Effect of Fly Ash characteristics, sodium-based alkaline activators, and process variables on the compressive strength of siliceous Fly Ash geopolymers with microstructural properties: A comprehensive review

Geopolymer concrete (GPC) exhibits enhanced performance compared to conventional concrete across various dimensions. These include decreased CO2 emissions, elevated mechanical strength, improved thermal insulation, greater fire resistance, the valorization of industrial wastes and increased efficien...

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Main Authors: Venkatesan G., Alengaram U.J., Ibrahim S., Ibrahim M.S.I.
Other Authors: 59166600700
Format: Review
Published: Elsevier Ltd 2025
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spelling my.uniten.dspace-364462025-03-03T15:42:28Z Effect of Fly Ash characteristics, sodium-based alkaline activators, and process variables on the compressive strength of siliceous Fly Ash geopolymers with microstructural properties: A comprehensive review Venkatesan G. Alengaram U.J. Ibrahim S. Ibrahim M.S.I. 59166600700 26533874300 7202480735 57199802346 Alkalinity Compressive strength Concretes Curing Fire resistance Fly ash Geopolymers Inorganic polymers Molar ratio Silicates Silicon Slags Sodium hydroxide Thermal insulation Alkaline activators Class F fly ash Compression strength Curing temperature Fly ash characteristics Geopolymer Geopolymer concrete Molarity Process Variables SiO2/al2O3 ratio Silica Geopolymer concrete (GPC) exhibits enhanced performance compared to conventional concrete across various dimensions. These include decreased CO2 emissions, elevated mechanical strength, improved thermal insulation, greater fire resistance, the valorization of industrial wastes and increased efficiency in energy conservation and production costs. This review focuses on the impact of 11 factors such as class F Fly Ash (FA) characteristics (fineness, SiO2/Al2O3 ratio, and iron content), sodium-based alkaline activators parameters such as molarity of sodium hydroxide (SH), Silicate Modulus (SM) of sodium silicate (SS) solution, ratio of SS/SH solution, alkaline liquid to binder ratio, water to binder (w/b) ratio, H2O/Na2Oequivalent, and process variables such as heat curing temperature and heating duration on the compression strength of low calcium (class F or siliceous) FA-based geopolymers (GP). Existing literature explicitly indicates that the molarity of NaOH solution is the primary strength parameter that significantly affects the compression strength of the GPC, among other factors. The range of alkaline activator parameters and heat curing temperature contingent on the SiO2/Al2O3 ratio of FA moreover accurately the reactive SiO2/Al2O3. Among all factors, one of the crucial parameter is the water content because of its importance in geopolymerization; the additional water released during the chemical reaction has to be considered in the mix design. The aforementioned eleven parameters are analysed and reported in the development of the compressive strength. ? 2024 Elsevier Ltd Final 2025-03-03T07:42:28Z 2025-03-03T07:42:28Z 2024 Review 10.1016/j.conbuildmat.2024.136808 2-s2.0-85195602113 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85195602113&doi=10.1016%2fj.conbuildmat.2024.136808&partnerID=40&md5=e4485be3a42c455d1b1d557bc7d6b174 https://irepository.uniten.edu.my/handle/123456789/36446 437 136808 Elsevier Ltd Scopus
institution Universiti Tenaga Nasional
building UNITEN Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Tenaga Nasional
content_source UNITEN Institutional Repository
url_provider http://dspace.uniten.edu.my/
topic Alkalinity
Compressive strength
Concretes
Curing
Fire resistance
Fly ash
Geopolymers
Inorganic polymers
Molar ratio
Silicates
Silicon
Slags
Sodium hydroxide
Thermal insulation
Alkaline activators
Class F fly ash
Compression strength
Curing temperature
Fly ash characteristics
Geopolymer
Geopolymer concrete
Molarity
Process Variables
SiO2/al2O3 ratio
Silica
spellingShingle Alkalinity
Compressive strength
Concretes
Curing
Fire resistance
Fly ash
Geopolymers
Inorganic polymers
Molar ratio
Silicates
Silicon
Slags
Sodium hydroxide
Thermal insulation
Alkaline activators
Class F fly ash
Compression strength
Curing temperature
Fly ash characteristics
Geopolymer
Geopolymer concrete
Molarity
Process Variables
SiO2/al2O3 ratio
Silica
Venkatesan G.
Alengaram U.J.
Ibrahim S.
Ibrahim M.S.I.
Effect of Fly Ash characteristics, sodium-based alkaline activators, and process variables on the compressive strength of siliceous Fly Ash geopolymers with microstructural properties: A comprehensive review
description Geopolymer concrete (GPC) exhibits enhanced performance compared to conventional concrete across various dimensions. These include decreased CO2 emissions, elevated mechanical strength, improved thermal insulation, greater fire resistance, the valorization of industrial wastes and increased efficiency in energy conservation and production costs. This review focuses on the impact of 11 factors such as class F Fly Ash (FA) characteristics (fineness, SiO2/Al2O3 ratio, and iron content), sodium-based alkaline activators parameters such as molarity of sodium hydroxide (SH), Silicate Modulus (SM) of sodium silicate (SS) solution, ratio of SS/SH solution, alkaline liquid to binder ratio, water to binder (w/b) ratio, H2O/Na2Oequivalent, and process variables such as heat curing temperature and heating duration on the compression strength of low calcium (class F or siliceous) FA-based geopolymers (GP). Existing literature explicitly indicates that the molarity of NaOH solution is the primary strength parameter that significantly affects the compression strength of the GPC, among other factors. The range of alkaline activator parameters and heat curing temperature contingent on the SiO2/Al2O3 ratio of FA moreover accurately the reactive SiO2/Al2O3. Among all factors, one of the crucial parameter is the water content because of its importance in geopolymerization; the additional water released during the chemical reaction has to be considered in the mix design. The aforementioned eleven parameters are analysed and reported in the development of the compressive strength. ? 2024 Elsevier Ltd
author2 59166600700
author_facet 59166600700
Venkatesan G.
Alengaram U.J.
Ibrahim S.
Ibrahim M.S.I.
format Review
author Venkatesan G.
Alengaram U.J.
Ibrahim S.
Ibrahim M.S.I.
author_sort Venkatesan G.
title Effect of Fly Ash characteristics, sodium-based alkaline activators, and process variables on the compressive strength of siliceous Fly Ash geopolymers with microstructural properties: A comprehensive review
title_short Effect of Fly Ash characteristics, sodium-based alkaline activators, and process variables on the compressive strength of siliceous Fly Ash geopolymers with microstructural properties: A comprehensive review
title_full Effect of Fly Ash characteristics, sodium-based alkaline activators, and process variables on the compressive strength of siliceous Fly Ash geopolymers with microstructural properties: A comprehensive review
title_fullStr Effect of Fly Ash characteristics, sodium-based alkaline activators, and process variables on the compressive strength of siliceous Fly Ash geopolymers with microstructural properties: A comprehensive review
title_full_unstemmed Effect of Fly Ash characteristics, sodium-based alkaline activators, and process variables on the compressive strength of siliceous Fly Ash geopolymers with microstructural properties: A comprehensive review
title_sort effect of fly ash characteristics, sodium-based alkaline activators, and process variables on the compressive strength of siliceous fly ash geopolymers with microstructural properties: a comprehensive review
publisher Elsevier Ltd
publishDate 2025
_version_ 1825816062935957504
score 13.244413