1016/j.susmat.2024.e00964 2-s2.0-85192677084 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85192677084&doi=10.1016%2fj.susmat.2024.e00964&partnerID=40&md5=7b688b3fcf448a0557414de70981ad9d https://irepository.uniten.edu.my/handle/123456789/36524 40 e00964 Elsevier B.V. Scopus
institution Universiti Tenaga Nasional
building UNITEN Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Tenaga Nasional
content_source UNITEN Institutional Repository
url_provider http://dspace.uniten.edu.my/
topic Anodes
Energy policy
Ions
Mass transfer
Nanostructured materials
Silicon
'current
Academic sectors
Emerging trends
Energy
Higher energy density
Industrial sector
New trend
Portable electronics
Silicon-based materials
Specific capacities
Lithium-ion batteries
spellingShingle Anodes
Energy policy
Ions
Mass transfer
Nanostructured materials
Silicon
'current
Academic sectors
Emerging trends
Energy
Higher energy density
Industrial sector
New trend
Portable electronics
Silicon-based materials
Specific capacities
Lithium-ion batteries
Hossain M.A.M.
Tiong S.K.
Hannan M.A.
Ker P.J.
Fattah I.M.R.
Mahlia T.M.I.
Recent advances in silicon nanomaterials for lithium-ion batteries: Synthesis approaches, emerging trends, challenges, and opportunities
description Lithium-ion batteries (LIBs) are essential for powering a wide range of current devices, including portable electronics and electric vehicles, because they have a high energy density, can be recharged, and are versatile. Silicon (Si)-based materials are being extensively studied as very promising anode compounds for future LIBs due to their moderate operating potential, high theoretical mass-specific capacity, and abundance. Consequently, it received considerable interest from both the academic and industrial sectors. However, electrochemical efficiency is hindered by significant changes in volume, leading to inadequate cyclability and eventual electrode malfunction. Nanostructured Si anodes address these issues by offering a reduced lithium diffusion distance, effective strain relaxation, improved mass transfer, and efficient electrical contact. The research on Si nanomaterials is highly significant due to the increasing need for improved energy density and safety in the rapidly developing field of energy storage. Recently, there have been attempts to mitigate the negative consequences of bulk effects, and nanosizing has emerged as a widely acknowledged and effective method. However, it has also encountered a limitation in its progress. Hence, this review aims to provide an in-depth overview of recent research on advances in Si materials, synthesis techniques, prevailing trends, and challenges, followed by emphasizing opportunities for future scientific study and commercial development of lithium-ion batteries. Overall, this review study holds significant merit as a reference tool for academics, researchers, and industry to explore research gaps and improve Si-based LIBs, which will shed light on solving the global energy crisis. ? 2024 Elsevier B.V.
author2 57226629032
author_facet 57226629032
Hossain M.A.M.
Tiong S.K.
Hannan M.A.
Ker P.J.
Fattah I.M.R.
Mahlia T.M.I.
format Review
author Hossain M.A.M.
Tiong S.K.
Hannan M.A.
Ker P.J.
Fattah I.M.R.
Mahlia T.M.I.
author_sort Hossain M.A.M.
title Recent advances in silicon nanomaterials for lithium-ion batteries: Synthesis approaches, emerging trends, challenges, and opportunities
title_short Recent advances in silicon nanomaterials for lithium-ion batteries: Synthesis approaches, emerging trends, challenges, and opportunities
title_full Recent advances in silicon nanomaterials for lithium-ion batteries: Synthesis approaches, emerging trends, challenges, and opportunities
title_fullStr Recent advances in silicon nanomaterials for lithium-ion batteries: Synthesis approaches, emerging trends, challenges, and opportunities
title_full_unstemmed Recent advances in silicon nanomaterials for lithium-ion batteries: Synthesis approaches, emerging trends, challenges, and opportunities
title_sort recent advances in silicon nanomaterials for lithium-ion batteries: synthesis approaches, emerging trends, challenges, and opportunities
publisher Elsevier B.V.
publishDate 2025
_version_ 1825816064820248576
score 13.244413